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Development of energy materials based on MOF and their applications

Research Project

Project/Area Number 15K13769
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic and hybrid materials
Research InstitutionKwansei Gakuin University

Principal Investigator

Yoshikawa Hirofumi  関西学院大学, 理工学部, 准教授 (60397453)

Co-Investigator(Renkei-kenkyūsha) TANIFUJI NAOKI  米子工業高等専門学校, 物質工学科, 准教授 (80423549)
AWAGA KUNIO  名古屋大学, 大学院理学研究科物質理学専攻, 教授 (10202772)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords金属有機構造体 / 二次電池 / ポリオキソメタレート / 炭素材料 / XAFS / ジスルフィド
Outline of Final Research Achievements

Metal organic frameworks (MOFs) have attracted much attention due to their application to energy storage. So far we have suggested a facile synthetic strategy to incorporate the redox active sites on both metal and ligand. In this work, we synthesized a novel MOF (Mn-MOF) consisting of Mn ions and AQDC ligands, and examined its battery performance. The Mn-MOF battery exhibited a gravimetric capacity of 200 mAh/g, which agreed well with the theoretical value of 190 mAh/g, assuming two electrons were accepted per anthraquinone and one electron for each manganese cation, and exhibited an excellent cyclability in the cycle performance test. Operando Mn K-edge XANES analysis on the Mn-MOF battery demonstrated that the electrochemical process of Mn-MOF was explained by both redox reactions of Mn ions and anthraquinone.
We also studied the battery performance of POMOF, which is composed of MOF and polyoxometalate (POM), and the preparation of carbon materials by using MOFs as a template.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (13 results)

All 2017 2016 2015 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 5 results) Remarks (2 results)

  • [Journal Article] Integration of Paramagnetic Diruthenium Complexes into an Extended Chain by Heterometallic Metal-Metal Bonds with Diplatinum Complexes2016

    • Author(s)
      K. Uemura, N. Uesugi, A. Matsuyama, M. Ebihara, H. Yoshikawa, K. Awaga
    • Journal Title

      Inorg. Chem.

      Volume: 55 Issue: 14 Pages: 7003-7011

    • DOI

      10.1021/acs.inorgchem.6b00741

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Discovery of a “Bipolar Charging” Mechanism In the Solid-State Electrochemical Process of a Flexible Metal-Organic Framework2016

    • Author(s)
      Zhongyue Zhang, Hirofumi Yoshikawa, Kunio Awaga
    • Journal Title

      Chem. Mater.

      Volume: 28 Issue: 5 Pages: 1298-1303

    • DOI

      10.1021/acs.chemmater.5b04075

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Vanadium-Incorporated, Polyoxometalate-Based Open Frameworks and Their Applications for Cathode-Active Materials2016

    • Author(s)
      Zhenxin Zhang, Hirofumi Yoshikawa, Zhongyue Zhang, Toru Murayama, Masahiro Sadakane, Yasunori Inoue, Wataru Ueda, Kunio Awaga, Michikazu Hara
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 2016 Issue: 8 Pages: 1242-1250

    • DOI

      10.1002/ejic.201501396

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] Rechargeable Batteries Using Polyoxovanadate Related Compounds as Cathode Active Materials2017

    • Author(s)
      Hirofumi Yoshikawa, Heng Wang
    • Organizer
      日本化学会 第97春季年会 (2017)
    • Place of Presentation
      慶応義塾大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Solid-state Electrochemistry of Coordination Compounds2016

    • Author(s)
      Hirofumi Yoshikawa
    • Organizer
      10th High-Tech Research Center International Symposium “Supramolecular Science-Based Organic Materials and Devices”
    • Place of Presentation
      東邦大学(千葉県・習志野市)
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 多電子の酸化還元能を有する金属有機構造体を正極活物質とする二次電池の開発2016

    • Author(s)
      吉川浩史、清水剛志
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ 国際会議場(千葉県・千葉市)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] Solid-state Electrochemistry of Molecular Clusters2016

    • Author(s)
      Hirofumi Yoshikawa
    • Organizer
      Satellite meeting of ICMM2016 “Molecular Technology for the Design and the Control of Functionalities in Materials”
    • Place of Presentation
      東京国際フォーラム(東京都・千代田区))
    • Year and Date
      2016-09-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属錯体系材料を正極活物質とする高性能二次電池の開発研究2016

    • Author(s)
      吉川浩史
    • Organizer
      新型電池オープンラボ第18回講演会
    • Place of Presentation
      神奈川大学(神奈川県・横浜市)
    • Year and Date
      2016-05-18
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 金属錯体系材料を正極とする高性能な二次電池の開発と放射光を利用した電池反応解析2016

    • Author(s)
      吉川浩史
    • Organizer
      第2回計算科学連携センターセミナー 放射光と計算科学との連携解析
    • Place of Presentation
      姫路じばさんビル(兵庫県・姫路市)
    • Year and Date
      2016-03-10
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 放射光を利用した多電子レドックスMOFの電池反応解析 ― 粉末X線とXAFS2016

    • Author(s)
      吉川浩史、張中岳、阿波賀邦夫
    • Organizer
      第5回名古屋大学シンクロトロン光研究センターシンポジウム
    • Place of Presentation
      名古屋大学(愛知県・名古屋市)
    • Year and Date
      2016-01-14
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 多孔性金属錯体を正極活物質とする二次電池の充放電特性と機能解明2015

    • Author(s)
      吉川浩史、張中岳、阿波賀邦夫
    • Organizer
      2015年電気化学秋季大会
    • Place of Presentation
      埼玉工業大学(埼玉県・深谷市)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Remarks] http://www.kg-nanotech.jp/yoshikawa/

    • Related Report
      2016 Annual Research Report
  • [Remarks] http://www.kg-nanotech.jp/yoshikawa/

    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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