Coordination soft materials possessing dynamic nanospaces
| Project/Area Number |
15K13771
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic and hybrid materials
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| Research Institution | Kyoto University |
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Principal Investigator |
Furukawa Shuhei 京都大学, 物質－細胞統合システム拠点, 准教授 (90452276)
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
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| Keywords | 金属錯体 / カゴ状物質 / ソフトマテリアル / 動的構造 / 空間 |
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| Outline of Final Research Achievements |
In this project, we aimed to tackle two main goals: the synthesis of supramolecular coordination molecules with dynamic and stable microporosity and the fabrication of soft materials by linking these molecules. We in particular succeeded in the unexpected progress of soft materialization. First, we achieved the synthesis of metal-organic polyhedra (MOP) with stable microporosity, which were unambiguously characterized by gas sorption experiments at the solid-state. Further, these MOPs were liked by supramolecular polymerization with imidazole-type linkers, leading to colloidal particles with a variety of sizes in controlled manner. By regulating thermodynamics and kinetics of supramolecular polymerization, we achieved the fabrication of soft materials as gels based on these MOPs and its permanent porosity was determined by gas sorption experiments.
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Report
(3 results)
Research Products
(8 results)
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[Journal Article] Metal-Organic Cuboctahedra for Synthetic Ion Channels with Multiple Conductance States2017
Author(s)
Ryuji Kawano, Nao Horike, Yuh Hijikata, Mio Kondo, Arnau Carne-Sanchez, Patrick Larpent, Shuya Ikemura, Toshihisa Osaki, Koki Kamiya, Susumu Kitagawa, Shoji Takeuchi, Shuhei Furukawa
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Journal Title
Chem
Volume: 2
Issue: 3
Pages: 393-403
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Journal Article] Rhodium-Organic Cuboctahedra as Porous Solids with Strong Binding Sites2016
Author(s)
Furukawa Shuhei, Horike Nao, Kondo Mio, Hijikata Yuh, Carne-Sanchez Arnau, Larpent Patrick, Louvain Nicolas, Diring Stephane, Sato Hiroshi, Matsuda Ryotaro, Kawano Ryuji, Kitagawe Susumu
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Journal Title
INORGANIC CHEMISTRY
Volume: 55
Issue: 21
Pages: 10843-10846
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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