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Develop of super resolution Raman microscope for the analyses of polymer nano structure toward single molecule

Research Project

Project/Area Number 15K13783
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionUniversity of Fukui

Principal Investigator

Maeda Yasushi  福井大学, 学術研究院工学系部門, 教授 (60242484)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords高分子構造・物性 / 顕微分光 / ナノ材料 / 分子分光 / 一分子計測 / 1分子計測 / ラマン散乱
Outline of Final Research Achievements

Super resolution Raman microscopes have been developed by combining Raman spectroscopy, which provides valuable information concerning molecular structure and interaction, with localized plasmon around the surface of Au and Ag, which enhances Raman scattering to a larger degree at the near field, to realize a high spatial resolution beyond diffraction limit and a high sensitivity toward single molecule measurements. A confocal Raman microscope with a spinning disk confocal laser scanner has also been developed, which realize a higher scanning rate than a piezo stage and a galvano mirror. Optical images based on Raman scattering can be directly observed with cooled CCD camera by selecting appropriate Raman bands with band pass filters.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2016 2015

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (12 results) (of which Invited: 1 results) Book (1 results)

  • [Journal Article] Metal-Free RAFT Cationic Polymerization of p-Methoxystyrene with HCl/Et2O Using a Xanthate-Type RAFT Cationogen2016

    • Author(s)
      Shinji Sugihara, Seiya Okubo, Yasushi Maeda
    • Journal Title

      Polym. Chem.

      Volume: 7 Issue: 44 Pages: 6854-6863

    • DOI

      10.1039/c6py01684g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure of Polymers as Observed by Vibrational Spectroscopy2016

    • Author(s)
      前田 寧
    • Journal Title

      Sen'i Gakkaishi

      Volume: 72 Issue: 4 Pages: P-213-P-213

    • DOI

      10.2115/fiber.72.P-213

    • NAID

      130005144736

    • ISSN
      0037-9875, 1884-2259
    • Related Report
      2016 Annual Research Report
  • [Journal Article] Direct Radical Polymerization of Vinyl Ethers: Reversible Addition-Fragmentation Chain Transfer Polymerization of Hydroxy-Functional Vinyl Ethers2016

    • Author(s)
      Shinji Sugihara, Yuki Kawamoto, and Yasushi Maeda
    • Journal Title

      Macromolecules

      Volume: 49 Issue: 5 Pages: 1563-1574

    • DOI

      10.1021/acs.macromol.6b00145

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] In situ nano-objects via RAFT aqueous dispersion polymerization of 2-methoxyethyl acrylate using poly(ethylene oxide) macromolecular chain transfer agent as steric stabilizer2015

    • Author(s)
      Sugihara, Shinji; Ma'Radzi, Akmal Hadi; Ida, Shota; Irie, Satoshi; Kikukawa, Takamaru; Maeda, Yasushi
    • Journal Title

      Polymer

      Volume: 76 Pages: 17-24

    • DOI

      10.1016/j.polymer.2015.08.051

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] HCl・Et2O-Catalyzed Metal-Free RAFT Cationic Polymerization: One-Pot Transformation from Metal-Free Living Cationic Polymerization to RAFT Radical Polymerization2015

    • Author(s)
      Sugihara, Shinji; Konegawa, Naoto; Maeda, Yasushi
    • Journal Title

      Macromolecules

      Volume: 48 Issue: 15 Pages: 5120-5131

    • DOI

      10.1021/acs.macromol.5b01071

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] N-置換アクリルアミドとN,N-二置換アクリルアミドの共重合体溶液の相分離に対する温度・圧力効果2016

    • Author(s)
      片川 成美、前田 寧、杉原 伸治
    • Organizer
      第65回高分子学会北陸支部研究発表会
    • Place of Presentation
      福井大学 文京キャンパス
    • Year and Date
      2016-11-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] 振動分光法による温度応答性高分子の水和の解析2016

    • Author(s)
      前田 寧
    • Organizer
      10th Mini-Symposium on Liquids
    • Place of Presentation
      岡山大学 津島キャンパス
    • Year and Date
      2016-10-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 振動分光法による温度応答性高分子の水和の解析2016

    • Author(s)
      前田 寧、片川 成美、杉原 伸治
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] ラマン散乱の増強効果を利用する高分子構造の分光学的解析2016

    • Author(s)
      前田 寧、藤村 和久、小林 祐貴、杉原 伸治
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 振動分光法で見る高分子の構造2016

    • Author(s)
      前田 寧
    • Organizer
      第 46 回繊維学会夏季セミナー
    • Place of Presentation
      福井市交流プラザ
    • Year and Date
      2016-07-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] N-置換アクリルアミドとN,N-二置換アクリルアミドの各種共重合体の水溶液中での温度・圧力応答性2015

    • Author(s)
      片川 成美・前田 寧・杉原 伸治
    • Organizer
      第64回高分子学会北陸支部研究発表会
    • Place of Presentation
      石川ハイテク交流センター
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 金属探針による表面プラズモン効果を利用したラマン分析装置の開発2015

    • Author(s)
      松木一真・前田寧・杉原伸治・藤村和久・矢田直人
    • Organizer
      第64回高分子学会北陸支部研究発表会
    • Place of Presentation
      石川ハイテク交流センター
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 原子間力顕微鏡と組み合わせた高空間分解能ラマン分光システムの開発2015

    • Author(s)
      藤村和久・松木一真・矢田直人・前田寧・杉原伸治
    • Organizer
      第64回高分子学会北陸支部研究発表会
    • Place of Presentation
      石川ハイテク交流センター
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 重合誘起自己組織化による有機溶媒分散ナノ組織の合成2015

    • Author(s)
      菊川雄丸・杉原伸治・前田寧
    • Organizer
      第64回高分子学会北陸支部研究発表会
    • Place of Presentation
      石川ハイテク交流センター
    • Year and Date
      2015-11-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 顕微ラマン分光法による高分子微細構造の解析2015

    • Author(s)
      前田 寧・松木 一真・藤村 和久・杉原 伸治
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-17
    • Related Report
      2015 Research-status Report
  • [Presentation] N-置換アクリルアミド―N,N-二置換アクリルアミド共重合体 溶液の温度・圧力応答性の解析2015

    • Author(s)
      片川 成美・前田 寧・杉原 伸治
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-17
    • Related Report
      2015 Research-status Report
  • [Presentation] 水酸基含有ビニルエーテル類のRAFT重合2015

    • Author(s)
      杉原 伸治・川本 裕紀・前田 寧
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Book] Temperature-responsive polymers: Chemistry, Properties and Applications. Chapter 12: Infrared and Raman spectroscopy2016

    • Author(s)
      Yasushi Maeda
    • Total Pages
      20
    • Publisher
      John Wiley & Sons
    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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