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Highly-functionalized oxygen-storage materials for innovative oxygen-gas production technologies

Research Project

Project/Area Number 15K13793
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionKanagawa University

Principal Investigator

MOTOHASHI Teruki  神奈川大学, 工学部, 教授 (00323840)

Co-Investigator(Kenkyū-buntansha) 齋藤 美和  神奈川大学, 工学部, 助教 (60594215)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsセラミックス / 酸素貯蔵材料 / 酸素ガス製造
Outline of Final Research Achievements

The present work dealt with highly-functionalized oxygen-storage materials (OSMs), which can reversibly store and release oxygen, for realizing innovative oxygen-gas production technologies. Our group focused on brownmillerite-type Ca2AlMnO5+d, aiming for lowered operation temperature and enhanced oxygen intake/release performance by means of chemical substitutions. The main achievements are as follows. (1) The oxygen intake/release temperatures were successfully lowered upon Ca-for-Sr substitution, retaining sufficiently high oxygen storage capacity. (2) For the pristine Ca2AlMnO5+d and its Sr-substituted phases, the rate limiting processes for the oxygen intake reaction were identified.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (10 results)

All 2016 2015

All Journal Article (2 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 2 results) Presentation (7 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] 新規酸素貯蔵材料の開発と酸素ガス製造・濃縮への応用2016

    • Author(s)
      本橋輝樹
    • Journal Title

      耐火物

      Volume: 68 Pages: 554-559

    • NAID

      40021022619

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] マンガンをベースにした酸素貯蔵材料:応用に向けた材料開発と材料テーラリング2015

    • Author(s)
      本橋輝樹
    • Journal Title

      神奈川大学工学研究所所報

      Volume: 38 Pages: 17-21

    • NAID

      120006940647

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] ブラウンミラーライト型(Ca1-xSrx)2AlMnO5+δにおける酸素吸収放出反応の速度論解析2016

    • Author(s)
      齋藤美和,秋田谷悠佑,荻久保雅貴,本橋輝樹
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学(広島県、広島)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 低結晶性により得られたYBaCo4O7+δの顕著な酸素吸収放出特性2016

    • Author(s)
      小宮山海兵,遠藤絵梨奈,齋藤美和,本橋輝樹
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学(広島県、広島)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] ブラウンミラーライト型(Ca1-xSrx)2AlMnO5+δの合成と酸素吸収放出特性2016

    • Author(s)
      齋藤美和、荻久保雅貴、本橋輝樹
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 酸素貯蔵材料(Ca1-xSrx)2AlMnO5+δの酸素吸収メカニズムに関する反応速度論研究2016

    • Author(s)
      秋田谷悠佑,齋藤美和,本橋輝樹
    • Organizer
      第11回セラミックスフェスタin神奈川
    • Place of Presentation
      神奈川大学(神奈川県、横浜)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 微粒子化したYBaCo4O7+δの温度誘起型酸素吸収放出特性2016

    • Author(s)
      遠藤絵梨奈,小宮山海兵,齋藤美和,本橋輝樹
    • Organizer
      第11回セラミックスフェスタin神奈川
    • Place of Presentation
      神奈川大学(神奈川県、横浜)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Remarkable energy-related functionalities hidden in strongly-correlated magnetic materials2015

    • Author(s)
      T. Motohashi
    • Organizer
      25th Annual Meeting of MRS-Japan
    • Place of Presentation
      Yokohama Port Opening Plaza (Yokohama)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Ca2AlMnO5+δの温度変化による顕著な酸素吸収/放出と酸素ガス濃縮への応用2015

    • Author(s)
      荻久保雅貴、本橋輝樹
    • Organizer
      神大テクノフェスタ
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2015-10-23
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 酸素過剰型金属酸化物及びその製造方法と再生方法、並びに、酸素濃縮装置及び酸素吸脱着装置2016

    • Inventor(s)
      原田隆、辻秀人、山原圭二、本橋輝樹、齋藤美和
    • Industrial Property Rights Holder
      原田隆、辻秀人、山原圭二、本橋輝樹、齋藤美和
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-131927
    • Filing Date
      2016-07-01
    • Related Report
      2016 Annual Research Report

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Published: 2015-04-16   Modified: 2018-03-22  

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