Formation of novel metalloaluminophosphoate zeolite frameworks through topotactic interlayer pillaring
| Project/Area Number |
15K13800
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Tokyo University of Agriculture and Technology |
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Principal Investigator |
Maeda Kazuyuki 東京農工大学, 工学(系)研究科(研究院), 准教授 (60343159)
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| Co-Investigator(Renkei-kenkyūsha) |
KONDO ATSUSHI 東京農工大学, 大学院工学研究院, 助教 (60533619)
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| Research Collaborator |
WAKUI KENTARO 東京農工大学, 大学院工学府, 大学院生
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | ゼオライト / アルミノホスフェート / 多孔体 / 層状物質 / イオン交換 / 層状化合物 / 層間架橋 / AFY型 / メタロアルミノホスフェート |
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| Outline of Final Research Achievements |
This study aims at novel preparation of metalloaluminophosphate (MeAPO) zeolites by cation exchange of interlayer cationic organic amines of layered aluminophosphates (ALPOs) with metal cations to realize topotactic pillaring of the ALPO layers. Two-step cation exchange of a 2D ALPO in organic solvents resulted in topotactic pillaring to form a 3D open-framework, and AFY-type MeAPOs without organic SDA were successfully prepared.
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Report
(3 results)
Research Products
(3 results)
