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High fluxi mass transport in a narrow space by smart control of nanobubble generation/dissolution

Research Project

Project/Area Number 15K13881
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Thermal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

Hirai Shuichiro  東京工業大学, 工学院, 教授 (10173204)

Co-Investigator(Kenkyū-buntansha) 植村 豪  東京工業大学, 工学院, 特任准教授 (70515163)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywordsリチウム空気電池
Outline of Final Research Achievements

To realize a more powerful lithium-air battery, it is necessary to clarify and improve the O2 transport phenomena in the cathode. In this study, the effect of dissolved O2 concentration in the electrolyte on the cathode performance of a lithium-air battery was investigated. Using a beaker-type cell and nano/micro-bubble generator to dissolve O2, O2 concentration in the electrolyte was varied from 6.5 to 15.0 mg/L.
As a result, discharge performance was improved by increasing the dissolved O2 concentration in the electrolyte. However, concentration overpotential still dominates the discharge at high current density. By using a fine optical oxygen sensor, O2 concentration in the porous cathode was measured. It was found that O2 concentration in the cathode reached considerably low value. In order to improve the performance, an electrolyte flow cell was employed, and the concentration overpotential (transport resistance) was lowered.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (5 results)

All 2017 2016 2015

All Presentation (5 results) (of which Int'l Joint Research: 3 results)

  • [Presentation] OPTICAL MEASUREMENT OF OXYGEN CONCENTRATION2017

    • Author(s)
      S. Fujimoto, S. Uemura, N. Imanishi, S. Hirai
    • Organizer
      The 9th JSME-KSME Thermal and Fluids Engineering Conference (TFEC9)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Oxygen Concentration Measurement in the Porous Cathode of Aqueous Lithium-Air Battery By Fine Optical Fiber2017

    • Author(s)
      Shogo Fujimoto, Suguru Uemura, Nobuyuki Imanishi and Shuichiro Hirai
    • Organizer
      232nd ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of O2 Concentration and Precipitates on the Lithium Air Battery2016

    • Author(s)
      2)Suguru Uemura, Kosuke Torikai, Tomoaki Furuyama, Takashi Sasabe, Nobuyuki Imanishi, Shuichiro Hirai
    • Organizer
      ECS meeting, PRiME2016
    • Place of Presentation
      Hawaii Convention Center(Honolulu, Hawaii)
    • Year and Date
      2016-10-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] リチウム空気電池性能特性に及ぼす酸素濃度・析出物の影響2016

    • Author(s)
      植村豪, 古山知諒, 鳥飼孝介, 笹部崇, 今西誠之, 平井秀一郎
    • Organizer
      第53回日本伝熱シンポジウム
    • Place of Presentation
      グランキューブ大阪(大阪)
    • Year and Date
      2016-05-24
    • Related Report
      2016 Research-status Report
  • [Presentation] 溶解酸素濃度がリチウム空気電池の分極現象に及ぼす影響2015

    • Author(s)
      鳥飼孝介, 植村豪, 笹部崇, 平井秀一郎
    • Organizer
      日本機械学会 熱工学コンファレンス2015
    • Place of Presentation
      大阪大学 吹田キャンパス
    • Year and Date
      2015-10-24
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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