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Study on reversible / irreversible switching mechanism of 3state smart-windows by anion concentration control

Research Project

Project/Area Number 15K13980
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electron device/Electronic equipment
Research InstitutionTokyo Polytechnic University

Principal Investigator

Uchida Takayuki  東京工芸大学, 工学部, 教授 (80203537)

Co-Investigator(Kenkyū-buntansha) 關 成之  仙台高等専門学校, 総合工学科, 准教授 (50449378)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords銀ナノ粒子 / フェルミ準位 / スマートウィンドウ / 安定性 / プラズモン / プッシュバック効果 / 核成長 / 銀イオン / プラズモン吸収 / エレクトロクロミズム / 酸化スズ / スプレーCVD / LSPR / エレクトロクロミック / 電気化学素子 / 熱遮蔽
Outline of Final Research Achievements

We focused on the particle size and distribution of the particle size of silver nanoparticles based on the growth process of silver and controlled them from electric field intensity, voltage waveform, and silver ion concentration in solution. As a result, the frequency of nucleation of silver changes depending on the ion concentration in the vicinity of the electrode interface, so that the size and the distribution of particle size formed nanoparticles are different. Finally, it is possible to indicate from transparent to mirror or black state.
Further, from the viewpoint of energy level, based on the guideline that the silver Fermi level (Ef) is stable when it is lower than the surrounding Ef in order to stabilize the silver nanoparticles which tend to aggregate and migrate Study was carried out. As a result, it was revealed that it is caused by the formation of a self-assembled monolayer of a specific organic compound.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (31 results)

All 2018 2017 2016 2015 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 3 results) Presentation (23 results) (of which Int'l Joint Research: 3 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Stabilization of Ag nanostructures by tuning their Fermi levels2018

    • Author(s)
      Tani Tadaaki、Kan Ryota、Yamano Yuka、Uchida Takayuki
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 5 Pages: 055001-055001

    • DOI

      10.7567/jjap.57.055001

    • NAID

      210000149055

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 大気中での銀ナノ粒子の安定性:フェルミ準位と酸化2017

    • Author(s)
      谷忠昭, 菅亮太, 山野侑香, 内田孝幸
    • Journal Title

      日本写真学会誌

      Volume: 第80巻 Pages: 104-110

    • NAID

      130007377747

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ペロブスカイト太陽電池の正孔輸送特性と経時変化2017

    • Author(s)
      山野侑香、菅亮太、谷忠昭、内田孝幸
    • Journal Title

      日本写真学会誌

      Volume: 80 Pages: 53-59

    • NAID

      130006410860

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] MoO x /Ag/MoO x transparent electrode by solution process2017

    • Author(s)
      Ryota Kan, Yuka Yamano, Tadaaki Tani and Takayuki Uchida.
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 5S2 Pages: 05EB05-05EB05

    • DOI

      10.7567/jjap.56.05eb05

    • NAID

      210000147783

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Improvement in luminance efficiency of organic light emitting diodes by suppression of secondary electron bombardment of substrate during sputter deposition of top electrode films2016

    • Author(s)
      1)Daichi Hamaguchi, Shin-ichi Kobayashi, Takayuki Uchida, Yutaka Sawada, Hao Lei, and Yoichi Hoshi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 10 Pages: 1-4

    • DOI

      10.7567/jjap.55.106501

    • NAID

      210000147138

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Reversible Change of the Transparent-Green for the Color Indication by Electrochemically Deposited Silver using Pulse Width Modulation2015

    • Author(s)
      市川正人、菅亮太、谷忠昭、内田孝幸
    • Journal Title

      NIHON GAZO GAKKAISHI (Journal of the Imaging Society of Japan)

      Volume: 54 Issue: 4 Pages: 276-283

    • DOI

      10.11370/isj.54.276

    • NAID

      130005092031

    • ISSN
      1344-4425, 1880-4675
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 金属/有機層界面の電子構造に基づく銀ナノ粒子の経時安定化2018

    • Author(s)
      谷忠昭, 山野侑香, 菅亮太, 内田孝幸
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ゼラチンをゲル化電解質のホストポリマーとして用いた銀電着型透明スマートウィンドウに関する研究2017

    • Author(s)
      内田孝幸, 菅亮太, 關成之, 谷忠昭
    • Organizer
      日本写真学会、画像関連学会 第四回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 光デバイス用銀ナノ構造体の電子構造と安定性2017

    • Author(s)
      谷忠昭, 山野侑香, 菅亮太, 内田孝幸
    • Organizer
      第36回固体・表面光化学討論会(光化学協会、 日本化学会、 触媒学会、電気化学会)
    • Related Report
      2017 Annual Research Report
  • [Presentation] プラズモニック銀ナノ粒子の電子構造と安定性2017

    • Author(s)
      谷忠昭, 菅亮太, 山野侑香, 内田孝幸
    • Organizer
      2017年光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Characteristics of MoO3/Ag/MoO3 Transparent Electrode and Their Electronic Structure2017

    • Author(s)
      R. Kan, Y. Yamano, T. Tani, T. Uchida, Y. Tabira and I. Yashima
    • Organizer
      10th International Symposium on Transparent Oxide and Related Materials for Electronics and Optics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化モリブデンと銀を用いた積層構造透明導電膜の発現機構の研究2017

    • Author(s)
      菅亮太,山野侑香,谷忠昭,内田孝幸
    • Organizer
      2017年度 日本写真学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 銀ナノ粒子の劣化機構-腐食理論から固体物理へ2017

    • Author(s)
      谷忠昭, 菅亮太, 山野侑香, 内田孝幸
    • Organizer
      2017年度 日本写真学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 銀ナノ粒子の劣化の要因分析と対策―酸化、硫化&Ag+の拡散2017

    • Author(s)
      谷忠昭, 菅亮太, 山野侑香, 内田孝幸
    • Organizer
      ナノ学会第15回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 銀ナノ粒子の安定性:銀塩写真からプラズモニクスへの展開2017

    • Author(s)
      谷忠昭, 菅亮太, 山野侑香, 内田孝幸
    • Organizer
      第64回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Flexible SnO2 Electrodes Prepared by Spray Deposition Processes for Ag Deposition-Based Three-Way EC Device2017

    • Author(s)
      H. Suzuki, W. Fujimoto, K. Suzuki, Y. Henmi, Y. Seki,T. Sasaki, K. Pak, S. Seki, T. Suenaga, K. Kumagai,T. Satoh, T. Uchida
    • Organizer
      The 24th International Display Workshops (IDW’17) EPp1 - 4L
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MoO3/Ag 積層膜を用いた透明導電膜と有機EL 素子への応用2016

    • Author(s)
      菅亮太,山野侑香,谷忠昭,内田孝幸
    • Organizer
      画像関連学会連合会 第3 回秋季大会
    • Place of Presentation
      京都工芸繊維大学、(京都)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 銀ナノ粒子の安定性:銀塩写真の視点からの検討2016

    • Author(s)
      谷 忠昭、菅 亮太、山野 侑香、内田 孝幸
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ国際会議場、(新潟)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 上部Al 電極作製時の基板温度上昇がOLED の動作特性に与え2016

    • Author(s)
      星 陽一, 濱口 大地, 小林 信一, 澤田 豊, 内田 孝幸, 安田 洋司
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ国際会議場、(新潟)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] ペロブスカイト太陽電池の正孔輸送層の特性及び経時変化の研究2016

    • Author(s)
      山野 侑香, 菅 亮太, 谷 忠昭, 内田 孝幸
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ国際会議場、(新潟)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Study of a MoOx/Ag/MoOx transparent electrode by solution process2016

    • Author(s)
      Ryota Kan, Yuka Yamano, Tadaaki Tani, Takayuki Uchida
    • Organizer
      2016 International Conference on Flexible and Printed Electronics
    • Place of Presentation
      山形大学(米沢、山形)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] MoO3/Ag/MoO3からなる積層膜の透明性ならびに導電性の発現機構の研究2016

    • Author(s)
      菅 亮太, 山野侑香, 市川正人, 谷忠昭, 内田孝幸
    • Organizer
      日本写真学会年次大会
    • Place of Presentation
      東京工業大学すずかけ台キャンパス、(神奈川)
    • Year and Date
      2016-06-13
    • Related Report
      2016 Research-status Report
  • [Presentation] ペロブスカイト型太陽電池の正孔輸送および陽極材料の検討2016

    • Author(s)
      山野侑香, 菅 亮太, 谷忠昭, 内田孝幸
    • Organizer
      日本写真学会年次大会
    • Place of Presentation
      東京工業大学すずかけ台キャンパス、(神奈川)
    • Year and Date
      2016-06-13
    • Related Report
      2016 Research-status Report
  • [Presentation] ゼラチン層中の銀ナノ粒子の酸化還元と安定性2016

    • Author(s)
      谷忠昭, 菅 亮太, 山野侑香, 内田孝幸
    • Organizer
      日本写真学会年次大会
    • Place of Presentation
      東京工業大学すずかけ台キャンパス、(神奈川)
    • Year and Date
      2016-06-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 透明-鏡面-黒色の3状態に変更可能なステッカー型ECスマートウィンドウの作製と評価2015

    • Author(s)
      志田共晶, 山田晃大, 柏真理実, 松本光平, 佐々木匠, 末永貴俊, 佐藤友章, 朴槿英, 関成之, 内田孝幸
    • Organizer
      応用物理学会東北支部第70回東北支部学術講演会
    • Place of Presentation
      南田温泉ホテルアップルランド(青森県)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] ゼラチン/銀系の状態と銀ナノ粒子の安定性2015

    • Author(s)
      忠昭、市川正人、菅 亮太、内田孝幸
    • Organizer
      画像関連学会連合会 第二回秋季大会
    • Place of Presentation
      京都工芸繊維大学(京都府)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Research-status Report
  • [Presentation] 透明EC素子における電圧制御,溶媒による多色表示の試み2015

    • Author(s)
      市川正人、関成之、菅亮太、横山拓実、志田共晶、山田晃大、谷忠昭、内田孝幸
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 銀/有機薄膜界面の電子構造と銀ナノ粒子の安定性2015

    • Author(s)
      谷忠昭、市川正人、菅亮太、内田孝幸
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 銀ナノ粒子の安定化と光化学およびプラズモニクスへの適用2015

    • Author(s)
      谷忠昭、市川正人、菅亮太、内田孝幸
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学 杉本キャンパス(大阪府)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Book] 月刊機能材料2017

    • Author(s)
      内田孝幸
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Research-status Report
  • [Remarks] 東京工芸大学 工学部 電子画像研究室

    • URL

      http://www.mega.t-kougei.ac.jp/denga_me/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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