Study on reversible / irreversible switching mechanism of 3state smart-windows by anion concentration control
Project/Area Number |
15K13980
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Electron device/Electronic equipment
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Research Institution | Tokyo Polytechnic University |
Principal Investigator |
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Co-Investigator(Kenkyū-buntansha) |
關 成之 仙台高等専門学校, 総合工学科, 准教授 (50449378)
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Project Period (FY) |
2015-04-01 – 2018-03-31
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Project Status |
Completed (Fiscal Year 2017)
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Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
|
Keywords | 銀ナノ粒子 / フェルミ準位 / スマートウィンドウ / 安定性 / プラズモン / プッシュバック効果 / 核成長 / 銀イオン / プラズモン吸収 / エレクトロクロミズム / 酸化スズ / スプレーCVD / LSPR / エレクトロクロミック / 電気化学素子 / 熱遮蔽 |
Outline of Final Research Achievements |
We focused on the particle size and distribution of the particle size of silver nanoparticles based on the growth process of silver and controlled them from electric field intensity, voltage waveform, and silver ion concentration in solution. As a result, the frequency of nucleation of silver changes depending on the ion concentration in the vicinity of the electrode interface, so that the size and the distribution of particle size formed nanoparticles are different. Finally, it is possible to indicate from transparent to mirror or black state. Further, from the viewpoint of energy level, based on the guideline that the silver Fermi level (Ef) is stable when it is lower than the surrounding Ef in order to stabilize the silver nanoparticles which tend to aggregate and migrate Study was carried out. As a result, it was revealed that it is caused by the formation of a self-assembled monolayer of a specific organic compound.
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Report
(4 results)
Research Products
(31 results)
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[Presentation] Flexible SnO2 Electrodes Prepared by Spray Deposition Processes for Ag Deposition-Based Three-Way EC Device2017
Author(s)
H. Suzuki, W. Fujimoto, K. Suzuki, Y. Henmi, Y. Seki,T. Sasaki, K. Pak, S. Seki, T. Suenaga, K. Kumagai,T. Satoh, T. Uchida
Organizer
The 24th International Display Workshops (IDW’17) EPp1 - 4L
Related Report
Int'l Joint Research
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