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Establish of Bonding Conversion in Isolated Cluster and Production of Boren

Research Project

Project/Area Number 15K14106
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical properties of metals/Metal-base materials
Research InstitutionThe University of Tokyo

Principal Investigator

Kimura Kaoru  東京大学, 大学院新領域創成科学研究科, 教授 (30169924)

Co-Investigator(Renkei-kenkyūsha) UCHIDA NORIYUKI  独立行政法人産業技術総合研究所, ナノエレクトロニクス研究部門, 主任研究員 (60400636)
Research Collaborator YAMAMURA HITOSHI  東京大学, 大学院新領域創成科学研究科
YAMAZAKI SHOHEI  東京大学, 大学院新領域創成科学研究科
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords分子軌道計算 / 金属結合 / 共有結合 / Wood-Saxonポテンシャル / 水素吸蔵 / 液体ボロン / コンプトン散乱 / 金属結合クラスター
Outline of Final Research Achievements

The orbital energies of metallic-bonded clusters correspond very well to electron energy levels in the Woods-Saxon potential, while those of covalent-bonded clusters do not. An electron in the Woods-Saxon potential is considered to be a free electron and a method of evaluation using this potential for metallic bonding of cluster has been given. The reason why an icosahedral structure is stable for Al13- and a triangle lattice planar one for B13- has been clear. On the other hand, production of boren has been given up, because other groups reported under our consideration. Instead of this, it has been discovered that the main bonding of liquid boron is covalent.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (5 results)

All 2017 2016 2015 Other

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results) Presentation (3 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] Visualizing the Mixed Bonding Properties of Liquid Boron with High-Resolution X-Ray Compton Scattering2015

    • Author(s)
      J. T. Okada, P.H.-L. Sit, Y. Watanabe, B. Barbiellini, T. Ishikawa, Y.J. Wang, M. Itou, Y. Sakurai, A. Bansil, R. Ishikawa, M. Hamaishi, P.-F. Paradis, K. Kimura, T. Ishikawa, and S. Nanao
    • Journal Title

      Physical Review Letters

      Volume: 114 Issue: 17 Pages: 177401-177401

    • DOI

      10.1103/physrevlett.114.177401

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 正二十面体Alクラスターの水素吸蔵媒体としての可能性2017

    • Author(s)
      山崎翔平、山村仁、木村薫
    • Organizer
      日本金属学会 2017年春期(第160回)講演大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] ホウ素融体中の結合状態の解明2016

    • Author(s)
      岡田純平、石川毅彦、木村薫、七尾進
    • Organizer
      第10回 日本ホウ素・ホウ化物研究会
    • Place of Presentation
      東京大学柏キャンパス 新領域基盤棟
    • Year and Date
      2016-03-05
    • Related Report
      2015 Research-status Report
  • [Presentation] ホウ素クラスターとクラスター固体・液体の結合転換と自己補償2015

    • Author(s)
      木村薫
    • Organizer
      東北大学 多元物質科学研究所 新機能無機物質探索研究センターシンポジウム
    • Place of Presentation
      東北大学 多元物質科学研究所 新機能無機物質探索研究センター
    • Year and Date
      2015-08-21
    • Related Report
      2015 Research-status Report
    • Invited
  • [Remarks] ホウ素は融けると金属になる? ~宇宙実験技術を活用してホウ素の謎を解明~

    • URL

      http://www.k.u-tokyo.ac.jp/info/entry/22_entry394/

    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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