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Study of the hetero-phase fluctuation in structural phase transition followed by the creation of novel concept of materials design and technologies

Research Project

Project/Area Number 15K14111
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical properties of metals/Metal-base materials
Research InstitutionShizuoka Institute of Science and Technology

Principal Investigator

Kubo Hiroshi  静岡理工科大学, 総合技術研究所, 客員教授 (30029904)

Co-Investigator(Renkei-kenkyūsha) Yoshida yutaka  静岡理工科大学, 理工学部, 教授 (40241129)
Nakayama masanobu  名古屋工業大学, 工学研究科, 准教授 (10401530)
Takesue naohisa  福岡大学, 理学部, 教授 (20292758)
Sahara ryouji  独立行政法人物質・材料研究機構, 研究員 (30323075)
Research Collaborator Sluiter Marcel H. F.  オランダデルフト大学, 材料学科, 教授
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywords相転移の熱統計力学 / Landau展開係数の秩序規則 / 中性子回折セントラルピーク / ヘテロ構造揺らぎ / 相転移kineticsの梯子登り理論 / ZrNb合金ω相転移 / 誘電体相転移 / ZrNb合金核燃料被覆材 / 相転移 / 熱統計力学 / 第一原理計算 / 揺らぎ / pre-ω相転移 / 臨界現象 / 中性子セントラルピーク / 相転移kinetics / ω相転移 / Landau自由エネルギー / ヘテロ構造揺らぎ理論 / ヘテロ構造揺らぎのkineics / 準安定相転移梯子登り理論 / 統計熱力学 / ω相転移の第1原理計算 / Landau自由エネルギーのq-点群表現 / 不均質相転移の自由エネルギー / ヘテロ構造揺らぎ理論確立 / オメガ相転移のkinetics / 構造揺らぎの梯子登りモデル
Outline of Final Research Achievements

The concept of the project is to study the mechanism of hetero-phase fluctuation of micro-domains formed in the bulk materials in structural phase transition, and accordingly to create the novel concept of materials design and technologies.
Three significant breakthroughs are made in the study of the science of structural phase transition. One is the establishment of statistical thermodynamics of Landau expansion model, where the sequence rule of the expansion coefficients in the Landau-type series is discovered and applied in the analysis of critical transition region. Second major accomplishment is the proposal of ladder-climing model in the kinetics of hetero-phase fluctuation of micro-domains. Third is the establishment of the theory of central peaks in the inelastic neutron scattering which has been left unvigorously analyzed over 45 years. It is revealed that the hetero-phase fluctuation of micro-domains is responsible to the central peak of neutron scattering.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (8 results)

All 2018 2017 2016

All Presentation (8 results)

  • [Presentation] 相転移のLandau理論_Sequence ruleとポテンシャル計算2018

    • Author(s)
      久保 紘
    • Organizer
      平成30年度日本金属学会春季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 相転移のLandau 理論・その本質とsequence rule2017

    • Author(s)
      久保 紘
    • Organizer
      平成29年度日本金属学会春季大会
    • Place of Presentation
      首都大学南大沢キャンパス
    • Year and Date
      2017-03-15
    • Related Report
      2016 Research-status Report
  • [Presentation] メスバウア分光法を用いた鉄鋼中の炭素挙動の観察2017

    • Author(s)
      藤田浩亨、久保 紘、吉田 豊
    • Organizer
      平成29年度日本金属学会春季大会
    • Place of Presentation
      首都大学南大沢キャンパス
    • Year and Date
      2017-03-15
    • Related Report
      2016 Research-status Report
  • [Presentation] 相転移のLandau 理論・その本質とsequence rule2017

    • Author(s)
      久保 紘
    • Organizer
      平成29年度日本金属学会春季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] メスバウア分光法を用いた鉄鋼中の炭素挙動の観察2017

    • Author(s)
      藤田浩亨、久保 紘、吉田 豊
    • Organizer
      平成29年度日本金属学会春季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Landau potential展開項の秩序性とTi50Ni1-xFex合金構造相転移機構の解明2016

    • Author(s)
      久保 紘
    • Organizer
      平成28年度日本金属学会秋季大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
  • [Presentation] 顕微メスバウア分光装置を用いた鉄鋼材料の微細組織観察2016

    • Author(s)
      藤田浩亨、久保 紘、吉田 豊
    • Organizer
      平成28年度日本金属学会秋季大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
  • [Presentation] Landau potential展開項の秩序性とmorhotropic phase boundary2016

    • Author(s)
      久保 紘
    • Organizer
      日本金属学会
    • Place of Presentation
      東京理科大学、葛飾キャンパス
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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