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Synthesis and characterization of mixed anion compounds with controlled Bi bonds

Research Project

Project/Area Number 15K14113
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionHokkaido University

Principal Investigator

MIURA AKIRA  北海道大学, 工学研究院, 助教 (10603201)

Co-Investigator(Kenkyū-buntansha) 長尾 雅則  山梨大学, 総合研究部, 助教 (10512478)
石井 聡  東京電機大学, 理工学部, 助教 (90442730)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords複合アニオン化合物 / ナノシート / ビスマス / BiS2 / BiCh2 / BiS2系化合物
Outline of Final Research Achievements

Layered mixed anion compounds, such as LaOBiS2, have been intensively studied since they have high flexibility for designing properties by changing composed anions. The aims of this research are 1) control properties by tuning chemical bond between Bi and S/Se and 2)producing new two-dimensional nanosheets by exfoliation. Research accomplishment includes the correlation between rare earth elements and superconductive transition, and the relationship between chemical pressure of the chmical bond of Bi-S/Se and superconductive transition temperature. The synthesis of LaOBiS2 nanosheets have been successful. We discover new layered oxysulfides including antimony and indium.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (12 results)

All 2017 2016 2015

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 7 results,  Open Access: 3 results) Presentation (2 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Synthesis of LaO0.5F0.5BiS2 nanosheets by ultrasonification2017

    • Author(s)
      Akira Miura, Satoshi Ishii, Masanori Nagao, Ryo Matsumoto, Yoshihiko Takano, Satoshi Watauchi, Isao Tanaka, Carolina Rosero, Kiyoharu Tadanaga
    • Journal Title

      Journal of Asian Ceramic Societies

      Volume: -

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Valence of praseodymium in superconducting Pr (O, F) BiS2 single crystals2016

    • Author(s)
      Satoshi Ishii, Yasuaki Hongu, Akira Miura, Masanori Nagao
    • Journal Title

      Applied Physics Express

      Volume: 9(6) Issue: 6 Pages: 063101-063101

    • DOI

      10.7567/apex.9.063101

    • NAID

      210000137944

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Superconductivity in CeOBiS2 with cerium valence fluctuation2016

    • Author(s)
      Masanori Nagao, Akira Miura, Ikuo Ueta, Satoshi Watauchi, Isao Tanakaa
    • Journal Title

      Solid State Communications

      Volume: 245 Pages: 11-14

    • DOI

      10.1016/j.ssc.2016.07.017

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structures and optical absorption of Bi2OS2 and LaOBiS22016

    • Author(s)
      Akira Miura, Yoshikazu Mizuguchi, Takahiro Takei, Nobuhiro Kumada, Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa, Kiyoharu Tadanaga
    • Journal Title

      Solid State Communications

      Volume: 227 Pages: 19-22

    • DOI

      10.1016/j.ssc.2015.11.016

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Compositional and temperature evolution of crystal structure of new thermoelectric compound LaOBiS2-xSex2016

    • Author(s)
      Yoshikazu Mizuguchi, Akira Miura, Nishida, Atushiro, Osuke Miura, Kiyoharu Tadanaga, Nobuhiro Kumada, Lee, C.H., Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa
    • Journal Title

      Journal of Applied Physics

      Volume: 119 Issue: 15 Pages: 155103-155103

    • DOI

      10.1063/1.4946836

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Growth and Structure of Ce(O,F)SbS2 Single Crystals2016

    • Author(s)
      Masanori Nagao, Masashi Tanaka, Ryo Matsumoto, Hiromi Tanaka, Satoshi Watauchi, Yoshihiko Takano, and Isao Tanaka
    • Journal Title

      Crystal Growth & Design

      Volume: - Issue: 5 Pages: 3037-3042

    • DOI

      10.1021/acs.cgd.6b00497

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] In-plane chemical pressure essential for superconductivity in BiCh2-based (Ch: S, Se) layered structure2015

    • Author(s)
      Yoshikazu Mizuguchi, Akira Miura, Joe Kajitani, Takafumi Hiroi, Osuke Miura, Kiyoharu Tadanaga, Nobuhiro Kumada, Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa
    • Journal Title

      Scientific Reports

      Volume: 2015 Issue: 1 Pages: 14968-14968

    • DOI

      10.1038/srep14968

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Growth and characterization of R (O, F) BiS2 (R= La, Ce, Pr, Nd) superconducting single crystals2015

    • Author(s)
      Masanori Nagao
    • Journal Title

      Novel Superconducting Materials

      Volume: 1 Issue: 1 Pages: 64-74

    • DOI

      10.1515/nsm-2015-0007

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] C-axis electrical resistivity of PrO1-aFaBiS2 single crystals2015

    • Author(s)
      Masanori Nagao, Akira Miura, Satoshi Watauchi, Yoshihiko Takano, Isao Tanaka
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Issue: 8 Pages: 083101-083101

    • DOI

      10.7567/jjap.54.083101

    • NAID

      210000145503

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Difference in Superconductive and Nonsuperconductive Bi-S Planes within Bi4O4Bi2S4 Blocks2015

    • Author(s)
      Akira Miura, Yoshikazu Mizuguchi, Tsuyoshi Sugawara, Yongming Wang, Takahiro Takei, Nobuhiro Kumada, Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa, Osuke Miura, Kiyoharu Tadanaga
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Issue: 21 Pages: 10462-10467

    • DOI

      10.1021/acs.inorgchem.5b01919

    • NAID

      120005851043

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] Crystal and electronic structures of LaOBiS2 and LaOInS22017

    • Author(s)
      Miura, Akira; Mizuguchi, Yoshikazu; Moriyoshi, Chikako; Kuroiwa, Yoshihiro; Higuchi, Mikio; Tadanaga, Kiyoharu
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 12)
    • Place of Presentation
      Hawai (USA)
    • Year and Date
      2017-05-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Pr(O,F)BiS2単結晶におけるPr価数のXPSによる評価2016

    • Author(s)
      ○石井 聡,本宮 靖章,三浦 章,長尾 雅則
    • Organizer
      応用物理学会2016年(平成28年)春季講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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