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Clarification of crystal growth through oriented attachment and its application for development of nanomaterials

Research Project

Project/Area Number 15K14129
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionKeio University

Principal Investigator

Imai Hiroaki  慶應義塾大学, 理工学部(矢上), 教授 (70255595)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords結晶成長 / 自己組織化 / 自己集合 / ナノ粒子
Outline of Final Research Achievements

We studied oriented attachment of various nanoscale rectangular blocks in iquid media as non-classical routes for fabrication techniques of nanoscale functional materials. First, we developed the controllability of oriented attachment for manganese oxide rectangular nanoblocks through changing the stabilizing agents, deposition rate, and the surface shape of the substrate. Second, we studied oriented attachment of rectangular nanoblocks composed of titanium dioxide, hydroxylapatite, and calcite. Finally, we provided new findings on oriented attachment for understanding and application of the non-classical crystal growth.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (31 results)

All 2018 2017 2016 2015

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Open Access: 4 results,  Acknowledgement Compliant: 9 results) Presentation (18 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results)

  • [Journal Article] Artificial Mineral Films Similar to Biogenic Calcareous Shells: Oriented Calcite Nanorods on a Self-Standing Polymer Sheet2018

    • Author(s)
      Nagai Yuta, Oaki Yuya, Imai Hiroaki
    • Journal Title

      CrystEngComm

      Volume: 20 Issue: 12 Pages: 1656-1661

    • DOI

      10.1039/c7ce02143g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of Calcite Nanocrystals through Oriented Attachment and Fragmentation: Multistep Pathway Involving Bottom-Up and Break-Down Stages2017

    • Author(s)
      Takasaki Mihiro、Kezuka Yuki、Tajika Masahiko、Oaki Yuya、Imai Hiroaki
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 12 Pages: 8997-9001

    • DOI

      10.1021/acsomega.7b01487

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Spatial Control of Crystallographic Direction in 2D Microarrays of Anisotropic Nanoblocks on Trenched Substrates2017

    • Author(s)
      Matsumoto Riho、Nakagawa Yoshitaka、Kato Kazumi、Oaki Yuya、Imai Hiroaki
    • Journal Title

      Langmuir

      Volume: 33 Issue: 48 Pages: 13805-13810

    • DOI

      10.1021/acs.langmuir.7b03264

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oriented Attachment of Calcite Nanocrystals: Formation of Single-Crystalline Configurations as 3D Bundles via Lateral Stacking of 1D Chains2017

    • Author(s)
      M. Takasaki, Y. Oaki, H. Imai
    • Journal Title

      Langmuir

      Volume: 33 Pages: 1516-1520

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Switchable Oriented Attachment and Detachment of Calcite Nanocrystal2016

    • Author(s)
      M. Takasaki, Y. Oaki, H. Imai
    • Journal Title

      CrystEngComm

      Volume: 18 Pages: 8999-9002

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Evaporation-Driven Regularization of Crystallographically Ordered Arrangements of Truncated Nanoblocks: From 1D Chains to 2D Rhombic Superlattices2016

    • Author(s)
      R. Matsumoto, Y. Nakagawa, H. Kageyama, Y. Oaki, H. Imai,
    • Journal Title

      CrystEngComm

      Volume: 18 Issue: 33 Pages: 6138-6142

    • DOI

      10.1039/c6ce01512c

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 1D Oriented Attachment of Calcite Nanocrystals: Formation of Single-Crystalline Rods through Collision2016

    • Author(s)
      Mihiro Takasaki, Yuki Kimura, Tomoya Yamazaki, Yuya Oaki, Hiroaki Imai
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 66 Pages: 61346-61350

    • DOI

      10.1039/c6ra09452j

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] UV-induced Epitaxial Attachment of TiO2 Nanocrystals in Molecularly Mediated 1D and 2D Alignments2016

    • Author(s)
      T. Hiraide, H. Kageyama, Y. Nakagawa, Y. Oaki, H. Imai
    • Journal Title

      Chemical Communications

      Volume: 52 Issue: 48 Pages: 7545-7548

    • DOI

      10.1039/c6cc02001a

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Orientation-Selective Alignments of Hydroxyapatite Nanoblocks through Epitaxial Attachment in a and c Directions2016

    • Author(s)
      K. Nakamura, Y. Nakagawa, H. Kageyama, Y. Oaki, H. Imai
    • Journal Title

      Langmuir

      Volume: 32 Issue: 16 Pages: 4066-4070

    • DOI

      10.1021/acs.langmuir.6b00732

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Orientation-Selective Alignments of Nanoblocks in a and c Directions of Tetragonal System through Molecularly Mediated Manipulation2016

    • Author(s)
      Y. Nakagawa, H. Kageyama, Y. Oaki, H. Imai
    • Journal Title

      Chemical Communications

      Volume: 52 Pages: 5597-5600

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of Monocrystalline 1D and 2D Architectures via Epitaxial Attachment: Bottom-Up Routes through Surfactant-Mediated Arrays of Oriented Nanocrystals2015

    • Author(s)
      Yoshitaka Nakagawa, Hiroyuki Kageyama, Yuya Oaki, and Hiroaki Imai
    • Journal Title

      Langmuir

      Volume: 31 Issue: 22 Pages: 6197-6201

    • DOI

      10.1021/acs.langmuir.5b00502

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Conductive polymer-mediated 2D and 3D arrays of Mn3O4 nanoblocks and mesoporous conductive polymers as their replicas2015

    • Author(s)
      Yoshitaka Nakagawa, Hiroyuki Kageyama, Riho Matsumoto, Yuya Oaki and Hiroaki Imai
    • Journal Title

      Nanoscale

      Volume: 7 Issue: 44 Pages: 18471-18476

    • DOI

      10.1039/c5nr05912g

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Formation of uniformly sized metal oxide nanocuboids in the presence of precursor grains in an apolar medium2015

    • Author(s)
      Yoshitaka Nakagawa, Hiroyuki Kageyama, Riho Matsumoto, Yuya Oaki and Hiroaki Imai*a
    • Journal Title

      CrystEngComm

      Volume: 17 Issue: 39 Pages: 7477-7481

    • DOI

      10.1039/c5ce01257k

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Control of oriented attachment of calcite nanocrystals for formation of various single-crystalline configurations2017

    • Author(s)
      M. Takasaki, Y. Oaki, H. Imai
    • Organizer
      IUMRS-ICAM 2017 The 15th international Conference of Advanced Meterials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水酸化カルシウムの炭酸化における凝集と開裂過程を含むカルサイトナノ結晶の形成2017

    • Author(s)
      髙﨑美宏、毛塚雄己、田近正彦、緒明佑哉、今井宏明
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] カルサイトナノ結晶の配向集積・開裂の制御による1~3次元階層構造体の構築・分解2017

    • Author(s)
      髙﨑美宏、緒明佑哉、今井宏明
    • Organizer
      第7回CSJ化学フェスタ
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機シート上における多段階成長によるバイオミネラル類似カルサイト配向構造体の作製2017

    • Author(s)
      永井雄太、緒明佑哉、今井宏明
    • Organizer
      第7回CSJ化学フェスタ
    • Related Report
      2017 Annual Research Report
  • [Presentation] CaCO3ナノロッドの集積による配向フィルムの作製2017

    • Author(s)
      髙﨑美宏、緒明佑哉、今井宏明
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カルサイトナノ結晶の配向集積成長による1次元・3次元構造体の構築2017

    • Author(s)
      髙﨑美宏、緒明佑哉、今井宏明
    • Organizer
      日本セラミックス協会2017年年会
    • Place of Presentation
      日本大学駿河台キャンパス(東京都・千代田区)
    • Related Report
      2016 Research-status Report
  • [Presentation] サマリウムをドープ化した二酸化セリウムナノキューブの合成と規則配列構造の形成2017

    • Author(s)
      築山慧之、髙﨑美宏、緒明佑哉、今井宏明
    • Organizer
      日本セラミックス協会2017年年会
    • Place of Presentation
      日本大学駿河台キャンパス(東京都・千代田区)
    • Related Report
      2016 Research-status Report
  • [Presentation] 二酸化チタン矩形ナノブロックによる秩序構造体の作製2017

    • Author(s)
      平出智之、景山宏之、緒明佑哉、今井宏明
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター(岡山県・岡山市)
    • Related Report
      2016 Research-status Report
  • [Presentation] pH-Sensitive Oriented Attachment of Calcite Nanocrystals2016

    • Author(s)
      M. Takasaki, Y. Oaki, H. Imai
    • Organizer
      The 33rd International Korea-Japan Seminar on Ceramics
    • Place of Presentation
      Daejeon (Korea)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Characterization of Biogenic Arrayed Nanocrystals and Fabrication of Their Mimetics Through Classical and Nonclassical Routes2016

    • Author(s)
      H. Imai
    • Organizer
      Gordon Research Conferences - 2016 Meeting - Biomineralization
    • Place of Presentation
      Girona (Spain)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Oriented Assembly of Anisotropic Nanoblocks for Direction-Controlled 1D, 2D, 3D Microarrays2016

    • Author(s)
      H. Imai, Y. Nakagawa, R. Matsumoto, Y. Oaki
    • Organizer
      13th International Conference on Ceramic Processing Science (ICCPS-13)
    • Place of Presentation
      Nara Prefecturl Cultural Hall (Nara・Nara)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] TiO2;矩形ナノブロックを用いた秩序構造体の作成および紫外線光照射による融合2016

    • Author(s)
      平出智之、景山宏之、緒明佑哉、今井宏明
    • Organizer
      第6回CSJフェスタ2016
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Related Report
      2016 Research-status Report
  • [Presentation] 方位選択・可逆的なカルサイトナノ結晶の配向集積2016

    • Author(s)
      髙﨑美宏、緒明佑哉、今井宏明
    • Organizer
      第6回CSJフェスタ2016
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Related Report
      2016 Research-status Report
  • [Presentation] 矩形ナノブロックの空間的な配列制御による異配向秩序構造体の構築2016

    • Author(s)
      松本里穂、中川義隆、加藤一実、緒明佑哉、今井宏明
    • Organizer
      第6回CSJフェスタ2016
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Related Report
      2016 Research-status Report
  • [Presentation] Mn3O4矩形ナノブロックによる空間的に制御された配列構造の形成2016

    • Author(s)
      松本里穂、加藤一実、緒明佑哉、今井宏明
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学東広島キャンパス(広島県・東広島市)
    • Related Report
      2016 Research-status Report
  • [Presentation] Crystal Growth through Oriented Attachment of Calcite Nanocrystals2015

    • Author(s)
      Mihiro Takasaki, Yuya Oaki, Hiroaki Imai
    • Organizer
      2nd International Symposium on Frontiers in Materials Science
    • Place of Presentation
      Waseda University(shinjuku-ku, Tokyo)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] カルサイトナノ結晶の配向集積2015

    • Author(s)
      髙﨑美宏・緒明佑哉・今井宏明
    • Organizer
      日本化学会秋季事業第5回CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2015-10-14
    • Related Report
      2015 Research-status Report
  • [Presentation] ナノブロックの集積によるカルサイト結晶の成長2015

    • Author(s)
      髙﨑美宏・緒明佑哉・今井宏明
    • Organizer
      日本セラミックス協会第28回秋季シンポジウム
    • Place of Presentation
      富山大学(富山県・富山市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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