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Novel design concept of organic battery electrodes based on crystallography

Research Project

Project/Area Number 15K14153
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

Honma Itaru  東北大学, 多元物質科学研究所, 教授 (90181560)

Co-Investigator(Kenkyū-buntansha) 永村 直佳  国立研究開発法人物質・材料研究機構, 先端材料解析研究拠点, 研究員 (40708799)
笘居 高明  東北大学, 多元物質科学研究所, 講師 (80583351)
Research Collaborator KITADA Yuta  東北大学, 環境科学研究科
SAITO Hayate  東北大学, 環境科学研究科
HANZAWA Kazuki  東北大学, 環境科学研究科
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords電池 / 有機活物質 / 結晶成長 / キャパシタ / エネルギー / 結晶工学 / ナノ材料 / 有機結晶
Outline of Final Research Achievements

Organic materials has attracted much attention as the electrodes in low-cost, environmentally-friendly and high-energy-density batteries. In this study, we analyzed the crystal structural change in organic electrode, and revealed that the crystal growth of organic compound during charge-discharge cycling can become a dominant mechanism of battery degradation. To avoid the organic crystal growth, the control of interface between electrode and electrolyte was effective. Moreover, by applying the organic active materials to electrochemical flow capacitor, the capacitance enhancement was achieved.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (11 results)

All 2017 2016 2015

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results)

  • [Journal Article] High-energy-density electrochemical flow capacitors containing quinone derivatives impregnated in nanoporous carbon beads2017

    • Author(s)
      Takaaki Tomai, Hayate Saito, Itaru Honma
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 5 Issue: 5 Pages: 2188-2194

    • DOI

      10.1039/c6ta08733g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] キノン系有機活物質を用いた高エネルギー密度型電気化学フローキャパシタの開発2016

    • Author(s)
      斎藤颯,笘居高明,本間格
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ 国際会議場 (千葉県、千葉市)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] Capacitance Enhancement based on combination of quinone derivatives with nanoporous carbon for Electrochemical Flow Capacitor2016

    • Author(s)
      Takaaki Tomai, Hayate Saito, Itaru Honma
    • Organizer
      2016 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Capacity Enhancement of Electrochemical Flow Capacitor Using Quinonic Compounds Couple2016

    • Author(s)
      Hayate Saito, Takaaki Tomai, Itaru Honma
    • Organizer
      PRiME 2016
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Improvement in cycling stability of aqueous organic redox capacitor via interface control2016

    • Author(s)
      Kazuki Hanzawa, Hayate Saito, Takaaki Tomai, Itaru Honma
    • Organizer
      PRiME 2016
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-energy-density proton redox capacitor using quinonic compounds couple2015

    • Author(s)
      Takaaki Tomai,Daiki Komatsu,Itaru Honma
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Degradation mechanism of quinone-based organic electrode in aqueous redox capacitor2015

    • Author(s)
      Takaaki Tomai, Hiroshi Hyodo, Daiki Komatsu, Itaru Honma
    • Organizer
      Frontier 2015
    • Place of Presentation
      Tohoku University
    • Year and Date
      2015-11-30
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] A metal-free organic crystalline electrode for high energy density batteries2015

    • Author(s)
      Itaru Honma
    • Organizer
      International Conference “Global/Local Innovations for Next Generation Automobiles”
    • Place of Presentation
      Sendai International Center
    • Year and Date
      2015-10-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] X-ray spectroscopic analysis of electronic states on quinone-based cathode materials for Li-ion batteries2015

    • Author(s)
      Yuta Kitada, Naoka Nagamura, Ryosuke Taniki and Itaru Honma
    • Organizer
      66th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Capacity enhancement of semi-solid flow capacitor using quinonic compounds2015

    • Author(s)
      Hayate Saito, Daiki Komatsu, Takaaki Tomai and Itaru Honma
    • Organizer
      66th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] キノン系有機材料を用いたセミソリッドフロー電池の開発2015

    • Author(s)
      斎藤颯、兵藤宏、笘居高明、本間格
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(札幌キャンパス)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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