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The graphene/silicon photoelectrode for solar energy conversion systems

Research Project

Project/Area Number 15K14161
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionKyoto University

Principal Investigator

Sugimura Hiroyuki  京都大学, 工学(系)研究科(研究院), 教授 (10293656)

Co-Investigator(Kenkyū-buntansha) UTSUNOMIYA TORU  京都大学, 大学院工学研究科, 助教 (70734979)
Project Period (FY) 2015-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywordsグラフェン / 光電気化学 / シリコン / 表面処理 / 2次元材料 / 光水素発生反応 / 電気化学 / 半導体電極 / 酸化防止膜 / 表面修飾
Outline of Final Research Achievements

We immobilized the graphene derivatives, Graphene Oxide (GO), on the hydrogen-terminated Si(111) surface. Because of the gas barrier properties, the immobilized sheets are expected to be the protective coating against the surface oxidation, which forms the insulating silicon oxide layer. In this study, we studied graphene derivatives/Si interfaces by using X-ray photoelectron spectroscopy, atomic force microscopy, and electrochemical measurements. The preserved conductivity and electrochemical properties clearly showed the barrier properties of the sheet against oxidation.

Report

(2 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • Research Products

    (8 results)

All 2016 2015

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (6 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Photochemical Preparation of Alkoxy Self-Assembled Monolayers on Si from 1,2-Epoxyalkane Molecules2016

    • Author(s)
      Ahmed I. A. Soliman, Sho Kokufu, Toru Utsunomiya, Takashi Ichii, and Hiroyuki Sugimura
    • Journal Title

      Chemistry Letters

      Volume: - Issue: 5 Pages: 561-563

    • DOI

      10.1246/cl.160064

    • NAID

      130005150475

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Vacuum-ultraviolet promoted oxidative micro photoetching of graphene oxide2016

    • Author(s)
      Yudi Tu, Toru Utsunomiya, Takashi Ichii, and Hiroyuki Sugimura
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: - Issue: 16 Pages: 10627-10635

    • DOI

      10.1021/acsami.6b00994

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] グラフェン誘導体被覆シリコン電極の電子移動特性2016

    • Author(s)
      國府 翔,宇都宮 徹,曽我 正寛,寶 雄也,一井 崇,杉村 博之
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水素終端化シリコンへの酸化グラフェンの固定化による高潤滑表面の作製2016

    • Author(s)
      國府 翔, Harshal P. Mungse, 宇都宮 徹, 一井 崇, Om P. Khatri, 杉村 博之
    • Organizer
      表面技術協会 第133回講演大会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Year and Date
      2016-03-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Immobilization and photoreduction of graphene oxide on hydrogen–terminated silicon2015

    • Author(s)
      Sho Kokufu, Yudi Tu, Takashi Ichii, Toru Utsunomiya, Hiroyuki Sugimura
    • Organizer
      THE INTERNATIONAL CHEMICAL CONGRESS OF PACIFIC BASIN SOCIETIES 2015
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水素終端化シリコン基板と酸化グラフェンの界面化学反応と電子移動特性2015

    • Author(s)
      國府 翔,屠 宇迪,一井 崇,宇都宮 徹,杉村 博之
    • Organizer
      平成27年度 第3回 材料化学研究会・鉄鋼プロセス研究会 合同研究会
    • Place of Presentation
      大阪府立大学(大阪府大阪市)
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 酸化グラフェンの水素終端化シリコン基板への固定化とその光電極特性2015

    • Author(s)
      國府 翔,屠 宇迪,一井 崇,宇都宮 徹,杉村 博之
    • Organizer
      2015年電気化学秋期大会
    • Place of Presentation
      埼玉工業大学(埼玉県深谷市)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Photochemical Immobilization of Graphene Oxide onto Hydrogen Terminated Silicon2015

    • Author(s)
      Yudi Tu, Sho Kokufu, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      13th European Conference on Molecular Electronics
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2015-09-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2017-05-10  

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