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Development of High Performance Mg2Ni Hydrogen Storage Alloy with Nano-Grained Structure

Research Project

Project/Area Number 15K14183
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Material processing/Microstructural control engineering
Research InstitutionKyushu University

Principal Investigator

Horita Zenji  九州大学, 工学研究院, 教授 (20173643)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords水素貯蔵合金 / Mg合金 / 超微細結晶粒 / 巨大ひずみ加工 / 結晶粒界 / 巨大ひずみ / 高圧ねじり加工 / 水素結合エネルギー / 格子欠陥 / 積層欠陥 / 結晶・組織制御
Outline of Final Research Achievements

Mg alloys were processed by high-pressure torsion so that the grain refinement occurred to the nanosize. Hydrogen absorption became feasible at 423 K with faster hydrogen kinetics. This was due to the introduction of high densities of planar lattice defects such as grain boundaries and stacking faults. High rotation numbers of HPT processing for an MgZr alloy led to atomic order mixture of the elements and it was possible to absorb ~1 wt.% of hydrogen under 9 MPa in ~20 s at room temperature and fully desorb the hydrogen in the air. Two Mg alloys, Mg4NiPd and Mg4NiSn of which compositions were determined based on binding energy engineering, were also processed by HPT. Hydrogen absorption of 1.3% and 0.4%, respectively, was achieved after short time exposure to hydrogen atmosphere at 353 K.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (42 results)

All 2017 2016 2015 Other

All Int'l Joint Research (1 results) Journal Article (13 results) (of which Int'l Joint Research: 11 results,  Peer Reviewed: 13 results,  Open Access: 9 results,  Acknowledgement Compliant: 9 results) Presentation (19 results) (of which Int'l Joint Research: 11 results,  Invited: 12 results) Book (2 results) Remarks (2 results) Patent(Industrial Property Rights) (3 results) Funded Workshop (2 results)

  • [Int'l Joint Research] アリゾナ州立大学(米国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Hydrogen diffusion in ultrafine-grained iron with the body-centered cubic crystal structure2017

    • Author(s)
      Hideaki Iwaoka, Makoto Arita, Zenji Horita
    • Journal Title

      Philosophical Magazine Letters

      Volume: 97 Issue: 4 Pages: 158-168

    • DOI

      10.1080/09500839.2017.1300702

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Hydrogen generation from pure water using Al-Sn powders consolidated through high-pressure torsion2016

    • Author(s)
      F. Zhang, R. Yonemoto, M. Arita, Z. Horita
    • Journal Title

      Journal of Materials Reseach

      Volume: 31 Issue: 6 Pages: 775-782

    • DOI

      10.1557/jmr.2016.74

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Activation of titanium-vanadium alloy for hydrogen storage by introduction of nanograins and edge dislocations using high-pressure torsion2016

    • Author(s)
      K. Edalati, H. Shao, H. Emami, H. Iwaoka, E. Akiba, Z. Horita
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 41 Issue: 21 Pages: 8917-8924

    • DOI

      10.1016/j.ijhydene.2016.03.146

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Impact of severe plastic deformation on microstructure and hydrogen storage of titanium-iron-manganese intermetallics2016

    • Author(s)
      K. Edalati, M. Matsuo, H. Emami, S. Itano, A. Alhamidi, A. Staykov, D.J. Smith, S. Orimo, E. Akiba, Z. Horita
    • Journal Title

      Scripta Materialia

      Volume: 124 Pages: 108-111

    • DOI

      10.1016/j.scriptamat.2016.07.007

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Scaling up of High-Pressure Sliding (HPS)for Grain Refinement and Superplasticity2016

    • Author(s)
      Y. Takizawa, T. Masuda, K. Fujimitsu, T. Kajita, K. Watanabe, M. Yumoto, Y. Otagiri, Z. Horita
    • Journal Title

      Metallurgical and Materials Transactions A

      Volume: 47 Issue: 9 Pages: 4669-4681

    • DOI

      10.1007/s11661-016-3623-3

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Plastic Strain and Grain Size Effect on Phase Transformations in TiO2 Ceramics Processed by high-pressure Torsion2016

    • Author(s)
      H. Razavi-Khosroshahi, K. Edalati, M. Arita, Z. Horita, M. Fuji
    • Journal Title

      Scripta Materialia

      Volume: 124 Pages: 59-62

    • DOI

      10.1016/j.scriptamat.2016.06.022

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Visible-Light-Driven Photocatalytic Hydrogen Generation on Nanosized TiO2-II Stabilized by High-Pressure Torsion2016

    • Author(s)
      Hadi Razavi-Khosroshahi, Kaveh Edalati, Masashige Hirayama, Hoda Emami, Makoto Arita, Miho Yamauchi, Hidehisa Hagiwara, Shintaro Ida,Tatsumi Ishihara, Etsuo Akiba, Zenji Horita, and Masayoshi Fuji
    • Journal Title

      ACS Catalysis

      Volume: 6 Issue: 8 Pages: 5103-5107

    • DOI

      10.1021/acscatal.6b01482

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Fundamentals of Superior Properties in Bulk NanoSPD Materials2016

    • Author(s)
      R.Z. Valiev, Y. Estrin, Z. Horita, T.G. Langdon, M.J. Zehetbauer and Y.T. Zhu
    • Journal Title

      Material Research Letters

      Volume: 4 Issue: 1 Pages: 1-21

    • DOI

      10.1080/21663831.2015.1060543

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Solid-state reactions and hydrogen storage in magnesium mixed with various elements by high-pressure torsion: experiments and first-principles calculations2016

    • Author(s)
      H. Emami, K. Edalati, A. Staykov, T. Hongo, H. Iwaoka, Z. Horita, E. Akiba
    • Journal Title

      Royal Society of Chemistry (RCS) Advances

      Volume: 6 Issue: 14 Pages: 11665-11674

    • DOI

      10.1039/c5ra23728a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Producing Bulk Ultrafine-Grained Materials by Severe Plastic Deformation: Ten Years Later2016

    • Author(s)
      R.Z. Valiev, Y. Estrin, Z. Horita, T.G. Langdon, M.J. Zehetbauer, Y.T. Zhu
    • Journal Title

      JOM

      Volume: 68 Issue: 4 Pages: 1216-1226

    • DOI

      10.1007/s11837-016-1820-6

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Significance of grain boundaries and stacking faults on hydrogen storage properties of Mg2Ni intermetallics processed by high-pressure torsion2015

    • Author(s)
      K. Edalati, J. Matsuda, M. Arita, T. Daio, E. Akiba, Z. Horita
    • Journal Title

      Acta Materialia

      Volume: 92 Pages: 46-54

    • DOI

      10.1016/j.actamat.2015.03.036

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Formation of Metastable Phases in Magnesium-Titanium System by High-Pressure Torsion and Their Hydrogen Storage Performance2015

    • Author(s)
      K. Edalati, H. Emami, A. Staykov, D. J. Smith, E. Akiba, Z. Horita
    • Journal Title

      Acta Materialia

      Volume: 99 Pages: 150-156

    • DOI

      10.1016/j.actamat.2015.07.060

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] New Nanostructured Phases with Reversible Hydrogen Storage Capability in Immiscible Magnesium-Zirconium System Produced by High-Pressure Torsion2015

    • Author(s)
      K. Edalati, H. Emami, Y. Ikeda, H. Iwaoka, Isao Tanaka, E. Akiba, Z. Horita
    • Journal Title

      Acta Materialia

      Volume: 108 Pages: 293-303

    • DOI

      10.1016/j.actamat.2016.02.026

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Upsizing of Severe Plastic Deformation Process under High Pressure2017

    • Author(s)
      Zenji Horita
    • Organizer
      7th Latin American Conference on Metastable and Nanostructured Materials (NANOMAT 2017)
    • Place of Presentation
      Brotas, SP, Brazil
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 巨大ひずみ加工による多機能性合金の開発2017

    • Author(s)
      堀田善治
    • Organizer
      日本金属学会2017年春期(第160回)講演大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Severe Plastic Deformation under High Pressure: Scaling-up of high-pressure sliding for grain refinement and enhanced mechanical properties2016

    • Author(s)
      Yoichi Takizawa, Takahiro Masuda, Kazushige Fujimitsu, Takahiro Kajita, Kyohei Watanabe, Manabu Yumoto, Yoshiharu Odagiri, Zenji Horita
    • Organizer
      Engineering Mechanics Institute Conference (2016EMI-IC)
    • Place of Presentation
      Metz, France
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 巨大ひずみ加工による材料改質と高性能化に関する研究2016

    • Author(s)
      堀田善治
    • Organizer
      日本金属学会2016年秋期(第159回)講演大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Role of Grain Boundary for Hydrogen Diffusion in FCC-Pd and BCC-Fe2016

    • Author(s)
      Hideaki Iwaoka, Makoto Arita, Zenji Horita
    • Organizer
      2016 International Hydrogen Conference
    • Place of Presentation
      Grand Teton Lodge, Moran, WY, USA
    • Year and Date
      2016-09-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Scaling up of high-pressure torsion and production of superplastic Mg alloys2016

    • Author(s)
      Takahiro Masuda and Zenji Horita
    • Organizer
      The 9th Pacific Rim International Conference on Advanced Materials and Processing (PRICM-9)
    • Place of Presentation
      Kyoto International Conference Center
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen storage performance of TiFe-based compounds processed by HPT2016

    • Author(s)
      Kaveh EDALATI, Motoaki MATSUO, Hoda EMAMI, Shota ITANO, Ali ALHAMIDI, Aleksandar STAYKOV, David J. SMITH, Shin-ichi ORIMO, Etsuo AKIBA, Zenji HORITA
    • Organizer
      The 9th Pacific Rim International Conference on Advanced Materials and Processing (PRICM-9)
    • Place of Presentation
      Kyoto International Conference Center
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Severe plastic deformation under high pressure for enhanced mechanical and functional properties2016

    • Author(s)
      Zenji Horita
    • Organizer
      2016 Nanomaterials Workshop
    • Place of Presentation
      Nanjing University of Science and Technology, Nanjing, China
    • Year and Date
      2016-06-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Influence of HPT on Hydrogen Storage Performance of TiFe-Mn Compounds2016

    • Author(s)
      Kaveh Edalati, Motoaki Matsuo, Hoda Emami, Ali Alhamidi, Aleksandar Staykov, David J. Smith, Shin-ichi Orimo, Etsuo Akiba, Zenji Horita
    • Organizer
      日本金属学会2016年春期(第158回)講演大会
    • Place of Presentation
      東京理科大学 葛飾キャンパス
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report
  • [Presentation] Development of New Mg4NiPd Hydrogen Storage Materials Using High-Pressure Torsion Method2016

    • Author(s)
      植弘量子, Kaveh Edalati, Hoda Emami, Hai-Wen Li, 有田誠, 秋葉悦男, 堀田善治
    • Organizer
      日本金属学会2016年春期(第158回)講演大会
    • Place of Presentation
      東京理科大学 葛飾キャンパス
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report
  • [Presentation] 巨大ひずみ加工による 材料の高性能化2016

    • Author(s)
      堀田善治
    • Organizer
      第48回材料研究会研究発表会
    • Place of Presentation
      富山大学工学部
    • Year and Date
      2016-02-09
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Hydrogen storage materials for energy saving and low CO2 emission: microstructural refinement by HPT for high performance2016

    • Author(s)
      Zenji Horita
    • Organizer
      International Symposium, Energies marines
    • Place of Presentation
      Caen, France
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 巨大ひずみ加工を利用した材料組織制御と高機能化2016

    • Author(s)
      堀田善治
    • Organizer
      SPring-8シンポジウム2016
    • Place of Presentation
      関西学院大学 神戸三田キャンパス
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Production of high-performance hydrogen storage materials using process of severe plastic deformation under high pressure2016

    • Author(s)
      Zenji Horita
    • Organizer
      9 th NATIONAL SEMINAR OF METALLURGY AND MATERIALS (SENAMM IX)
    • Place of Presentation
      University of Sultan Ageng Tirtayasa, Indonesia.
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 巨大ひずみ加工を利用した水素貯蔵特性の向上2015

    • Author(s)
      堀田 善治
    • Organizer
      日本金属学会2015年秋期講演大会
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Potential of Metastable Mg-Ti Phases Produced by HPT for Hydrogen Storage2015

    • Author(s)
      Kaveh Edalati, Aleksandar Staykov, David J.Smith, Etsuo Akiba, Zenji Horita
    • Organizer
      2015 Fall Annual (157th) Meeting, JIM
    • Place of Presentation
      Kyushu University Ito Campus
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Severe plastic deformation under high pressure for enhanced performance of bulk nanomaterials: Introduction of International Research Center2015

    • Author(s)
      Zenji Horita
    • Organizer
      International Workshop of Giant Straining Process for Advanced Materials in 2015 (GSAM2015)
    • Place of Presentation
      Dai-hakata Bldg. Room 1204, Fukuoka
    • Year and Date
      2015-09-03
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Developing High-Performance Structural and Functional Materials Using Severe Plastic Deformation under High Pressure2015

    • Author(s)
      Zenji Horita
    • Organizer
      International Materials Research Congress (IMRC)
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2015-08-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Production of Mg-Ti alloys by HPT for hydrogen storage2015

    • Author(s)
      Kaveh Edalati, Hoda Emami, Aleksander Staykov, David J Smith, 秋葉 悦男, 堀田 善治
    • Organizer
      日本金属学会九州支部・日本鉄鋼協会九州支部・軽金属学会九州支部・北九州市 共催 平成27年度合同学術講演会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2015-06-06
    • Related Report
      2015 Research-status Report
  • [Book] Promoting Functionality by Severe Plastic Deformation Significance of Lattice Defects and Phase Transformation2016

    • Author(s)
      Kaveh Edalati, Yoshifumi Ikoma and Zenji Horita
    • Total Pages
      80
    • Publisher
      IRC-GSAM, Kyushu University
    • Related Report
      2016 Annual Research Report
  • [Book] Proceedings of the International Workshop on Giant Straining Process for Advanced Materials (GSAM2015) “Exploring SPD Potential: Innovative Approach for Production of High-Performance Materials”2016

    • Author(s)
      Kaveh Edalati, Yoshifumi Ikoma and Zenji Horita
    • Total Pages
      71
    • Publisher
      IRC-GSAM Press, Fukuoka
    • Related Report
      2015 Research-status Report
  • [Remarks] 堀田研究室ホームページ

    • URL

      http://zaiko6.zaiko.kyushu-u.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 九州大学巨大ひずみマテリアル国際研究センター

    • URL

      http://irc-gsam.kyushu-u.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 相当ひずみ付与材料の作製方法2016

    • Inventor(s)
      小田切吉治、瀧沢陽一、湯本学、堀田善治
    • Industrial Property Rights Holder
      小田切吉治、瀧沢陽一、湯本学、堀田善治
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-15
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 相当ひずみ付与装置2016

    • Inventor(s)
      小田切吉治、瀧沢陽一、湯本学、堀田善治
    • Industrial Property Rights Holder
      小田切吉治、瀧沢陽一、湯本学、堀田善治
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-15
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 水素分離膜の製造方法及び水素分離膜2016

    • Inventor(s)
      松本佳久、岩岡秀明、有田誠、堀田善治
    • Industrial Property Rights Holder
      松本佳久、岩岡秀明、有田誠、堀田善治
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-03-30
    • Related Report
      2015 Research-status Report
  • [Funded Workshop] International Workshop on Giant Straining Process for Advanced Materials in 2016 (GSAM2016)2016

    • Place of Presentation
      Dai-hakata Bldg. Room 1107, Fukuoka
    • Year and Date
      2016-07-28
    • Related Report
      2016 Annual Research Report
  • [Funded Workshop] International Workshop of Giant Straining Process for Advanced Materials in 2015 (GSAM2015)2015

    • Place of Presentation
      Dai-hakata Bldg. Room 1204, Fukuoka
    • Year and Date
      2015-09-03
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2022-01-27  

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