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Photochemical Morphology Control of Metal Nanoparticles Based on Their Plasmonic Absorption

Research Project

Project/Area Number 15K14203
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionOsaka University

Principal Investigator

Hirai Takayuki  大阪大学, 太陽エネルギー化学研究センター, 教授 (80208800)

Co-Investigator(Kenkyū-buntansha) 白石 康浩  大阪大学, 太陽エネルギー化学研究センター, 准教授 (70343259)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords金属ナノ粒子 / プラズモン / 光化学 / 調製 / サイズ制御 / モルフォロジー / 液相合成 / 金 / フォトクロミック分子 / 光化学反応
Outline of Final Research Achievements

We have studied a new method for preparation of metal nanoparticles such as gold, silver, and copper by “light”. We successfully developed a new method consisting of photoirradiation of water containing metal precursors and photoresponsive reducing agent. In that, the added reducing agent behaves as a surface stabilizing agent that suppresses aggregation of the formed metal nanoparticles. The proposed method facilitates the formation of metal nanoparticles with tunable sizes and narrow size distributions.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (8 results)

All 2017 2016 2015 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (4 results) Remarks (2 results)

  • [Journal Article] Photoreductive Synthesis of Monodispersed Au Nanoparticles with Citric Acid as Reductant and Surface Stabilizing Reagent2017

    • Author(s)
      Yasuhiro Shiraishi, Haruki Tanaka, Hirokatsu Sakamoto, Satoshi Ichikawa, and Takayuki Hirai
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 11 Pages: 6187-6192

    • DOI

      10.1039/c6ra27771c

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Amino-Substituted Spirothiopyran as an Initiator for Self-Assembly of Gold Nanoparticles2015

    • Author(s)
      Yasuhiro Shiraishi, Haruki Tanaka, Hirokatsu Sakamoto, Satoshi Ichikawa, and Takayuki Hirai
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 95 Pages: 77572-77580

    • DOI

      10.1039/c5ra14752b

    • Related Report
      2015 Research-status Report
  • [Presentation] 安息香酸を触媒および安定化剤とする単分散金ナノ粒子の光化学的合成2017

    • Author(s)
      田中悠幹、白石康浩、平井隆之
    • Organizer
      第97回日本化学会春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] クエン酸光還元法による単分散金ナノ粒子の室温合成2016

    • Author(s)
      田中悠幹、白石康浩、平井隆之
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学(東京都目黒区)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] アミノ基修飾スピロチオピランによる金ナノ粒子の凝集制御2016

    • Author(s)
      田中悠幹、白石康浩、平井隆之
    • Organizer
      第96回日本化学会春季年会
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパス
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] アミノ基修飾スピロチオピランによる金ナノ粒子の凝集制御2015

    • Author(s)
      田中悠幹、白石康浩、平井隆之
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Remarks] 大阪大学太陽エネルギー化学研究センター平井研究室ホームページ

    • URL

      http://www.cheng.es.osaka-u.ac.jp/hirailab/home.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 大阪大学太陽エネルギー化学研究センター平井研究室

    • URL

      http://www.cheng.es.osaka-u.ac.jp/hirailab/home.html

    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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