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Upgrading of low-rank coal via deoxygenation and recovery of aromatic chemicals

Research Project

Project/Area Number 15K14218
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionHokkaido University

Principal Investigator

Masuda Takao  北海道大学, 工学研究院, 教授 (20165715)

Co-Investigator(Kenkyū-buntansha) 中坂 佑太  北海道大学, 工学研究院, 助教 (30629548)
吉川 琢也  北海道大学, 工学研究院, 助教 (20713267)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords化学工学 / 資源化学プロセス / 化石燃料有効利用技術
Outline of Final Research Achievements

In this study, we investigated two-step process for converting low-rank coal into high-rank coal and recovering aromatic compounds. Regarding to the upgrading of low-rank coal (1st step), non-polar solvent such as toluene was found to be appropriate for co-solvent of water. We examined the effect of reaction conditions and succeeded in producing bituminous-like coal with a high yield at 350 degree C for 2 hour. Next, brown coal-derived organic phase was employed in the reaction over iron oxide-based catalyst. Depolymerization of brown coal-derived compounds proceeded, and aromatic compounds increased after the reaction. Moreover, this process was applied to peat under optimal conditions, resulting in the conversion into sub-bituminous-like coal.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (4 results)

All 2016

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (3 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] The effects of H2O addition on oil sand bitumen cracking using a CeO2-ZrO2-Al2O3-FeOX catalyst2016

    • Author(s)
      Hisaki Kondoh, Natsumi Hasegawa, Takuya Yoshikawa, Yuta Nakasaka, Teruoki Tago, Takao Masuda
    • Journal Title

      Energy & Fuels

      Volume: 30 Issue: 12 Pages: 10358-10364

    • DOI

      10.1021/acs.energyfuels.6b02428

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] 重質油のアップグレーディングにおけるTiO2-ZrO2触媒への添加成分の効果2016

    • Author(s)
      長谷川夏未、近藤永樹、吉川琢也、中坂佑太、多湖輝興、増田隆夫
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学(岩手)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Role of H2O addition on heavy oil cracking using iron oxide-based catalyst2016

    • Author(s)
      Hisaki Kondoh, Natsumi Hasegawa, Takuya Yoshikawa, Yuta Nakasaka, Teruoki Tago, Takao Masuda
    • Organizer
      9th International Conference on Environmental Catalysis
    • Place of Presentation
      Newcastle(Australia)
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水/有機溶媒による褐炭の改質及び有用化学物質製造2016

    • Author(s)
      鈴木健太、中坂佑太、吉川琢也、多湖輝興、増田隆夫
    • Organizer
      化学系学協会北海道支部2016年冬季研究発表会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2016-01-19
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-12-17  

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