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Solid catalysts for highly selective conversions of next generation biomass resources

Research Project

Project/Area Number 15K14224
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionKochi University

Principal Investigator

Onda Ayumu  高知大学, 教育研究部総合科学系複合領域科学部門, 講師 (80335918)

Co-Investigator(Kenkyū-buntansha) 平岡 雅規  高知大学, 教育研究部総合科学系黒潮圏科学部門, 准教授 (30380306)
椿 俊太郎  東京工業大学, 物質理工学院, 助教 (90595878)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords多糖 / 加水分解 / 固体酸触媒 / 海藻 / ウルバン / ラムノース / バイオマス / 海藻固有多糖 / 固体酸 / 触媒 / 水熱反応
Outline of Final Research Achievements

Ulvan, a sulfated glucuronorhamnan polysaccharide extracted from Ulva spp. green macroalgae, is selectively hydrolyzed to monosaccharides, such as rhamnose, over solid acid catalysts under mild hydrothermal conditions at approximately 403K. The order of the catalytic activities of the solid-acid catalysts depends on the kinds of polysaccharides.
Ulvan is selectively hydrolyzed to monosaccharides over solid acid catalysts under mild conditions.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (15 results)

All 2017 2016 2015

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 2 results) Book (1 results)

  • [Journal Article] Catalytic hydrolysis of polysaccharides derived from fast growing green macroalgae2017

    • Author(s)
      Onda, A., Onda, S., Koike, M., Yanagisawa, K., Tsubaki, S., Hiraoka, M.
    • Journal Title

      ChemCatChem

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Microwave-assisted hydrolysis of biomass over activated carbon supported polyoxometalates2017

    • Author(s)
      Tsubaki, S., Oono, K., Onda, A., Ueda, T., Mitani, T., Hiraoka, M.
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 20 Pages: 12346-12350

    • DOI

      10.1039/c6ra28778f

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One pot direct catalytic conversion of cellulose to C3 and C4 hydrocarbons using Pt/H-USY zeolite catalyst at low temperature2016

    • Author(s)
      S. Ogo, T. Nishio, H. Sekine, A. Onda, Yasushi Sekine
    • Journal Title

      Fuel Processing Technology

      Volume: 141 Pages: 123-129

    • DOI

      10.1016/j.fuproc.2015.06.032

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of ionic conduction on hydrothermal hydrolysis of corn starch and crystalline cellulose induced by microwave irradiation2016

    • Author(s)
      S. Tsubaki, K. Oono, A. Onda, K. Yanagisawa, T. Mitani, J. Azuma
    • Journal Title

      Carbohydrate Polymers

      Volume: 137 Pages: 594-599

    • DOI

      10.1016/j.carbpol.2015.11.022

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Microwave-assisted hydrothermal extraction of sulfated polysaccharides from Ulva spp. and Monostroma latissimum2016

    • Author(s)
      S. Tsubaki, K. Oono, A. Onda, T. Mitani
    • Journal Title

      Food Chemistry

      Volume: 210 Pages: 311-316

    • DOI

      10.1016/j.foodchem.2016.04.121

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 様々な多糖の加水分解におけるスルホン化活性炭触媒とアンバーリスト触媒の活性比較2016

    • Author(s)
      坂本友樹, 恩田歩武, 今村和也, 柳澤和道
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      高松
    • Year and Date
      2016-11-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] 海藻多糖から有用化合物への水熱変換プロセスの開発2016

    • Author(s)
      小池美雪, 恩田歩武, 今村和也, 柳澤和道
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      高松
    • Year and Date
      2016-11-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] 担持ポリオキソメタレート触媒を用いた糖変換2016

    • Author(s)
      恩田歩武, 恩田さゆり, 上田忠治, 今村和也, 柳澤和道
    • Organizer
      第118回触媒学会討論会
    • Place of Presentation
      盛岡
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Catalytic hydrolysis of polysaccharides derived from macroalgae, International Symposium on Catalytic Conversions of Biomass2016

    • Author(s)
      Onda, A., Tsubaki, S., Masanori, M.
    • Organizer
      International Symposium on Catalytic Conversions of Biomass (ISCCB2016)
    • Place of Presentation
      Taipei
    • Year and Date
      2016-06-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 海藻多糖の加水分解に対する固体酸触媒作用2016

    • Author(s)
      恩田歩武, 恩田さゆり, 小池美雪, 柳澤和道, 椿俊太郎, 平岡雅規
    • Organizer
      第117回触媒討論会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] マイクロ波により活性化される固体触媒を用いたバイオマスの加水分解2016

    • Author(s)
      椿俊太郎, 恩田歩武, 上田忠治, 三谷友彦, 米谷真人, 鈴木榮一, 和田雄二
    • Organizer
      第117回触媒討論会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Application of microwave induced reaction on biomass conversion2015

    • Author(s)
      Tsubaki, S., Hiraoka, M., Onda, A., Ueda, T.
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ハワイ
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 海藻多糖ウルバンから単糖への選択的加水分解2015

    • Author(s)
      恩田歩武, 恩田さゆり, 椿俊太郎, 平岡雅規
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学(三重県)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 海藻多糖の触媒水熱法による加水分解2015

    • Author(s)
      恩田歩武, 恩田さゆり, 椿 俊太郎, 平岡雅規
    • Organizer
      第64回石油学会研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report
  • [Book] “Production of Platform Chemicals from Sustainable Resources, Chapter 7: Production of Glucaric/Gluconic Acid from Biomass by Chemical Processes using Heterogeneous Catalysts”, Ed. Fang, Smith and Qi2017

    • Author(s)
      Onda, A
    • Total Pages
      24
    • Publisher
      Springer Nature Singapore Pte Ltd.
    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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