Design and synthesis of concerted supported molecular catalysts by precise living polymerization
| Project/Area Number |
15K14225
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 触媒設計 / 精密重合 / 遷移金属錯体触媒 / 環境調和型合成法 / 固定化分子触媒 / リビング重合 / 触媒・化学プロセス / 協奏機能触媒 / 触媒反応 / 合成化学 |
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| Outline of Final Research Achievements |
The project concern design of concerted reaction sphere by placement of different functionalities on the surface of star-shaped polymers prepared by the living polymerization technique. We have succeeded in controlled synthesis of star-shaped polymers with more arms (branching) and the exclusive end modification under optimized conditions by adopting living ring-opening metathesis polymerization using molybdenum-alkylidene catalyst. The method enables us introduction of different ligand precursors on the star surface as well as synthesis of functional materials by intra-molecular interaction with two different functionalities on the surface.
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Report
(4 results)
Research Products
(18 results)
