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Synthesis and fabrication of biotemplated lithium ion sieve

Research Project

Project/Area Number 15K14275
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Earth system and resources engineering
Research InstitutionKyushu University

Principal Investigator

SASAKI Keiko  九州大学, 工学研究院, 教授 (30311525)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywordslithium ion sieve / lithium / adsorption / biomineralization / manganese oxides / geothermal waters / lithium ions / 生体鉱物 / リチウムイオンシーブ / イオン交換 / 集積化
Outline of Final Research Achievements

Optimizing the calcination of biomineralized manganese oxides, biotemplated lithium ion sieve was successfully synthesized, which has the maximum adsorption capacity of 14.7 mg-Li/g-MnOx. Fabrication of powdery biotemplated lithium ion sieve in alginate beads improved the handleability. After fabrication, the maximum adsorption capacity and recycability were still maintained, although the adsorption kinetics decreased. Fabrication of powdery biotemplated lithium ion sieve in alginate beads largely contributed to separation and recovery of lithium from natural waters including geothermal and sea waters.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (16 results)

All 2017 2016 2015 Other

All Int'l Joint Research (5 results) Journal Article (7 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 7 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (2 results) (of which Int'l Joint Research: 2 results) Book (1 results) Remarks (1 results)

  • [Int'l Joint Research] Madidol University(Thailand)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Virginia Tech(米国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] China University of Geoscience(China)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] マヒドン大学(タイ)

    • Related Report
      2015 Research-status Report
  • [Int'l Joint Research] バージニア州立大学(米国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Simultaneous Determination of Manganese Peroxidase and Lignin Peroxidase by Capillary Electrophoresis Enzyme Assays2017

    • Author(s)
      Sumire Kudo, Airi Harada, Hiroe Kubota, Keiko Sasaki, Takashi Kaneta
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 10 Pages: 7329-7333

    • DOI

      10.1021/acsomega.7b00998

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Bio-modification of carbonaceous matter in gold ores: Model experiments using powdered activated carbon and cell-free spent medium of Phanerochaete chrysosporium2017

    • Author(s)
      Konadu Kojo T.、Sasaki Keiko、Kaneta Takashi、Ofori-Sarpong Grace、Osseo-Asare Kwadwo
    • Journal Title

      Hydrometallurgy

      Volume: 168 Pages: 76-83

    • DOI

      10.1016/j.hydromet.2016.08.003

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of lignin-degrading enzymes on the decomposition of large aromatic hydrocarbons: Coronene as a surrogate for powdered activated carbon2017

    • Author(s)
      Kojo Twum Konadu, Keiko Sasaki , Kwadwo Osseo-Asare , Takashi Kaneta
    • Journal Title

      MRS Advances

      Volume: 2 Pages: 1-7

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enzymatic pre-treatment of carbonaceous matter in preg-robbing gold ores: Effect of ferrous ion additives2017

    • Author(s)
      Kojo T. Konadu, Keiko Sasaki, Kwadwo Osseo-Asare and Takashi Kaneta
    • Journal Title

      Solid State Phenomena

      Volume: 262 Pages: 1-4

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Encapsulation of a powdery spinel-type Li+ ion sieve derived from biogenic manganese oxide in alginate beads2016

    • Author(s)
      P. Koilraj, S.M. Smith, Q. Yu, S. Ulrich, K. Sasaki
    • Journal Title

      Powder Technology

      Volume: 301 Pages: 1201-1207

    • DOI

      10.1016/j.powtec.2016.08.009

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Microwave-assisted synthesis of nanocrystalline lithium-ion sieve from biogenic manganese oxide: Effect of crystalline phase and morphology on the lithium adsorption capacity2016

    • Author(s)
      Qianqian Yu, Keiko Sasaki
    • Journal Title

      Hydrometallurgy

      Volume: 未定 Pages: 118-124

    • DOI

      10.1016/j.hydromet.2015.10.002

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] バイオテンプレートイオンシーブによる模擬地熱水からのリチウムイオン吸着特性の速度論的および熱力学的評価2015

    • Author(s)
      桃木大地、余 茜倩、平島剛、笹木圭子
    • Journal Title

      J. MMIJ

      Volume: 131 Pages: 465-469

    • NAID

      130005085486

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Enzymatic pre-treatment of carbonaceous matter in preg-robbing gold ores: Effect of ferrous ion additives2017

    • Author(s)
      Kojo T. Konadu, Keiko Sasaki, Kwadwo Osseo-Asare and Takashi Kaneta
    • Organizer
      The 22nd International Biohydrometallurgy Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] BIOTEMPLATED SYNTHESIS OF A LITHIUM ION-SIEVE DERIVED FROM BIOGENIC MN OXIDE2016

    • Author(s)
      Qianqian Yu, Keiko Sasaki
    • Organizer
      the 3rd Asian Clay 2016
    • Place of Presentation
      広州
    • Year and Date
      2016-11-18
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Book] Advances in the Environmental Biogeochemistry of Manganese Oxides2015

    • Author(s)
      Keiko Sasaki, Qianqian Yu
    • Total Pages
      14
    • Publisher
      American Chemical Society
    • Related Report
      2015 Research-status Report
  • [Remarks] 九州大学工学府地球資源システム工学専攻 資源処理・環境修復工学研究室

    • URL

      http://process.mine.kyushu-u.ac.jp/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2022-02-16  

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