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Research and Development of Lithium Recovery from Used Li-ion Batteries for Fusion Reactor

Research Project

Project/Area Number 15K14285
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nuclear fusion studies
Research InstitutionNational Institutes for Quantum and Radiological Science and Technology (2016-2017)
Japan Atomic Energy Agency (2015)

Principal Investigator

HOSHINO Tsuyoshi  国立研究開発法人量子科学技術研究開発機構, 六ヶ所核融合研究所 ブランケット研究開発部, 上席研究員(定常) (80370469)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords核融合炉 / トリチウム / リチウム / 分離回収 / 電気透析 / イオン伝導体 / 資源 / 分離膜 / セラミックス
Outline of Final Research Achievements

Fusion reactors need deuterium and tritium as their fuel. Since tritium does not exist in nature, it is necessary to produce tritium in a reactor by neutron irradiation of lithium (Li).
I have developed an innovative method for recycling Li from used Li-ion batteries using the Li ionic conductor. Only Li ions in a solution of used Li-ion batteries permeate during electrodialysis; the other ions, including Co, Al, and F, do not permeate the Li ionic conductor. Li0.29La0.57TiO3 was selected as the Li ionic conductor, and the applied dialysis voltage was 5 V. The Li recovery ratio increased with electrodialysis time.
After electrodialysis, CO2 gas was bubbled in the Li recovery water to produce lithium carbonate (Li2CO3) as a raw material for Li-ion batteries. This new method for recycling Li-ion batteries shows good energy efficiency and is easily scalable. Thus, this electrodialysis method is suitable for the recovery of Li from used Li-ion batteries.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2017 2016 2015

All Journal Article (1 results) Presentation (15 results) (of which Int'l Joint Research: 10 results,  Invited: 9 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] 次世代リチウム資源循環型社会の実現へ -核融合研究の新たなイノベーション-2017

    • Author(s)
      星野 毅
    • Journal Title

      ATOMOΣ 日本原子力学会誌 9月号

      Volume: 59(9) Pages: 16-20

    • NAID

      130007800319

    • Related Report
      2017 Annual Research Report
  • [Presentation] Lithium Recovery from Used Li-ion Batteries using an Innovative Electrodialysis Method with a Lithium Ionic Superconductor2017

    • Author(s)
      T. Hoshino
    • Organizer
      41st International Conference and Exposition on Advanced Ceramics and Composites
    • Place of Presentation
      Daytona Beach(USA)
    • Year and Date
      2017-01-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Innovative Lithium Recovery Technology from Seawater using a Lithium Ionic Superconductor Membrane2017

    • Author(s)
      T. Hoshino
    • Organizer
      EMN Meeting on Membranes
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Lithium Recovery from Used Li-ion Batteries using Innovative Electrodialysis Method with Lithium Ionic Superconductor2017

    • Author(s)
      T. Hoshino
    • Organizer
      231st ECS MEETING
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Innovative Lithium Recycling Technology from Used Li-ion Batteries using a Lithium Ionic Superconductor2017

    • Author(s)
      T. Hoshino
    • Organizer
      EMN Americas Meetings
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Lithium Recovery using Innovative Electrodialysis Method with Lithium Ionic Superconductor for Recycling of Used Li-ion Batteries2016

    • Author(s)
      T. Hoshino
    • Organizer
      67th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Hague(Netherlands)
    • Year and Date
      2016-08-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] リチウム資源循環型社会を目指したイオン伝導体による海水からの新分離技術2016

    • Author(s)
      星野 毅
    • Organizer
      六ヶ所・核燃料サイクルセミナー
    • Place of Presentation
      六ヶ所(日本)
    • Year and Date
      2016-08-05
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Lithium Recovery Technique using an Innovative Electrodialysis Method with a Lithium Ionic Superconductor for Recycling of Used Li-ion Batteries2016

    • Author(s)
      T. Hoshino
    • Organizer
      18th International Meeting on Lithium Batteries
    • Place of Presentation
      Chicago(USA)
    • Year and Date
      2016-06-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 革新的なイオン伝導体を用いた透析法による海水中のリチウム回収技術2016

    • Author(s)
      星野 毅
    • Organizer
      第5回JACI/GSCシンポジウム
    • Place of Presentation
      神戸(日本)
    • Year and Date
      2016-06-03
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 排CO2利用による革新的リチウム資源回収プロセス研究2016

    • Author(s)
      星野 毅
    • Organizer
      第5回新化学技術研究奨励賞
    • Place of Presentation
      東京(日本)
    • Year and Date
      2016-05-27
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Lithium Extraction to Advance the Realization of Nuclear Fusion and E-Mobility2016

    • Author(s)
      T. Hoshino
    • Organizer
      Invited Talk at the Karlsruhe Materials Colloquium
    • Place of Presentation
      Karlsruhe(Germany)
    • Year and Date
      2016-04-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] リチウム資源循環型社会を目指したイオン伝導体による海水からの新分離技術2015

    • Author(s)
      星野 毅
    • Organizer
      日本海水学会 海水資源・環境セミナー
    • Place of Presentation
      千葉工業大学(千葉県・習志野市)
    • Year and Date
      2015-11-13
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] ゼロ・エミッションを目指した発電する海水からの革新的リチウム資源回収2015

    • Author(s)
      星野 毅
    • Organizer
      公益社団法人新化学技術推進協会 エネルギー・資源技術部会 エネルギー分科会 講演会
    • Place of Presentation
      新化学技術推進協会(東京都・千代田区)
    • Year and Date
      2015-10-23
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Development of Lithium Recovery Technique from Seawater by using Innovative Electrodialysis with Lithium Ionic Superconductor2015

    • Author(s)
      Tsuyoshi Hoshino
    • Organizer
      66th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Taipei(Taiwan)
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Lithium Recovery Technique from Seawater by using Innovative Dialysis with Lithium Ionic Superconductor2015

    • Author(s)
      Tsuyoshi Hoshino
    • Organizer
      2nd International Conference on Desalination using Membrane Technology
    • Place of Presentation
      Singapore(Singapore)
    • Year and Date
      2015-07-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Lithium Recovery Technique from Seawater by using Innovative Dialysis with a Lithium Ionic Superconductor2015

    • Author(s)
      Tsuyoshi Hoshino
    • Organizer
      EMN Meeting on Droplets 2015
    • Place of Presentation
      Phuket(Thailand)
    • Year and Date
      2015-05-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Patent(Industrial Property Rights)] リチウム選択透過膜、リチウム回収装置、リチウム回収方法、水素製造方法2017

    • Inventor(s)
      星野 毅
    • Industrial Property Rights Holder
      国立研究開発法人量子科学技術研究開発機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017-01-26
    • Related Report
      2016 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] リチウム選択透過膜、リチウム回収装置、リチウム回収方法、水素製造方法2016

    • Inventor(s)
      星野 毅
    • Industrial Property Rights Holder
      国立研究開発法人日本原子力研究開発機構
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-015423
    • Filing Date
      2016-01-29
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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