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Development of monojunction Cu2O devices for water splitting devices

Research Project

Project/Area Number 15K14299
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

Miyajima Shinsuke  東京工業大学, 工学院, 准教授 (90422526)

Co-Investigator(Kenkyū-buntansha) 宮崎 尚  防衛大学校(総合教育学群、人文社会科学群、応用科学群、電気情報学群及びシステム工学群), 電気情報学群, 助教 (30531991)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
KeywordsCu2O / 電気化学製膜 / 光電変換 / 水分解 / ドーピング / 水素生成 / pn接合
Outline of Final Research Achievements

We investigated properties of Cu2O films for the development of water splitting devices with Cu2O homojunction. Although we investigated the effect of chlorine doping and deposition conditions to prepare n-type Cu2O, we could not realize clear n-type conductivity and homojunciton devices. However, we obtained big progresses in the improvement of p-type Cu2O and the device fabrication. We demonstrated that thermal annealing at 150℃ significantly improves hole mobility of electrochemically deposited p-type Cu2O. By using this p-type Cu2O, we successfully fabricated a ZnO/Cu2O heterojunction device with good long wavelength response.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (11 results)

All 2017 2016 2015

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (8 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Improving Optoelectronic Properties of Electrochemically Deposited Cuprous Oxide Thin-Films by Low-Temperature Post-Deposition Annealing2017

    • Author(s)
      Takiguchi Yuki、Orisaka Aoi、Miyajima Shinsuke
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 164 Issue: 12 Pages: D802-D804

    • DOI

      10.1149/2.0081713jes

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of post-deposition annealing on low temperature metalorganic chemical vapor deposited gallium oxide related materials2016

    • Author(s)
      Yuki Takiguchi, Shinsuke Miyajima
    • Journal Title

      Journal of Crystal Growth

      Volume: NA Pages: 129-134

    • DOI

      10.1016/j.jcrysgro.2016.11.005

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Device simulation of cuprous oxide heterojunction solar cells2016

    • Author(s)
      Yuki Takiguchi, Shinsuke Miyajima
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Issue: 11 Pages: 112303-112303

    • DOI

      10.7567/jjap.54.112303

    • NAID

      210000145823

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] EFFECT OF LOW-TEMPERATURE POST-DEPOSITION ANNEALING2017

    • Author(s)
      Yuki Takiguchi, Aoi Orisaka, Shinsuke Miyajima
    • Organizer
      27th International Photovoltaic Science and Engineering Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 電気化学製膜Cu2O薄膜への製膜後熱処理の効果2017

    • Author(s)
      滝口 雄貴, 折坂 葵, 宮島 晋介
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電気化学製膜Cu2OへのClドーピングの効果2017

    • Author(s)
      折坂 葵, 滝口 雄貴, 宮島 晋介
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Investigation of Optical Confinement Structure for Cu2O Heterojunction Solar Cells Using Two Dimensional Device Simulations2016

    • Author(s)
      Yuki Takiguchi, Shinsuke Miyajima
    • Organizer
      PVSEC-26
    • Place of Presentation
      Marina Bay Sands, Sands Expo and Convention Centre, Singapore
    • Year and Date
      2016-10-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 電気化学製膜Cu2O薄膜の光電特性評価2016

    • Author(s)
      滝口 雄貴, 折坂 葵, 宮島 晋介
    • Organizer
      第77回 応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ、新潟
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Low temperature deposition of gallium oxide by metalorganic chemical vapor deposition2016

    • Author(s)
      Yuki Takiguchi, Shinsuke Miyajima
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy (ICCGE-18)
    • Place of Presentation
      Nagoya Congress Center
    • Year and Date
      2016-08-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] pH制御による電気化学製膜Cu2Oの電気特性制御2016

    • Author(s)
      辻 玄貴, 滝口 雄貴, 宮島 晋介
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 酸化銅(I)薄膜の光音響分光測定2015

    • Author(s)
      宮﨑尚、守本純、辻玄貴、滝口雄貴、宮島晋介
    • Organizer
      第36回超音波エレクトロニクスの基礎と応用に関するシンポジウム
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2015-11-05
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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