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Development of real-time vaporization system for atmospheric aerosols using high-temperature plasma jet

Research Project

Project/Area Number 15K16117
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental dynamic analysis
Research InstitutionYokohama City University

Principal Investigator

Sekimoto Kanako  横浜市立大学, 生命ナノシステム科学研究科(八景キャンパス), 助教 (40583399)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords質量分析 / コロナ放電 / プラズマジェット / 揮発性有機化合物 / バイオマス燃焼 / プロトン移動反応速度定数 / 分極率 / 永久双極子モーメント / 大気化学 / 森林火災 / ヘリウム / プロトン移動反応 / アルゴン
Outline of Final Research Achievements

Understanding the behavior of various organic acids and resulting aerosols in the atmosphere is one of important topics in atmospheric chemistry. However, a methodology for high-sensitive and real-time measurements of organic acids in aerosol phase has not been established yet. On the basis of these backgrounds, the following subjects were conducted in this work: (i) development of real-time vaporization system for atmospheric aerosols using high-temperature plasma jet, (ii) development of a methodology for comprehensive quantitation of atmospheric volatile organic compounds using proton-transfer-reaction mass spectrometry, and (iii) chemical characteristics of volatile organic compound emission from western US wildfire fuels.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (24 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (11 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 11 results,  Open Access: 6 results,  Acknowledgement Compliant: 3 results) Presentation (8 results) (of which Int'l Joint Research: 4 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] 米国立海洋大気庁 地球システム科学研究所/コロラド大学/モンタナ大学(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] 米国海洋大気庁 地球システム研究所(米国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] 米国立海洋大気庁 地球システム研究所(米国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Characterization of a catalyst-based total nitrogen and carbon conversion technique to calibrate particle mass measurement instrumentation2018

    • Author(s)
      Chelsea E. Stockwell, Agnieszka Kupc, Bartlomiej Witkowski, Ranajit K. Talikdar, Yong Liu, Vanessa Selimovic, Kyle J. Zarzana, Kanako Sekimoto, Carsten Warneke, Rebecca A. Washenfelder, Robert J. Yokelson, Ann M. Middlebrook and James M. Roberts
    • Journal Title

      Atmospheric Measurement Techniques

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment2018

    • Author(s)
      A. R. Koss, K. Sekimoto, J. B. Gilman, V. Selimovic, M. M. Coggon, K. J. Zarzana, B. Yuan, B. M. Lerner, S. S. Brown, J. L. Jimenez, J. Krechmer, J. M. Roberts, C. Warneke, R. J. Yokelson and J. de Gouw
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 18 Issue: 5 Pages: 3299-3319

    • DOI

      10.5194/acp-18-3299-2018

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ab initio investigations of stable geometries of the atmospheric negative ion NO3-(HNO3)2 and its monohydrate2018

    • Author(s)
      Atsuko Ueda, Yukiumi Kita, Kanako Sekimoto and Masanori Tachikawa
    • Journal Title

      Methods and Applications of Quantum Systems in Chemistry and Physics

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Collision-Induced Dissociation Study of Strong Hydrogen-Bonded Cluster Ions Y<sup>−</sup>(HF)<i><sub>n</sub></i> (Y=F, O<sub>2</sub>) Using Atmospheric Pressure Corona Discharge Ionization Mass Spectrometry Combined with a HF Generator2017

    • Author(s)
      K. Sakamoto, K. Sekimoto and M. Takayama
    • Journal Title

      Mass Spectrometry

      Volume: 6 Issue: 1 Pages: A0063-A0063

    • DOI

      10.5702/massspectrometry.A0063

    • NAID

      130006091407

    • ISSN
      2186-5116, 2187-137X
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Proton-transfer-reaction mass spectrometry: Applications in atmospheric sciences2017

    • Author(s)
      Bin Yuan, Abigail Koss, Carsten Warneke, Matthew Coggon, Kanako Sekimoto and Joost de Gouw
    • Journal Title

      Chemical Reviews

      Volume: 117 Issue: 21 Pages: 13187-13229

    • DOI

      10.1021/acs.chemrev.7b00325

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ionization Capabilities of Hydronium Ions and High Electric Fields Produced by Atmospheric Pressure Corona Discharge2017

    • Author(s)
      N. Sato, K. Sekimoto, M. Takayama
    • Journal Title

      Mass Spectrometry

      Volume: 5 Issue: 2 Pages: S0067-S0067

    • DOI

      10.5702/massspectrometry.S0067

    • NAID

      130005476003

    • ISSN
      2186-5116, 2187-137X
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Calculation of the sensitivity of proton-transfer-reaction mass spectrometry (PTR-MS) for organic trace gases using molecular properties2017

    • Author(s)
      Kanako Sekimoto, Shao-Meng Li, Bin Yuan, Abigail Koss, Matthew Coggon, Carsten Warneke and Joost de Gouw
    • Journal Title

      International Journal Mass Spectrometry

      Volume: 印刷中 Pages: 71-94

    • DOI

      10.1016/j.ijms.2017.04.006

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 化学イオン化法 -定性的・定量的イオン化に適したイオン分子反応系-2017

    • Author(s)
      関本 奏子
    • Journal Title

      Journal of the Mass Spectrometry Society of Japan

      Volume: 65 Pages: 2-6

    • NAID

      130005332303

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] リアルタイム直接分析(DART)法のイオン化特性と コロナ放電による高感度化2017

    • Author(s)
      関本 奏子
    • Journal Title

      Journal of the Mass Spectrometry Society of Japan

      Volume: 印刷中

    • NAID

      130007342636

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Improvement in ionization efficiency of direct analysis in real time-mass spectrometry (DART-MS) by corona discharge2016

    • Author(s)
      K. Sekimoto, M. Sakakura, T. Kawamukai, H. Hike, T. Shiota, F. Usui, Y. Bando and M. Takayama
    • Journal Title

      Analyst

      Volume: 141 Issue: 16 Pages: 4879-4892

    • DOI

      10.1039/c6an00779a

    • NAID

      120006530538

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of H3O+, OH-, O2-, NOx- and NOx for Escherichia Coli inactivation in atmospheric pressure DC corona discharges2015

    • Author(s)
      K. Sekimoto, R. Gonda and M. Takayama
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 48 Issue: 30 Pages: 305401-305401

    • DOI

      10.1088/0022-3727/48/30/305401

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] Calculation of the sensitivity of proton-transfer-reaction mass spectrometry (PTR-MS) for volatile organic compounds2017

    • Author(s)
      Kanako Sekimoto, Shao-Meng Li, Bin Yuan, Abigail Koss, Matthew Coggon, Carsten Warneke and Joost de Gouw
    • Organizer
      The 64th ASMS Conference on Mass Spectrometry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Unravelling the chemical complexity of biomass burning VOC emissions via H3O+ ToF-CIMS: Separation of high- and low-temperature pyrolysis products2017

    • Author(s)
      Kanako Sekimoto, Abigail Koss, Jessica B. Gilman, Vanessa Selimovic, Matthew M. Coggon, Kyle J. Zarzana, Bin Yuan, Brin M. Lerner, Steven B. Brown, Carsten Warneke, Robert J. Yokelson and Joost de Gouw
    • Organizer
      2017 American Geophysical Union Fall meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 揮発性有機化合物の分子情報を用いたプロトン移動反応質量分析法の感度計算2017

    • Author(s)
      関本 奏子, Shao-Meng Li, Bin Yuan, Abigail Koss, Matthew Coggon, Carsten Warneke and Joost de Gouw
    • Organizer
      第65回質量分析総合討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Calculation of average-dipole-orientation rate constants for proton transfer reactions between H3O+ and organic compounds using molecular mass and elemental composition2016

    • Author(s)
      Kanako Sekimoto, Shao-Meng Li, Bin Yuan, Abigail Koss, Matthew Coggon, Carsten Warneke and Joost de Gouw
    • Organizer
      The 64th ASMS Conference on Mass Spectrometry
    • Place of Presentation
      Gonzalez Convention Center, San Antonio, TX, USA
    • Year and Date
      2016-06-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 質量・元素組成・ADO理論を用いたH3O+ および大気中微量成分間のプロトン移動反応速度定数の計算2016

    • Author(s)
      関本 奏子, Shao-Meng Li, Bin Yuan, Abigail Koss, Matthew Coggon, Carsten Warneke and Joost de Gouw
    • Organizer
      第64回質量分析総合討論会
    • Place of Presentation
      ホテル阪急エキスポパーク(大阪府吹田市)
    • Year and Date
      2016-05-18
    • Related Report
      2016 Research-status Report
  • [Presentation] 大気圧コロナ放電イオン化質量分析法を用いたペチュニア花弁の香気成分のアンビエント分析2015

    • Author(s)
      ◯関本 奏子,芦澤 ゆりの,高山 光男
    • Organizer
      第63回質量分析総合討論会
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2015-06-17
    • Related Report
      2015 Research-status Report
  • [Presentation] 直流コロナ放電を用いたリアルタイム直接質量分析法(DART―MS)の高感度化2015

    • Author(s)
      ◯関本 奏子,坂倉 幹始,川向 孝知,比毛 浩,塩田 晃久,碓井 史彦,板東 泰彦,高山 光男
    • Organizer
      第63回質量分析総合討論会
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2015-06-17
    • Related Report
      2015 Research-status Report
  • [Presentation] Improving ionization efficiency of direct analysis in real time-mass spectrometry (DART-MS) by using DC corona discharges2015

    • Author(s)
      ◯K. Sekimoto, M. Sakakura, T. Kawamukai, H. Hike, T. Shiota, F. Usui, Y. Bando and M. Takayama
    • Organizer
      The 63rd ASMS Conference on Mass Spectrometry
    • Place of Presentation
      St. Louis, Missouri, USA
    • Year and Date
      2015-05-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 大気中揮発性有機化合物の計測手法「プロトン移動反応質量分析法」の最新総説

    • URL

      https://www.yokohama-cu.ac.jp/news/2017/20171016_Sekimoto.html

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 大気圧イオン化方法2015

    • Inventor(s)
      関本 奏子,高山 光男,比毛 浩,坂倉 幹始
    • Industrial Property Rights Holder
      公立大学法人横浜市立大学,エーエムアール株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-165952
    • Filing Date
      2015-08-25
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2022-06-07  

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