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Bond state selective synthesis of doped-graphene

Research Project

Project/Area Number 15K17446
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Okada Takeru  東北大学, 流体科学研究所, 助教 (90616385)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsグラフェン / ドーピング / 窒化 / 窒化グラフェン
Outline of Final Research Achievements

In this study, hetero atom doping of graphene was investigated. Doping was carried out by neutral beam process that enables to irradiate energy-controlled beam. In the case of nitrogen doping in graphene, it is found that the formation of nitrogen-carbon bond depends on energy of irradiated beam, thus CN double bond (pyridinic nitrogen) is formed under higher energy (12 eV) and CN single bond (graphitic nitrogen) is formed under 7 eV. Furthermore, nitrogen doped graphene shows catalytic activity of oxygen reduction reaction, and graphitic nitrogen has higher activity.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (21 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results) Presentation (12 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results)

  • [Int'l Joint Research] NASA Ames Research Center(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] NASA Ames Research Center(米国)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Energy control of neutral oxygen particles passing through an aperture electrode2018

    • Author(s)
      Ohno Takeo、Nakayama Daiki、Okada Takeru、Samukawa Seiji
    • Journal Title

      Results in Physics

      Volume: 8 Pages: 169-171

    • DOI

      10.1016/j.rinp.2017.12.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room-Temperature Synthesis of GaN Driven by Kinetic Energy beyond the Limit of Thermodynamics2017

    • Author(s)
      Imaoka Takane、Okada Takeru、Samukawa Seiji、Yamamoto Kimihisa
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 9 Issue: 48 Pages: 41629-41633

    • DOI

      10.1021/acsami.7b13694

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bonding state and defects of nitrogen-doped graphene in oxygen reduction reaction2016

    • Author(s)
      T.Okada, K. Y. Inoue, G Kalita, M Tanemura, T Matsue, M. Meyyappan, and S. Samukawa
    • Journal Title

      Chemical Physics Letters

      Volume: 665 Pages: 117-120

    • DOI

      10.1016/j.cplett.2016.10.061

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Formation of Ge Oxide Film by Neutral Beam Post Oxidation using Al Metal Film2016

    • Author(s)
      T. Ohno, D. Nakayama, T. Okada, and S. Samukawa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 4S Pages: 04EJ03-04EJ03

    • DOI

      10.7567/jjap.55.04ej03

    • NAID

      210000146366

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Flux and Energy of Hydrogen Neutral Beam on Hydrogenation Process of Graphene2016

    • Author(s)
      T. Okada, C. Thomas, M. Meyyappan, and S. Samukawa
    • Journal Title

      IEEE Xplore

      Volume: -

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Selective in-plane nitrogen doping of graphene by energy-controlled neutral beam2015

    • Author(s)
      T. Okada and S. Samukawa
    • Journal Title

      Nanotechnology

      Volume: 26 Issue: 48 Pages: 485602-485602

    • DOI

      10.1088/0957-4484/26/48/485602

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Selective nitrogen doping of graphene by energy-controlled neutral beam2015

    • Author(s)
      T. Okada and S.Samukawa,
    • Journal Title

      Proceedings of the 15th IEEE International Conference on Nanotechnology

      Volume: na Pages: 1247-1249

    • DOI

      10.1109/nano.2015.7388856

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] Energy Harvesting Application of Graphene -Power Generation from Graphene-water Interface-2018

    • Author(s)
      T. Okada
    • Organizer
      Mini-Symposium of Multi-Energy Innovation Center
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] グラフェン-水界面の動電現象における窒素ドーピング効果2018

    • Author(s)
      岡田 健、Golap Kalita、種村眞幸、山下一郎、M. Meyyappan、寒川 誠二
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ナノ電気化学セル顕微鏡によるグラフェン/グラファイト構造における電気化学活性の局所電気化学測定と可視化2017

    • Author(s)
      三浦 千穂、熊谷 明哉、岡田 健、寒川 誠二、珠玖 仁、高橋 康史、末永 智一
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Scanning Electrochemical Cell Microscopy for Visualization of Local Electrochemical Activities on Graphene/Graphite2017

    • Author(s)
      A. Kumatani, C. Miura, T. Okada, S. Samukawa, H. Shiku, Y. Takahashi, and T. Matsue
    • Organizer
      The 52nd Fullerenes-Nanotubes-Graphene General Symposium
    • Place of Presentation
      東京大学(東京都・文京区)
    • Year and Date
      2017-03-01
    • Related Report
      2016 Research-status Report
  • [Presentation] Selective Formation of Nitrogen-Doped Graphene by Neutral Nitrogen Beam2017

    • Author(s)
      T.Okada
    • Organizer
      27th Annual Meeting of MRS-J (The Material Research Society of Japan)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 運動エネルギーで駆動される窒素固定反応によるGaNの室温合成2017

    • Author(s)
      今岡享稔、岡田健、寒川誠二、山元公寿
    • Organizer
      応用物理学会 シリコンナノテクノロジー分科会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] グラフェンを用いた固液摩擦帯電におけるドーピング効果検証2017

    • Author(s)
      岡田健、Kalita Golap、種村眞幸、寒川誠二
    • Organizer
      第78回応用物理学会 秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 窒素中性粒子ビームによる窒化ガリウムの室温合成2017

    • Author(s)
      岡田健、 今岡享稔、 山元公寿、 寒川誠二
    • Organizer
      第78回応用物理学会 秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 塩化ガリウムを前駆体とする窒素中性粒子ビームによる窒化ガリウム室温合成2017

    • Author(s)
      岡田健、 今岡享稔、 山元公寿、 寒川誠二
    • Organizer
      Plasma Conference 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effect of Flux and Energy of Hydrogen Neutral Beam on Hydrogenation Process of Graphene2016

    • Author(s)
      T. Okada, C. Thomas, M. Meyyappan, and S. Samukawa
    • Organizer
      The 16th IEEE International Conference on Nanotechnology
    • Place of Presentation
      仙台国際センター(宮城県・仙台市)
    • Year and Date
      2016-08-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Investigation of carbon-nitrogen bonding state in graphene on catalytic activity2016

    • Author(s)
      T. Okada, K. Y. Inoue, T. Matsue, G. Kalita, M. Tanemura, M. Meyyappan, and S. Samukawa
    • Organizer
      International Conference on the Science and Application of Nanotubes - NT16
    • Place of Presentation
      Vienna/Austria
    • Year and Date
      2016-08-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Selective nitrogen doping of graphene by energy-controlled neutral beam2015

    • Author(s)
      2.T. Okada and S.Samukawa,
    • Organizer
      The 15th IEEE International Conference on Nanotechnology
    • Place of Presentation
      Rome/Italy
    • Year and Date
      2015-07-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2022-06-07  

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