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Nano-scale processing of graphene liquid cell

Research Project

Project/Area Number 15K17462
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionHokkaido University

Principal Investigator

Yamazaki Kenji  北海道大学, 工学研究院, 助教 (10732985)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsグラフェン / 電子顕微鏡 / 金属単原子 / 溶液セル / TEM / 原子層セル / 単原子触媒 / TEM
Outline of Final Research Achievements

First, I observed moire structures in transmission electron microscopy (TEM) observations; these are signature patterns in multilayer, although Raman spectra showed monolayer. We also performed a multi- slice TEM image simulation to compare the 3D atomic structures. We found that the experimental moire image was constructed with a 0.9-1.2 nm interlayer distance between graphene membranes. This structure was constructed by transferring CVD-grown graphene films that formed on both sides of the Cu substrate at once.
Second, I synthesized the graphene liquid cells and dispersed single metal atoms on graphene surfaces.I confirmed the graphene liquid cells transformed during electron beam irradiation.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (15 results)

All 2018 2017 2016 2015

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (7 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Characterization of TEM Moire Patterns Originating from Two Monolayer Graphenes Grown on the Front and Back Sides of a Copper Substrate Using the CVD method2018

    • Author(s)
      K. Yamazaki, Yosuke Maehara, K. Gohara
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 87 Issue: 6 Pages: 061011-061011

    • DOI

      10.7566/jpsj.87.061011

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Substrate-Induced Structure and Molecular Dynamics in a Lipid Bilayer Membrane2017

    • Author(s)
      Motegi Toshinori、Yamazaki Kenji、Ogino Toshio、Tero Ryugo
    • Journal Title

      Langmuir

      Volume: 33 Issue: 51 Pages: 14748-14755

    • DOI

      10.1021/acs.langmuir.7b03212

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of local hydrophobicity on sapphire surfaces in aqueous environment by colloidal probe atomic force microscopy2016

    • Author(s)
      T. Wada, T. Isono, K. Yamazaki, T. Ogino
    • Journal Title

      Applied Surface Science

      Volume: 396 Pages: 1206-1211

    • DOI

      10.1016/j.apsusc.2016.11.112

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Gas Nanobubbles as Nucleation Acceleration in the Gas-Hydrate Memory Effect2016

    • Author(s)
      T. Uchida, K. Yamazaki, and K. Gohara: Gas Nanobubbles as Nucleation Acceleration in the Gas-Hydrate Memory Effect, J. Phys. Chem. C,120(47),26620-26629, 2016.
    • Journal Title

      J. Phys. Chem. C,

      Volume: 120 Issue: 47 Pages: 26620-26629

    • DOI

      10.1021/acs.jpcc.6b07995

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Design of Core-Pd/Shell-Ag Nanocomposite Catalyst for Selective Semihydrogenation of Alkynes2016

    • Author(s)
      1.T. Mitsudome, T. Urayama, K. Yamazaki, Y. Maehara, J. Yamasaki, K. Gohara, Z. Maeno, T. Mizugaki, K. Jitsukawa, and K. Kaneda
    • Journal Title

      ACS Catalysis

      Volume: 6 Issue: 2 Pages: 666-670

    • DOI

      10.1021/acscatal.5b02518

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Generation of micro- and nano-bubble distributions in water via dissociation of gas hydrates2016

    • Author(s)
      T. Uchida, K. Yamazaki, K. Gohara
    • Journal Title

      Korean Journal of Chemical Engineering

      Volume: 33 Issue: 5 Pages: 1-7

    • DOI

      10.1007/s11814-016-0032-7

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] A XPS study of Pt Single Atoms Dispersed on a Graphene Support2017

    • Author(s)
      Kenji Yamazaki, Yosuke Maehara, Kazutoshi Gohara
    • Organizer
      2017 MRS (Materials Research Society) Fall Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Atomic Resolved Imaging of Nanostructures on Graphene by TEM2017

    • Author(s)
      Kenji Yamazaki, Yosuke Maehara, Kazutoshi Gohara
    • Organizer
      International Workshop on NanoScience and NanoOptics 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nano-structure Imaging using Electron Microscope2017

    • Author(s)
      Kenji Yamazaki, Yosuke Maehara, Kazutoshi Gohara
    • Organizer
      Swedish-Japanese Workshop on Nano-Structure Science by Novel Light Sources
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] グラフェン上Pt単原子の原子分解能イメージングと電子状態解析2017

    • Author(s)
      山崎 憲慈, 前原 洋祐, 郷原 一寿
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] TEM analysis of Moiré patterns originating from two monolayer graphenes grown on the front and back sides of a copper substrate used in CVD2015

    • Author(s)
      K. Yamazaki, Y. Maehara, and K. Gohara
    • Organizer
      2015 MRS (Materials Research Society) Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2015-11-29
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] CVD法によって銅箔の両面に成長させたグラフェン膜に由来するモアレパターンの解析2015

    • Author(s)
      山崎 憲慈, 前原 洋祐, 郷原 一寿
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] CVD成長させたグラフェン膜に観察されるモアレパターンの解析2015

    • Author(s)
      山崎 憲慈, 前原 洋祐, 郷原 一寿
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      京都国際会館(京都市)
    • Year and Date
      2015-05-13
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 支持体上に単原子が分散した構造体、支持体上に単原子が分散した構造体を製造する方法およびスパッタ装置2016

    • Inventor(s)
      郷原一寿、前原洋祐、山崎憲慈
    • Industrial Property Rights Holder
      郷原一寿、前原洋祐、山崎憲慈
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016
    • Acquisition Date
      2017
    • Related Report
      2017 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 分散体を製造する方法および分散体2016

    • Inventor(s)
      郷原一寿、前原洋祐、山崎憲慈
    • Industrial Property Rights Holder
      郷原一寿、前原洋祐、山崎憲慈
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-016872
    • Filing Date
      2016-02-01
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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