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Control of surface electronic states for anatase TiO2 thin film by interface engineering

Research Project

Project/Area Number 15K17470
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

Minohara Makoto  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 特別助教 (70728633)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords酸化物表面・界面 / 酸化物界面
Outline of Final Research Achievements

We have investigated the electronic structure of polar/nonpolar oxide heterointerfaces between (001)-oriented LaFeO3 film and Nb:SrTiO3 substrate with different interfacial termination layer using x-ray photoemission spectroscopy. A certain built-in potential forms in Nb:SrTiO3 substrate for the LaFeO3/SrO-Nb:SrTiO3, while almost flat band is maintained even after the LaFeO3 deposition for the LaFeO3/TiO2-Nb:SrTiO3. Since the estimated charge in the depletion layer is not sufficient to solve the polarity mismatch, the electronic reconstruction are presumably occurred in both sides of the LaFeO3 film and the Nb:SrTiO3 substrate. Moreover, the valence band spectra of thick LaFeO3 films rigidly shifts ~0.4 eV by changing the interfacial termination layer. This result indicates the different internal potential formation in LaFeO3 film depending on the interfacial polarity, supporting the abovementioned interpretation on the possible electric reconstruction in LaFeO3 layer.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (11 results)

All 2018 2017 2016 2015

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (6 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Thickness dependence and dimensionality effects on charge and magnetic orderings in La1/3Sr2/3FeO3 thin films2018

    • Author(s)
      K. Yamamoto, Y. Hirata, M. Horio, Y. Yokoyama, K. Takubo, M. Minohara, H. Kumigashira, Y. Yamasaki, H. Nakao, Y. Murakami, A. Fujimori, and H. Wadati
    • Journal Title

      Phys. Rev. B

      Volume: 97 Issue: 7 Pages: 75134-75134

    • DOI

      10.1103/physrevb.97.075134

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomically-engineered epitaxial anatase TiO2 metal-semiconductor field-effect transistors2018

    • Author(s)
      B. S. Y. Kim, M. Minohara, Y. Hikita, C. Bell, and H. Y. Hwang
    • Journal Title

      Appl. Phys. Lett.

      Volume: 112 Issue: 13 Pages: 133506-133506

    • DOI

      10.1063/1.5024418

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric collapse at the LaAlO3/SrTiO3 (001) heterointerface under applied electric field2017

    • Author(s)
      M. Minohara, Y. Hikita, C. Bell, H. Inoue, M. Hosoda, H. K. Sato, H. Kumigashira, M. Oshima, E. Ikenaga, and H. Y. Hwang
    • Journal Title

      Scientific Report

      Volume: VOL. 7 Issue: 1 Pages: 9516-9516

    • DOI

      10.1038/s41598-017-09920-9

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Thickness-dependent physical properties of La1/3Sr2/3FeO3 thin films grown on SrTiO3 (001) and (111) substrates2016

    • Author(s)
      Makoto Minohara, Miho Kitamura, Hiroki Wadati, Hironori Nakao, Reiji Kumai, Youichi Murakami, and Hiroshi Kumigashira
    • Journal Title

      Journal of Applied Physics

      Volume: 120 Issue: 2 Pages: 025303-025303

    • DOI

      10.1063/1.4958670

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of k⊥-broadening on ARPES spectra of the (110) and (001) surfaces of SrVO3 films2016

    • Author(s)
      T. Mitsuhashi, M. Minohara, R. Yukawa, M. Kitamura, K. Horiba, M. Kobayashi, and H. Kumigashira
    • Journal Title

      Phys. Rev. B

      Volume: 94 Issue: 12 Pages: 125148-125148

    • DOI

      10.1103/physrevb.94.125148

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] PLD法によるアンチペロブスカイト型酸化物 Ca3SnO薄膜の作製2017

    • Author(s)
      簔原 誠人、湯川 龍、組頭 広志
    • Organizer
      第64回 応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 面方位制御La1/3Sr2/3FeO3薄膜における 電荷不均化の膜厚依存性2017

    • Author(s)
      簔原誠人、北村未歩、和達大樹、中尾裕則、熊井玲児、村上洋一、組頭広志
    • Organizer
      第30回 日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      神戸技術センター(兵庫県・神戸市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 面方位制御La1/3Sr2/3FeO3薄膜における電荷不均化の膜厚依存性2016

    • Author(s)
      簑原誠人、北村未歩、和達大樹、組頭広志
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京、目黒区)
    • Year and Date
      2016-03-20
    • Related Report
      2015 Research-status Report
  • [Presentation] 終端面制御したLaFeO3/Nb:SrTiO3ヘテロ接合界面の電子状態2016

    • Author(s)
      簑原誠人、北村未歩、三橋太一、小林正起、堀場弘司、組頭広志
    • Organizer
      第29回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      柏の葉カンファレンスセンター(千葉、柏市)
    • Year and Date
      2016-01-10
    • Related Report
      2015 Research-status Report
  • [Presentation] Thickness Dependent Physical Properties of La1/3Sr2/3FeO3 Thin Films Grown on SrTiO3 (001) and (111) Substrates2016

    • Author(s)
      M. Minohara, M. Kitamura, H. Wadati, H. Nakao, R, Kumai, Y. Murakami, and H. Kumigashira
    • Organizer
      International Workshop on Oxide Electronics 23
    • Place of Presentation
      南京(中国)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 終端面制御したLaFeO3/Nb:SrTiO3ヘテロ接合界面の電子状態2015

    • Author(s)
      簑原誠人、北村未歩、三橋太一、小林正起、堀場弘司、組頭広志
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知、名古屋市)
    • Year and Date
      2015-09-14
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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