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Electric-double-layer doping into organic correlated electron systems

Research Project

Project/Area Number 15K17714
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Condensed matter physics II
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Kawasugi Yoshitaka  国立研究開発法人理化学研究所, 加藤分子物性研究室, 研究員 (40590964)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords分子性導体 / キャリアドーピング / モット絶縁体 / 電場誘起超伝導
Outline of Final Research Achievements

Charge carrier density is one of the most fundamental parameters that determines the electronic properties of strongly correlated electron systems. The properties can be drastically changed by varying this parameter, such as the case of metal-insulator transitions. In this study, the carrier density of organic correlated electron systems is electrostatically modified by means of electric double layer transistor.
By virtue of the high tunability of organic molecular material, both electron and hole carriers are successfully injected into the same sample of an organic Mott insulator (materials that are insulating because of electron electron interaction). The results indicate that a two-dimensional Mott insulator with next nearest neighbor hopping shows intrinsic doping asymmetry originating from the band structure.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (15 results)

All 2018 2017 2016 2015 Other

All Journal Article (4 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 4 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Organic Phase-transition Transistor with Strongly-correlated Electrons2018

    • Author(s)
      H. M. Yamamoto, M. Suda and Y. Kawasugi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 3S2 Pages: 03EA02-03EA02

    • DOI

      10.7567/jjap.57.03ea02

    • NAID

      210000148737

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Critical Behavior in Doping-Driven Metal-Insulator Transition on Single-Crystalline Organic Mott-FET2017

    • Author(s)
      Yoshiaki Sato, Yoshitaka Kawasugi, Masayuki Suda, Hiroshi M Yamamoto, Reizo Kato
    • Journal Title

      Nano Letters

      Volume: 17 Issue: 2 Pages: 708-714

    • DOI

      10.1021/acs.nanolett.6b03817

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electron-hole doping asymmetry of Fermi surface reconstructed in a simple Mott insulator2016

    • Author(s)
      Yoshitaka Kawasugi, Kazuhiro Seki, Yusuke Edagawa, Yoshiaki Sato, Jiang Pu, Taishi Takenobu, Seiji Yunoki, Hiroshi M. Yamamoto, Reizo Kato
    • Journal Title

      Nature Communications

      Volume: 7 Issue: 1 Pages: 12356-12356

    • DOI

      10.1038/ncomms12356

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Simultaneous enhancement of conductivity and Seebeck coefficient in an organic Mott transistor2016

    • Author(s)
      Yoshitaka Kawasugi, Kazuhiro Seki, Yusuke Edagawa, Yoshiaki Sato, Jiang Pu, Taishi Takenobu, Seiji Yunoki, Hiroshi M. Yamamoto, Reizo Kato
    • Journal Title

      Appl. Phys. Lett.

      Volume: 109 Issue: 23 Pages: 233301-233301

    • DOI

      10.1063/1.4971310

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 電気二重層ドーピングとひずみ制御による κ 型 ET 塩の超伝導相の探索II2018

    • Author(s)
      川椙義高、関和弘、蒲江、竹延大志、柚木清 司、山本浩史、加藤礼三
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電気二重層ドーピングとひずみ制御による κ 型 ET 塩の超伝導相の探索2017

    • Author(s)
      川椙義高、関和弘、蒲江、竹延大志、柚木清 司、山本浩史、加藤礼三
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Electron-Hole Doping Asymmetry in an Organic Mott Insulator Investigated by Electric-double-Layer Doping2017

    • Author(s)
      Yoshitaka Kawasugi
    • Organizer
      ISCOM2017 (The 12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] κ型ET塩に対する電気二重層を用いたキャリアドーピングIV2016

    • Author(s)
      川椙義高、関和弘、枝川祐介、佐藤慶明、蒲江、竹延大志、柚木清司、山本浩史、加藤礼三
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] κ型ET塩に対する電気二重層を用いたキャリアドーピングIV2016

    • Author(s)
      川椙義高、関和弘、枝川祐介、佐藤慶明、蒲江、竹延大志、柚木清司、山本浩史、加藤礼三
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Asymmetric Reconstruction of Fermi Surface in a Gate-Tuned Organic Mott Insulator2016

    • Author(s)
      Y. Kawasugi, K. Seki, Y. Edagawa, Y. Sato, J. Pu, T. Takenobu, S. Yunoki, H. M. Yamamoto, and R. Kato
    • Organizer
      Gordon Research Conference: Conductivity & Magnetism in Molecular Materials
    • Place of Presentation
      South Hadley, MA, USA
    • Year and Date
      2016-08-14
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 分子性導体に対する電界効果キャリアドーピング2016

    • Author(s)
      川椙義高
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学 (宮城県・仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] κ型ET塩に対する電気二重層を用いたキャリアドーピングIII2015

    • Author(s)
      川椙義高、関和弘、枝川祐介、佐藤慶明、蒲江、竹延大志、山本浩史、加藤礼三
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学 (大阪府・吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Carrier doping into a Mott insulator κ-(BEDT-TTF)2Cu[N(CN)2]Cl using electric double layer transistor”2015

    • Author(s)
      Yoshitaka Kawasugi, Kazuhiro Seki, Yusuke Edagawa, Yoshiaki Sato, Jiang Pu, Taishi Takenobu, Hiroshi M. Yamamoto, and Reizo Kato
    • Organizer
      International Symposium on Crystalline Organic Metals (ISCOM)
    • Place of Presentation
      Bad Gogging (Germany)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Book] 固体物理(記事タイトル: 分子性2次元モット絶縁体におけるフィリング制御の新展開)2016

    • Author(s)
      川椙義高、関和弘、須田理行、山本浩史
    • Total Pages
      13
    • Publisher
      アグネ技術センター
    • Related Report
      2016 Research-status Report
  • [Remarks] 両極性動作する有機モット転移トランジスタを実現

    • URL

      http://www.riken.jp/pr/press/2016/20160805_3/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2020-05-15  

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