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Development of intramolecular isotope analysis for understanding the origin of natural gas hydrocarbons

Research Project

Project/Area Number 15K17774
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Geology
Research InstitutionTokyo Institute of Technology

Principal Investigator

Gilbert Alexis  東京工業大学, 理学院, 特任助教 (20726955)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
KeywordsNatural gas / Stable isotopes / hydrocarbons / Analytical development / Isotope / Hydrocarbons / アイソトプ
Outline of Final Research Achievements

We developed a method to understand the origin of natural gas. Natural gas is made from various processes and understanding these processes has several implications, including fossil energy, origin of life and habitability of other planetary systems.
The method is based on the analysis of stable isotope ratio of carbon (13C/12C) in hydrocarbons from natural gas. Stable isotopes are used to infer the origin and history of a given molecule. The method we developed is unique and brings new type of information regarding the origin of natural gas. In particular, we were able to distinguish hydrocarbons that formed from biological organisms to those formed by chemical or inorganic means. In addition, we could understand the mechanism of formation of hydrocarbons in a Japanese hotspring (Hakuba-Happo, Japan). Overall, our work has implications to understand the origin of natural gas and will be used in the near future in other geological settings.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (16 results)

All 2017 2016 2015 Other

All Journal Article (8 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 8 results,  Open Access: 3 results,  Acknowledgement Compliant: 4 results) Presentation (7 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results) Remarks (1 results)

  • [Journal Article] Compound- and position-specific carbon isotopic signatures of abiogenic hydrocarbons from on-land serpentinite-hosted Hakuba Happo hot spring in Japan2017

    • Author(s)
      Suda, K., Gilbert, A., Yamada, K., Yoshida, Y., Ueno, Y.
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 206 Pages: 201-215

    • DOI

      10.1016/j.gca.2017.03.008

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] The Abiotic Chemistry of Thiolated Acetate Derivatives and the Origin of Life2016

    • Author(s)
      Chandru, K., Gilbert, A., Butch, C., Aono, M., Cleaves, HJ.
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 29883-29883

    • DOI

      10.1038/srep29883

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Measurement of position-specific 13C isotopic composition of propane at the nanomole level2016

    • Author(s)
      A. Gilbert, K. Suda, K. Yamada, Y. Ueno, N. Yoshida.
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 177 Pages: 205-216

    • DOI

      10.1016/j.gca.2016.01.017

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Evaluation of on-line pyrolysis coupled to isotope ratio mass spectrometry for the determination of position-specific 13 C isotope composition of short chain n-alkanes (C6-C 12)2016

    • Author(s)
      Alexis Gilbert, Keita Yamada, Naohiro Yoshida
    • Journal Title

      Talanta

      Volume: 153 Pages: 158-162

    • DOI

      10.1016/j.talanta.2016.03.014

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Measurement of the intramolecular 13C isotope ratio of pyruvate in diet pills using HS-SPME-GC-Py-GC-C-IRMS2016

    • Author(s)
      T. Nimmanwudipong, A. Gilbert, K. Yamada, N. Yoshida.
    • Journal Title

      Journal of Analytical and bioanalytical techniques

      Volume: 7 Issue: 1 Pages: 1-5

    • DOI

      10.4172/2155-9872.1000293

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Measurement of natural carbon isotopic composition of acetone in human urine2015

    • Author(s)
      Yamada K., Ohishi K., Gilbert A., Akasaka M., Yoshida N., Yoshimura R.
    • Journal Title

      Anal. Bioanal. Chem.

      Volume: 408 Issue: 6 Pages: 1597-1607

    • DOI

      10.1007/s00216-015-9268-z

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Position-Specific Isotope Analysis of Xanthines: A 13C Nuclear Magnetic Resonance Method to Determine the 13C Intramolecular Composition at Natural Abundance.2015

    • Author(s)
      D. G. Diomande, E. Martineau, A. Gilbert, P. Nun, A. Murata, K. Yamada, N. Watanabe, I. Tea, R. J. Robins, N. Yoshida, G. S. Remaud
    • Journal Title

      Analytical Chemistry

      Volume: 87 Issue: 13 Pages: 6600-6606

    • DOI

      10.1021/acs.analchem.5b00559

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Analytical method for simultaneous determination of bulk and intramolecular 13C isotope compositions of acetic acid2015

    • Author(s)
      T. Nimmanwudipong, A. Gilbert, K. Yamada, N. Yoshida.
    • Journal Title

      Rapid Communications in Mass Spectrometry

      Volume: 29 Issue: 24 Pages: 2337-2340

    • DOI

      10.1002/rcm.7398

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Recent insights into intramolecular 13C isotope composition of biomolecules2016

    • Author(s)
      Alexis Gilbert, Gerald Remaud, Keita Yamada, Yuichiro Ueno, Richard Robins, Naohiro Yoshida
    • Organizer
      AGU 2016
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-12-12
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Position-specific isotope analysis by on-line pyrolysis coupled to IRMS2016

    • Author(s)
      Alexis Gilbert, Keita Yamada, Yuichiro Ueno, Naohiro Yoshida
    • Organizer
      AGU 2016
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-12-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] Stable isotopes in Biogeosciences2016

    • Author(s)
      Alexis Gilbert
    • Organizer
      International Symposium on Isotopomer 2016
    • Place of Presentation
      Nantes (France)
    • Year and Date
      2016-10-03
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Abiogenesis of hydrocarbons revealed by position-specific isotope analysis2016

    • Author(s)
      Alexis Gilbert, Konomi Suda, Keita Yamada, Naohiro Yoshida, Yuichiro Ueno
    • Organizer
      4th ELSI Symposium
    • Place of Presentation
      Tokyo Institute of Technology
    • Year and Date
      2016-01-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] On-line pyrolysis combined with IRMS for 13C intramolecular isotope determination2016

    • Author(s)
      Alexis Gilbert, Keita Yamada, Yuichiro Ueno, Naohiro Yoshida
    • Organizer
      Workshop on isotopologues (Goldschmidt Conference 2016)
    • Place of Presentation
      Tokyo (Japan)
    • Related Report
      2016 Annual Research Report
  • [Presentation] An apparatus dedicated to the measurement of position-specific isotope compsition of natural gas component2015

    • Author(s)
      Alexis Gilbert, Konomi Suda, Keita Yamada, Naohiro Yoshida, Yuichiro Ueno
    • Organizer
      3-rd International Workshop “Exploitation of Intramolecular Isotope Compositions and Emerging Techniques for their Measurement”
    • Place of Presentation
      Aix-en-Provence (France)
    • Year and Date
      2015-10-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Position-specific 13C isotope composition of non-methane hydrocarbons2015

    • Author(s)
      Alexis Gilbert, Konomi Suda, Keita Yamada, Naohiro Yoshida, Yuichiro Ueno
    • Organizer
      Goldschmidt 2015
    • Place of Presentation
      Prague (Czech Republic)
    • Year and Date
      2015-08-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] Alexis Gilbert

    • URL

      http://www.elsi.jp/ja/research/member/researcher/assistant-professor/alexis-gilbert.html

    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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