| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Outline of Final Research Achievements |
We synthesized phosphole-fused porphyrin dimer for the first time as a representative of a new class of porphyrins with a phosphorus atom. This porphyrin dimer possesses excellent electron-accepting character. Then, we synthesized octaphyrins with a dithieno[3,4-b:3',4'-d]thiophene unit as thiophene-fused dithiaoctaphyrin. The octaphyrins revealed cross-conjugated and macrocyclic 36π-electron networks.
In addition, we synthesized dithieno[3,4-b:3',4'-d]phosphole derivatives as a new type of thiophene-fused phopholes. They exhibit the unique hybrid character of electron-withdrawing phosphole and electron-donating thiophene.
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