Multistep switchable materials based on the assembly of photofunctional metal complexes
| Project/Area Number |
15K17827
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
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| Research Collaborator |
KATO Masako
KOBAYASHI Atsushi
SHITAMA Hotaka
NAKAJIMA Airi
SAMEERA W. M. C.
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | 錯体化学 / 光物性 |
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| Outline of Final Research Achievements |
In this work, we tried to investigate the development of stimuli-responsive materials driven by the self-assembly/dissociation of photofunctional Pt(II) complexes. As a result, we have discovered (i) the multistep electrochromic material based on the self-assembled mixed-valent platinum complex by the introduction of hydrogen bonds, and (ii) the post-synthetically color-tunable electrochromic material based on the coordination/dissociation of guest molecules on the redox-bistable mixed-valent platinum complex. These results provide the new strategy to construct multifunctional electronic devices based on the self-assembly of Pt(II) complexes.
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Report
(4 results)
Research Products
(48 results)
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[Journal Article] A pentanuclear iron catalyst designed for water oxidation2016
Author(s)
Masaya Okamura, Mio Kondo, Reiko Kuga, Yuki Kurashige, Takeshi Yanai, Shinya Hayami, Vijayendran K. K. Praneeth, Masaki Yoshida, Ko Yoneda, Satoshi Kawata, and Shigeyuki Masaoka
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Journal Title
Nature
Volume: 530
Issue: 7591
Pages: 465-468
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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