Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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Outline of Final Research Achievements |
In this work, we tried to investigate the development of stimuli-responsive materials driven by the self-assembly/dissociation of photofunctional Pt(II) complexes. As a result, we have discovered (i) the multistep electrochromic material based on the self-assembled mixed-valent platinum complex by the introduction of hydrogen bonds, and (ii) the post-synthetically color-tunable electrochromic material based on the coordination/dissociation of guest molecules on the redox-bistable mixed-valent platinum complex. These results provide the new strategy to construct multifunctional electronic devices based on the self-assembly of Pt(II) complexes.
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