Immobilizaiton of complex catalyst in metal-organic framework for hydrogenation reaction under low H2 pressure atmosphere
| Project/Area Number |
15K17836
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Konan University |
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Principal Investigator |
Takashima Yohei 甲南大学, フロンティアサイエンス学部, 助教 (40720652)
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | 多孔性金属錯体 / 不均一系触媒 / 水素 / 触媒 |
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| Outline of Final Research Achievements |
Hydrogenation reaction under low H2 pressure atmosphere is of great interest from a safety view point because H2 gas is highly flammable in air and shows explosion triggered by spark, heat or sunlight. In this work, Rh complex catalyst- MOF hybrid was newly synthesized and used as catalyst for hydrogenation of alkene substrates. Noteworthy, the composite maintained good catalytic activity even under low H2 concentration atmosphere where no hydrogenation proceeded with Rh complex catalyst.
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Report
(3 results)
Research Products
(18 results)
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[Journal Article] Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-Doped Polymer Substrate2016
Author(s)
Takaaki Tsuruoka, Misato Kumano, Koji Mantani, Tetsuhiro Matsuyama, Ayumi Miyanaga, Takashi Ohhashi, Yohei Takashima, Hideto Minami, Toyoko Suzuki, Kaori Imagawa, Kensuke Akamatsu
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Journal Title
Crystal Growth & Design
Volume: 16
Issue: 5
Pages: 2472-2476
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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