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Immobilizaiton of complex catalyst in metal-organic framework for hydrogenation reaction under low H2 pressure atmosphere

Research Project

Project/Area Number 15K17836
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionKonan University

Principal Investigator

Takashima Yohei  甲南大学, フロンティアサイエンス学部, 助教 (40720652)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords多孔性金属錯体 / 不均一系触媒 / 水素 / 触媒
Outline of Final Research Achievements

Hydrogenation reaction under low H2 pressure atmosphere is of great interest from a safety view point because H2 gas is highly flammable in air and shows explosion triggered by spark, heat or sunlight. In this work, Rh complex catalyst- MOF hybrid was newly synthesized and used as catalyst for hydrogenation of alkene substrates. Noteworthy, the composite maintained good catalytic activity even under low H2 concentration atmosphere where no hydrogenation proceeded with Rh complex catalyst.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2017 2016 2015

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 3 results) Presentation (12 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] An Integrated Function System Using Metal Nanoparticle@Mesoporous Silica@Metal-Organic Framework Hybrids2017

    • Author(s)
      Takashi Ohhashi, Takaaki Tsuruoka, Kohei Inoue, Yohei Takashima, Kensuke Akamatsu
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 245 Pages: 104-108

    • DOI

      10.1016/j.micromeso.2017.02.074

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-Doped Polymer Substrate2016

    • Author(s)
      Takaaki Tsuruoka, Misato Kumano, Koji Mantani, Tetsuhiro Matsuyama, Ayumi Miyanaga, Takashi Ohhashi, Yohei Takashima, Hideto Minami, Toyoko Suzuki, Kaori Imagawa, Kensuke Akamatsu
    • Journal Title

      Crystal Growth & Design

      Volume: 16 Issue: 5 Pages: 2472-2476

    • DOI

      10.1021/acs.cgd.6b00007

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Morphology Control of Metal-Organic Frameworks Based on Paddle-Wheel Units on Ion-Doped Polymer Substrate Using an Interfacial Growth Approach2016

    • Author(s)
      T. Tsuruoka, K. Mantani, A. Miyanaga, T. Matsuyama, T. Ohhashi, T. Takashima, K. Akamatsu
    • Journal Title

      Langmuir

      Volume: 32 Issue: 24 Pages: 6068-6073

    • DOI

      10.1021/acs.langmuir.6b01687

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Site-selective growth of metal-organic frameworks using an interfacial growth approach combined with VUV photolithography2016

    • Author(s)
      T. Tsuruoka, T. Matsuyama, A. Miyanaga, T. Ohhashi, T. Takashima, K. Akamatsu
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 81 Pages: 77297-77300

    • DOI

      10.1039/c6ra18340a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Unusual Colorimetric Change for Alkane Solvents with a Porous Coordination Framework2016

    • Author(s)
      Yohei Takashima, Yasushi Sato, Takaaki Tsuruoka, Kensuke Akamatsu
    • Journal Title

      Inorganic Chemistry

      Volume: 55 Issue: 22 Pages: 11617-11620

    • DOI

      10.1021/acs.inorgchem.6b01754

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Metal nanocrystal/metal-organic framework core/shell nanostructure from selective self-assembly induced by localization of metal ion precursors on nanocrystal surface2015

    • Author(s)
      Takashi Ohhashi, Takaaki Tsuruoka, Tetsuhiro Matsuyama, Yohei Takashima, Hidemi Nawafune, Hideto Minami, Kensuke Akamatsu
    • Journal Title

      Jounal of Colloid and Interface Science

      Volume: 451 Pages: 212-215

    • DOI

      10.1016/j.jcis.2015.03.044

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] ジメチルアミンボランを還元剤として用いた多孔性金属錯体内での金属ナノ粒子合成2017

    • Author(s)
      佐藤泰士、髙嶋洋平、中上まどか、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学(神奈川県、横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] MOF内へのロジウム錯体触媒の固定化と触媒活性評価2017

    • Author(s)
      髙嶋洋平、福原良昌、佐藤泰士、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学(神奈川県、横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] イオン交換反応による均一系錯体触媒のMOFへの固定化と触媒活性評価2016

    • Author(s)
      福原良昌、髙嶋洋平、佐藤泰士、鶴岡孝章、赤松謙祐
    • Organizer
      第18回関西表面技術フォーラム
    • Place of Presentation
      甲南大学(兵庫県、神戸市)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] DMABを気相還元剤として用いたポーラスマトリックス内での金属ナノ構造体形成2016

    • Author(s)
      中上まどか、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      第18回関西表面技術フォーラム
    • Place of Presentation
      甲南大学(兵庫県、神戸市)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Stable immobilization of homogeneous Rh complex catalyst inside metal-organic framework by ion-exchange reaction for improved reactivity and reusability2016

    • Author(s)
      Yohei Takashima, Yoshimasa Fukuhara, Yasushi Sato, Takaaki Tsuruoka, Kensuke Akamatsu
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学(福岡県、福岡市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 多孔性金属錯体/イオン液体複合体の合成と機能2016

    • Author(s)
      佐藤泰士、髙嶋洋平、横山舞、鶴岡孝章、赤松謙祐
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学(福岡県、福岡市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Colorimetric Alkane Sensing using Porous Coordination Framework2016

    • Author(s)
      Yohei Takashima, Yasushi Sato, Takaaki Tsuruoka, Kensuke Akamatsu
    • Organizer
      International Conference on Coordination Chemistry, 2016
    • Place of Presentation
      Brest, France
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 炭化水素ゲスト分子で色調が変化する多孔性金属錯体システムの開発2016

    • Author(s)
      高嶋洋平、佐藤泰士、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] 加圧水素還元による多孔性金属錯体内での金属ナノ粒子合成2016

    • Author(s)
      佐藤泰士、高嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] スルホン酸基を有するMOF細孔内での銀ナノ粒子合成2015

    • Author(s)
      佐藤泰士、高嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      第17回関西表面技術フォーラム
    • Place of Presentation
      甲南大学(兵庫県・神戸市)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Research-status Report
  • [Presentation] 多孔性金属錯体を用いた炭化水素比色センサーの開発2015

    • Author(s)
      高嶋洋平、佐藤泰士、鶴岡孝章、赤松謙祐
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良県・奈良市)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 水素を還元剤として用いた多孔性金属錯体内での金属ナノ粒子精密合成2015

    • Author(s)
      佐藤泰士、高嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良県・奈良市)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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