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Design of novel layered oxyhalide compounds with unusual coordination environment

Research Project

Project/Area Number 15K17837
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

Tsujimoo Yoshihro  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主任研究員 (50584075)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords複合アニオン / 酸ハロゲン化物 / 高圧物性 / スピン転移 / 平面4配位 / 層状ペロフスカイト構造 / バンドギャップ / バンドギャップ絶縁体 / 平面四配位 / 層状化合物 / 複合アニオン化合物 / 酸化物 / ハロゲン / 低次元磁性
Outline of Final Research Achievements

Synthesis, structure and physical properties of new layered perovskite oxyhalides were investigated. We successfully synthesized two new members of oxyhalide phases Sr2MnO3F and Sr2ZnO2Cl2 under high temperature, high pressure condition. In addition, we observed a pressure-driven spin crossover in Sr2CoO3F. Surprisingly, it was found that the spin crossover involved a novel polyhedral transformation from CoO5 pyramid to CoO5F octahedron as a result of covalent-bond formation between Co and F ions.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (22 results)

All 2017 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Acknowledgement Compliant: 4 results,  Open Access: 2 results) Presentation (14 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results) Remarks (2 results)

  • [Int'l Joint Research] ANSTO(オーストラリア)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Paul Scherrer Instiut(スイス)

    • Related Report
      2015 Research-status Report
  • [Journal Article] A layered wide-gap oxyhalide semiconductor with an infinite ZnO2 square planar sheet: Sr2ZnO2Cl22017

    • Author(s)
      Yu Su, Yoshihiro Tsujimoto, Akira Miura, Shinichiro Asai, Maxim Avdeev, Hiraku Ogino, Miho Ako, Alexei A. Belik, Takatsugu Masuda, Tetsuo Uchikoshi, Kazunari Yamaura
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 27 Pages: 3826-3829

    • DOI

      10.1039/c7cc01011g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Pressure-Driven Spin Crossover Involving Polyhedral Transformation in Layered Perovskite Cobalt Oxyfluoride2016

    • Author(s)
      Yoshihiro Tsujimoto, Satoshi Nakano, Naoki Ishimatsu, Masaichiro Mizumaki, Naomi Kawamura, Takateru Kawakami, Yoshitaka Matsushita, Kazunari Yamaura
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 36253-36253

    • DOI

      10.1038/srep36253

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 75.High-Pressure Synthesis, Crystal Structure, and Magnetic Properties of Sr2MnO3F: A New Member of Layered Perovskite Oxyfluorides2016

    • Author(s)
      Yu Su, Yoshihiro Tsujimoto, Yoshitaka Matsushita, Yahua Yuan, Jianfeng He, and Kazunari Yamaura
    • Journal Title

      Inorganic Chemistry

      Volume: 55 Issue: 5 Pages: 2627-2633

    • DOI

      10.1021/acs.inorgchem.5b02984

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 71.Size dependence of structural, magnetic and electrical properties in corundum-type Ti2O3 nanoparticles showing insulator-metal transition2015

    • Author(s)
      Yoshihiro Tsujimoto, Yoshitaka Matsushita, Shan Yu, Kazunari Yamaura, Tetsuo Uchikoshi
    • Journal Title

      Journal of Asian Ceramic Society

      Volume: 3 Issue: 3 Pages: 325-333

    • DOI

      10.1016/j.jascer.2015.06.007

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 配位構造変換を伴う圧力誘起スピン転移現象の観測2017

    • Author(s)
      辻本 吉廣,中野 智志,松下 能孝,山浦 一成,石松 直樹,水牧 仁一郎,河村 直己,川上隆輝
    • Organizer
      日本セラミックス協会2017年年会
    • Place of Presentation
      日本大学駿河台キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 長距離磁気秩序を示さない二次元正方格子磁性体Sr2MnO2Cl2の磁性2017

    • Author(s)
      Su Yu, 辻本 吉廣, 山浦 一成, 浅井 晋一郎, 大久保 毅, 益田 隆嗣, Pomjakushin Vladimir
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 2次元正方格子磁性体Sr2MnO2Cl2のESR測定32017

    • Author(s)
      大久保 晋,高橋 昭彦,太田 仁,原 茂生,櫻井 敬博,松岡 英一,菅原 仁,辻本 吉廣,Su Yu,山浦 一成
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] 2次元正方格子磁性体Sr2MnO2Cl2のmSR2017

    • Author(s)
      岡部 博孝,平石 雅俊,小嶋 健児,竹下 聡史,幸田 章宏,門野 良典,辻本 吉廣, Su Yu, 山浦 一成
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] New Materials Design by Anion-Lattice Engineering2016

    • Author(s)
      Yoshihiro Tsujimoto
    • Organizer
      MRS-J2016年度年次大会
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] Unusual Pressure-Driven Spin Crossover in Layered Cobalt Oxyfluoride2016

    • Author(s)
      Yoshihiro Tsujimoto, Satoshi Nakano, Naoki Ishimatsu, Masaichiro Mizumaki, Naomi Kawamura, Takateru Kawakami, Yoshitaka Matsushita, Kazunari Yamaura
    • Organizer
      AMEC2016
    • Place of Presentation
      GIS TAIPEI TECH Convention Center,Taipei,Taiwan
    • Year and Date
      2016-12-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 2次元正方格子磁性体Sr2MnO2Cl2のESR測定22016

    • Author(s)
      高橋 昭彦,大久保 晋,原 茂生,櫻井 敬博,太田 仁,松岡 英一,菅原 仁,辻本 吉廣,Su Yu,山浦 一成
    • Organizer
      日本物理学会2016年度秋季大会
    • Place of Presentation
      金沢大学角間キャンパス
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 配位数の変化を伴う新奇圧力誘起スピン転移現象2016

    • Author(s)
      辻本 吉廣、中野 智志,山浦 一成,石松 樹,水牧 任一郎,川村 直己
    • Organizer
      第一回固体化学フォーラム研究会:固体物質・材料研究の現在と未来2
    • Place of Presentation
      東京大学柏キャンパス
    • Year and Date
      2016-06-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] S = 2 二次元正方格子反強磁性体Sr2MnO3F2016

    • Author(s)
      辻本 吉廣,Yu Su,松下 能孝,山浦 一成,白 貂大,益田 隆嗣
    • Organizer
      日本物理学会年会
    • Place of Presentation
      東北学院大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 2次元正方格子磁性体Sr2MnO2Cl2のESR測定2016

    • Author(s)
      高橋昭彦、大久保晋、太田仁、櫻井敬博、松岡英一、菅原仁、辻本吉廣、Su Yu、山浦一成
    • Organizer
      日本物理学会年会
    • Place of Presentation
      東北学院大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 低温固相還元法による遷移金属酸化物のナノ構造制御2016

    • Author(s)
      辻本 吉廣
    • Organizer
      日本セラミック協会年会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] High-Pressure Synthesis, Crystal Structure, and Magnetic Properties of Sr2MnO3F2016

    • Author(s)
      Yu Su, Yoshihiro Tsujimoto, Kazunari Yamaura
    • Organizer
      日本セラミック協会年会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 低温固相還元法を用いた遷移金属酸化物ナノクリスタルの創製2015

    • Author(s)
      辻本 吉廣
    • Organizer
      日本セラミックス協会題28回秋季シンポジウム
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] High-Pressure Synthesis, Crystal Structure, and Magnetic Properties of Sr2MnO3F: A New Member of Layered Oxyfluoride Perovskites2015

    • Author(s)
      Yu Su, Yoshihiro Tsujimoto, Kazunari Yamaura
    • Organizer
      日本セラミックス協会題28回秋季シンポジウム
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Remarks] NIMS Researcher Database

    • URL

      http://samurai.nims.go.jp/TSUJIMOTO_Yoshihiro-e.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] NIMS研究者データベスSAMURAI

    • URL

      http://samurai.nims.go.jp/TSUJIMOTO_Yoshihiro-j.html

    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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