| Project/Area Number |
15K17841
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional solid state chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
OKAZAWA Atsushi 東京大学, 大学院総合文化研究科, 助教 (30568275)
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
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| Keywords | 分子性磁性体 / 金属錯体 / 有機ラジカル / 交換相互作用 / 希土類イオン / 構造磁性相関 / マルチラジカルキレート / 分子性固体 / 磁性 / 分子磁石 / 遷移金属錯体 / 強磁性的相互作用 / 結晶構造解析 |
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| Outline of Final Research Achievements |
Toward achieving room-temperature molecular magnets, we developed a novel multiradical and multichelating ligand, which has a chelating ability on multiple radical functional groups, and its polynuclear complexes.
(1) One-dimensional metal complexes were successfully obtained by complexing the radical ligand with copper(II) chloride and bromide. The complexes showed extremely strong metal-radical magnetic couplings (~1000 K) beyond a thermal energy of room temperature, which were clarified by means of magnetic measurements and quantum chemical calculations.
(2) Dinuclear lanthanide(III)-radical complexes were synthesized, where we demonstrated a coordination ability to lanthanide ions on the two radical moieties in the multiradical lingad.
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