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Investigation on property of single molecular junciton by developing shot noise measurement system

Research Project

Project/Area Number 15K17842
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Kaneko Satoshi  東京工業大学, 理学院, 助教 (10738537)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords電子物性 / 単分子接合 / ショットノイズ / 単原子・単分子接合 / 電子輸送 / 物性解明 / ノイズ計測
Outline of Final Research Achievements

In this research, the shot noise measurement system and conductance measurement system for single-atomic/molecule junction were established with a view to clarify the electric property of single-atomic/molecule junction. The established measurement system was applied to the single-atomic/molecule junctions. Especially, the gold atomic contact in the presence of pyrazine molecule showed interesting phenomena.
Gold atomic contact was fabricated using mechanically controllable break junction technique. The shot noise measurements together with the conductance measurement verified that gold atomic contact has the one conductance channel with perfect transmission without pyrazine; on the other hand, it has additional channels with pyrazine. The presence of the additional channel is explained by the interaction between pyrazine and gold.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (26 results)

All 2017 2016 2015 Other

All Journal Article (17 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 16 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (7 results) (of which Int'l Joint Research: 2 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Gap width-independent spectra in ATP surface enhanced Raman scattering stimulated in Au-gap array2017

    • Author(s)
      S. Watanabe, S. Kaneko, S. Fujii, T. Nishino, S. Kasai, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      apanese Journal of Applied Physics

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Single Molecular Junction Study on H2O@C60: H2O is "Electrostatically Isolated"2017

    • Author(s)
      Satoshi Kaneko, Yoshifumi Hashikawa, Shintaro Fujii, Yasujiro Murata, Manabu Kiguchi
    • Journal Title

      Chem. Phys. Chem.

      Volume: 18 Issue: 10 Pages: 1-6

    • DOI

      10.1002/cphc.201700173

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Process and Atomic Structures of Single Pyrazine Molecular Junction by Tuning the Strength of the Metal-Molecule Interaction2017

    • Author(s)
      S. Kaneko, R. Takahashi, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 15 Pages: 9843-9848

    • DOI

      10.1039/c6cp08862g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical control of the plasmon coupling with Au nanoparticle arrays fixed on the elastomeric film via chemical bond2017

    • Author(s)
      E. Bedogni, S. Kaneko, S. Fujii, M. Kiguchi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 56 Issue: 3 Pages: 35201-35201

    • DOI

      10.7567/jjap.56.035201

    • NAID

      210000147477

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Atomic structure of water/Au, Ag, Cu and Pt atomic junction2017

    • Author(s)
      Y. Li, S. Kaneko, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 6 Pages: 4673-4677

    • DOI

      10.1039/c6cp07549e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of the number of atoms present in nano contact based on shot noise measurements with highly stable nano fabricated electrodes2016

    • Author(s)
      R. Takahashi, S. Kaneko, S. M. Gonzaez, S. Fujii, T. Nishino, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      Nanotechnology

      Volume: 27 Issue: 29 Pages: 295203-295203

    • DOI

      10.1088/0957-4484/27/29/295203

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Site selection in single-molecule junction for highly reproducible molecular electronics2016

    • Author(s)
      S. Kaneko, D. Murai, S. Marques-Gonzalez, H. Nakamura, Y. Komoto, S. Fujii, T. Nishino, K. Ikeda, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 4 Pages: 1294-1300

    • DOI

      10.1021/jacs.5b11559

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Surface enhanced Raman scattering of single 1,4-benzendithiol molecular junction2016

    • Author(s)
      S. Kaneko, D. Murai, S. Fujii, M. Kiguchi
    • Journal Title

      Int. J. Mod. Phys. B

      Volume: * Issue: 13 Pages: 1642010-1642010

    • DOI

      10.1142/s0217979216420108

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Evaluation of the energy barrier for failure of Au atomic contact based on temperature dependent current-voltage characteristics2016

    • Author(s)
      A. Aiba S. Kaneko, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 31 Pages: 21586-21589

    • DOI

      10.1039/c6cp03437c

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical Conductance of a Single 1,2-Ethanedithiol Molecular Junction Prepared in2016

    • Author(s)
      E. Bedogni, S. Kaneko, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Chem. Lett.

      Volume: * Issue: 7 Pages: 804-806

    • DOI

      10.1246/cl.160238

    • NAID

      130005252995

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Atomic and Electronic Structures of Single Oxygen Molecular Junction with Au, Ag and Cu Electrodes2016

    • Author(s)
      Y. Li, S. Kaneko, Y. Komoto, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Phys. Chem. C

      Volume: 120 Issue: 29 Pages: 16254-16258

    • DOI

      10.1021/acs.jpcc.6b04862

    • NAID

      130006245143

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the Molecule-Metal Interface on Surface Enhanced Raman Scattering of 1,4-Benzenedithiol Molecule2016

    • Author(s)
      S. Suzuki, S. Kaneko, S. Fujii, S. Marques-Gonzalez, T. Nishino, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 2 Pages: 1038-1042

    • DOI

      10.1021/acs.jpcc.5b10385

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 単分子接合における吸着サイトを認識可能な分光法の開発2016

    • Author(s)
      金子哲,村井大午,小本祐貴,藤井慎太郎,中村恒夫,木口学
    • Journal Title

      表面科学

      Volume: *

    • NAID

      130005165550

    • Related Report
      2015 Research-status Report
  • [Journal Article] Electrical conduction and structure of copper atomic junctions in the presence of water molecules2015

    • Author(s)
      Y. Li, F. Demir, S. Kaneko, S. Fujii, T. Nishino, A. Saffarzadeh, G. Kirczenow, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 48 Pages: 32436-32442

    • DOI

      10.1039/c5cp05227k

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Symmetry of Single Hydrogen Molecular Junction with Au, Ag and Cu Electrodes2015

    • Author(s)
      Y. Li, S. Kaneko, S. Fujii, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 33 Pages: 19143-19148

    • DOI

      10.1021/acs.jpcc.5b04720

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simultaneous Measurement of Electrical Conductance and Thermopower of Single Benzeneditiol Molecular Junctions2015

    • Author(s)
      S.Kaneko, Y. Nakamura, R. Matsushita, S. Marques-Gonzalez, M. Kiguchi
    • Journal Title

      APEX

      Volume: 8 Issue: 6 Pages: 065201-065201

    • DOI

      10.7567/apex.8.065201

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Single naphthalene and anthracene molecular junctions using Ag and Cu electrodes in ultra high vacuum2015

    • Author(s)
      S. Fujii, S. Kaneko, L. Chenyang, and M. Kiguchi
    • Journal Title

      Appl. Surf. Sci

      Volume: 354 Pages: 362-362

    • DOI

      10.1016/j.apsusc.2015.05.071

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 構造が規定されたナノ構造体を利用した4-アミノチオフェノールのプラズモン誘起光化学反応2016

    • Author(s)
      金子哲, 葛西伸哉, 塚越一仁, 木口学
    • Organizer
      光化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Enhancement mechanism for surface-enhanced Raman scattering at metal nanostructures2016

    • Author(s)
      Satoshi Kaneko, Shuhei Watanabe, Manabu Kiguchi
    • Organizer
      ECOSS32
    • Place of Presentation
      Grenoble (France)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 単分子接合における吸着サイト選択的な表面増強ラマン散乱2016

    • Author(s)
      金子哲
    • Organizer
      大阪大学産業科学研究所ナノテクロジーセンター「第3回若手セミナ ー」 ・日本化学会新領域ナノ ス ケール分子デバイス ケール「第5回若手セミナー」
    • Place of Presentation
      梅田まちラボ,大阪府
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report
  • [Presentation] 単分子素子実現に向けた吸着サイト選択的な単分子分光法の開発2016

    • Author(s)
      金子哲,村井大午,中村恒夫,池田勝佳,塚越一仁,木口学
    • Organizer
      応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学,東京都
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 表面増強ラマンスペクトル・電流-電圧特性同時計測による単分子接合の原子・電子構造解析2015

    • Author(s)
      金子 哲,村井 大午,小本 祐貴,塚越 一仁,木口 学
    • Organizer
      真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場,茨城県
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] 金ナノ構造体を用いたベンゼン誘導体の表面増強ラマン散乱の界面構造依存性2015

    • Author(s)
      金子 哲,鈴木 翔,木口 学
    • Organizer
      分子化学討論会
    • Place of Presentation
      東京工業大学,東京都
    • Year and Date
      2015-09-17
    • Related Report
      2015 Research-status Report
  • [Presentation] Electron transport and surface enhanced Raman scattering at structurally well-defined single 1,4-benzenedithiole2015

    • Author(s)
      Satoshi Kaneko, Daigo Murai, Yuki Komoto, Kazuhito Tsukagoshi, Manabu Kiguchi
    • Organizer
      European Conference on Surface Science
    • Place of Presentation
      Centre de Convencions Internacional de Barcelona,Barcelona,Spain
    • Year and Date
      2015-08-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Book] Design and Control of Highly Conductive Single-Molecule Junctions2017

    • Author(s)
      Satoshi Kaneko
    • Total Pages
      84
    • Publisher
      Springer
    • Related Report
      2016 Annual Research Report
  • [Remarks] T2R2 東京工業大学リサーチリポジトリ

    • URL

      http://t2r2.star.titech.ac.jp/cgi-bin/researcherpublicationlist.cgi?q_researcher_content_number=CTT100510428&alldisp=1&tab_yf=2017

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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