Syntheis of novel binaphthol derivatives via remote C-H funcionalization
| Project/Area Number |
15K17859
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nara National College of Technology |
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Principal Investigator |
Kamei Toshiyki 奈良工業高等専門学校, 物質化学工学科, 准教授 (70534452)
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | Ｃ－Ｈ官能基化 / ｐ型半導体 / ペリキサンテノキサンテン / 銅触媒 / 空気酸化 / Ｃ－Ｈ環化反応 / ペリキサンテノキサンテンビスイミド / ｐ型半導体材料 / ｎ型半導体材料 / 多環芳香族化合物 / C－H結合活性化 / 有機半導体材料 |
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| Outline of Final Research Achievements |
Metal-catalyzed functionalization at 8 position of binaphthol proceeded. However, the intramolecular cyclization with hydroxy group was much faster than intermolecular reactions to afford peri-xanthenoxanthene (PXX) preferentially.
Since practical synthesis of PXX did not reported so far, the study was focused on the development of this intramolecular cyclization. As a result, efficient synthesis of PXX was developed using air as the reoxidant.
I disclosed that radical cation of newly synthesized PXX derivatives was found very stable from electrochemical analysis.
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Report
(3 results)
Research Products
(7 results)
