Development of living aryne polymerization and functionality
Project/Area Number |
15K17863
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Polymer chemistry
|
Research Institution | Sagami Chemical Research Institute |
Principal Investigator |
Mikami Koichiro 公益財団法人相模中央化学研究所, その他部局等, 研究員 (40633574)
|
Project Period (FY) |
2015-04-01 – 2017-03-31
|
Project Status |
Completed (Fiscal Year 2016)
|
Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
Keywords | リビング / フェニレン / オルト / アライン / 連鎖 / 銅 / 共役系 / 重合 / ポリフェニレン / 触媒 / π-共役 |
Outline of Final Research Achievements |
Recently we reported that the polymerization of aryne which has a distorted triple bond in the aromatic ring, and is a highly reactive intermediate proceeds to afford poly(ortho-phenylene)s. In this work, I investigated aryne polymerization with living fashion. It was found that the polymerization gave resultant polymers with narrow polydispersity index when organic fluoride sources, or a combination of inorganic fluoride sources and NHC copper catalyst were used. On the other hand, the polymerization with multifunctional monomer gave microporous materials with gas absorption and desorption ability.
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Report
(3 results)
Research Products
(9 results)