• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Biorefinery by using ionic liquids which can shift the structures

Research Project

Project/Area Number 15K17867
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionKanazawa University

Principal Investigator

Kosuke Kuroda  金沢大学, 自然システム学系, 特任助教 (10748891)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsイオン液体 / セルロース / バイオリファイナリー / 動的共有結合 / 疎水性 / 可逆変化 / スイッチング
Outline of Final Research Achievements

Ionic liquids, salts whose melting points are below 374K, show "cellulose-dissolving ability", "good solubility of proteins", and "hydrophobicity" depending on their ion structures. However, one ionic liquid basically cannot show multi-functions. Here I developed a novel ionic liquid which has a dynamic covalent bond. The structure of the ionic liquid shifted by external stimuli and therefore the functions of the ionic liquid were reversibly changed.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (42 results)

All 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (14 results) (of which Int'l Joint Research: 12 results,  Peer Reviewed: 13 results,  Open Access: 5 results,  Acknowledgement Compliant: 3 results) Presentation (19 results) (of which Int'l Joint Research: 14 results,  Invited: 3 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results)

  • [Int'l Joint Research] The State University of New Jersey(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] University of Averiro(Portugal)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] University of Western Australia(Australia)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Efficient hydrolysis of lignocellulose by acidic ionic liquids under low-toxic condition to microorganisms2017

    • Author(s)
      K. Kuroda, K. Inoue, K. Miyamura, H. Satria, K. Takada, K. Ninomiya, K. Takahashi
    • Journal Title

      Catalysts

      Volume: 7 Issue: 4 Pages: 108-108

    • DOI

      10.3390/catal7040108

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Renaturation of cytochrome c dissolved in polar phosphonate-type ionic liquids using highly polar zwitterions2017

    • Author(s)
      K. Kuroda, Y. Kohno, H. Ohno
    • Journal Title

      Chemistry Letters

      Volume: in press Issue: 6 Pages: 870-872

    • DOI

      10.1246/cl.170153

    • NAID

      130005689362

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effective dissolution of biomass in ionic liquids by irradiation of non-thermal atmospheric pressure plasma2017

    • Author(s)
      Kosuke Kuroda, Kai Shimomura, Tatsuo Ishijima, Kazuaki Ninomiya, Kenji Takahashi
    • Journal Title

      Australian Journal of Chemistry

      Volume: 印刷中 Issue: 6 Pages: 731-734

    • DOI

      10.1071/ch16554

    • NAID

      120005860226

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Efficient recovery of ionic liquid by electrodialysis in acid hydrolysis process2017

    • Author(s)
      Takatsugu Endo, Mai Tatsumi, Kosuke Kuroda, Heri Satria, Yumiko Shimada, Kazuaki Ninomiya, Kenji Takahashi
    • Journal Title

      Sep Sci Technol

      Volume: 印刷中 Issue: 7 Pages: 1240-1245

    • DOI

      10.1080/01496395.2017.1281957

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Efficient hydrolysis of polysaccharides in bagasse by in situ synthesis of an acidic ionic liquid after pretreatment2016

    • Author(s)
      Heri Satria, Kosuke Kuroda (co-first author), Takatsugu Endo, Kenji Takada, Kazuaki Ninomiya, Kenji Takahashi
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 5 Issue: 1 Pages: 708-713

    • DOI

      10.1021/acssuschemeng.6b02055

    • NAID

      120005860227

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrolysis of cellulose using an acidic and hydrophobic ionic liquid, and subsequent separation of glucose aqueous solution from the ionic liquid and 5-(hydroxymethyl)furfural2016

    • Author(s)
      Kosuke Kuroda, Kyohei Miyamura, Heri Satria, Kenji Takada, Kazuaki Ninomiya, Kenji Takahashi
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 4 Issue: 6 Pages: 3352-3356

    • DOI

      10.1021/acssuschemeng.6b00420

    • NAID

      120005860228

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Enhanced Hydrolyisis of Lignocellulosic Biomass Assisted by a Combination of Acidic Ionic Liquids and Microwave Heating2016

    • Author(s)
      Kosuke Kuroda, Ken Inoue, Kyohei Miyamura, Kenji Takada, Kazuaki Ninomiya, and Kenji Takahashi
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: in press

    • NAID

      130005405118

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 植物から飛行機をつくる最先端研究室2016

    • Author(s)
      黒田浩介、高橋憲司
    • Journal Title

      イオン液体サーキュラー

      Volume: 6 Pages: 13-14

    • Related Report
      2015 Research-status Report
  • [Journal Article] Effects of polarity, hydrophobicity, and density of ionic liquids on cellulose solubility2015

    • Author(s)
      Mitsuru Abe, Kosuke Kuroda, Daiki Sato, Hiroyuki Ohno
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 17 Issue: 48 Pages: 32276-32282

    • DOI

      10.1039/c5cp05808b

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Polar ionic liquid enables accurate chromatographic analysis of polyelectrolytes2015

    • Author(s)
      Kosuke Kuroda and Hiroyuki Ohno
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 52 Pages: 10551-10553

    • DOI

      10.1039/c5cc02595h

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Molecular weight distributions of polysaccharides and lignin extracted from plant biomass with a polar ionic liquid analysed without a derivatisation process2015

    • Author(s)
      Kosuke Kuroda, Yukinobu Fukaya, Tatsuhiko Yamada, and Hiroyuki Ohno
    • Journal Title

      Analytical Methods

      Volume: 7 Issue: 5 Pages: 1719-1726

    • DOI

      10.1039/c4ay02493a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Application of a Non-thermal Atmospheric Pressure Plasma Jet to the Decomposition of Salicylic Acid to Inorganic Carbon2015

    • Author(s)
      Kosuke Kuroda, Tatsuo Ishijima, Toshiki Kaga, Kai Shiomomura, Kazuaki Ninomiya, Kenji Takahashi
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 11 Pages: 1473-1475

    • DOI

      10.1246/cl.150656

    • NAID

      130005108076

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Maintenance-free cellulose solvents based on onium hydroxides2015

    • Author(s)
      Mitsuru Abe, Kosuke Kuroda, and Hiroyuki Ohno
    • Journal Title

      ACS Sustainable Chemistry and Engineering

      Volume: 3 Issue: 8 Pages: 1771-1776

    • DOI

      10.1021/acssuschemeng.5b00303

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Saccharification and ethanol fermentation from cholinium ionic liquid-pretreated bagasse with a different number of post-pretreatment washings2015

    • Author(s)
      Kazuaki Ninomiya, Sayuri Omote, Chiaki Ogino, Kosuke Kuroda, Mana Noguchi, Takatsugu Endo, Ryohei Kakuchi, Nobuaki Shimizu, Kenji Takahashi
    • Journal Title

      Bioresource Technology

      Volume: 189 Pages: 203-209

    • DOI

      10.1016/j.biortech.2015.04.022

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Extremely biocompatible cellulose solvents: what is the key structure of ionic liquids to satisfy both low toxicity and cellulose dissolution ability?2017

    • Author(s)
      K. Kuroda, K Miyamura, H. Satria, Y. Tsuge, K. Ninomiya, K. Takahashi
    • Organizer
      The 97th Annual Meeting of The Chemical Society of Japan-Asian International Symposium
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Cellulose hydrolysis and simultaneous purification in hydrophobic and acidic ionic liquids2016

    • Author(s)
      K. Kuroda, K. Miyamura, K. Ninomiya, K. Takahashi
    • Organizer
      EMN Meeting on Ionic Liquids
    • Place of Presentation
      Bangkok, Thailand
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 新規カルボン酸系liquid zwitterionによるバイオマスのワンポット発酵2016

    • Author(s)
      黒田浩介・宮村恭平・Heri Satria・仁宮一章・高橋憲司
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢市文化ホール
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオン液体とzwitterionの可逆構造変換への挑戦: 伝導度/親疎水性の制御は可能か?2016

    • Author(s)
      島田悠実子・黒田浩介・仁宮一章・高橋憲司
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢市文化ホール
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Efficient one-pot conversion of biomass to ethanol in liquid zwitterion/ DMSO mixtures2016

    • Author(s)
      Heri Satria・黒田浩介・宮村恭平・仁宮一章・高橋憲司
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢市文化ホール
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] バイオマスのワンポットエタノール発酵に適した新規 Liquid zwitterion の開発2016

    • Author(s)
      宮村恭平・黒田浩介・Heri Satria・仁宮一章・高橋憲司
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢市文化ホール
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオン液体中で合成したリグニン誘導体による炭素繊維/ポリプロピレンの界面強度の変化2016

    • Author(s)
      酒井啓基・室山栞・畑綾乃・高見澤悠太・小島良介・黒田浩介・覚知亮平・高田健司・大道正明・生越友樹・附木貴行・仁宮一章・高橋憲司
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢市文化ホール
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ionic liquids with dynamic covalent bonds: switching between unique physico-chemical properties2016

    • Author(s)
      Y. Shimada, K. Kuroda, K. Ninomiya, K. Takahashi
    • Organizer
      Gordon Research Conference
    • Place of Presentation
      USA
    • Year and Date
      2016-08-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One-pot production of ethanol from biomass using biocompatible liquid zwitterions2016

    • Author(s)
      K. Kuroda, K. Miyamura, H. Satria, K. Ninomiya, K. Takahashi
    • Organizer
      Gordon Research Conference
    • Place of Presentation
      USA
    • Year and Date
      2016-08-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] How can we realize successive processes from lignocellulose to ethanol?2016

    • Author(s)
      K. Kuroda, K. Miyamura, H. Satria, Y. Shimada, D. Sato, H. Ohno, K. Ninomiya, K. Takahashi
    • Organizer
      FILL symposium
    • Place of Presentation
      東京農工大学 工学部
    • Year and Date
      2016-01-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] セルロースを溶解かつ発酵菌への毒性が小さいカルボン酸系zwitterionic liquidの開発2015

    • Author(s)
      黒田浩介・宮村恭平・Heri Satria・仁宮一章・高橋憲司
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス 寒梅館
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
  • [Presentation] イオン液体の密度はセルロース溶解に影響を及ぼす因子であるか?2015

    • Author(s)
      佐藤大樹・阿部充・黒田浩介・大野弘幸
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス 寒梅館
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
  • [Presentation] 疎水生かつ酸性のイオン液体を用いたセルロースの加水分解および発酵可能なグルコース水溶液の回収2015

    • Author(s)
      宮村恭平・黒田浩介・仁宮一章・高橋憲司
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス 寒梅館
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
  • [Presentation] 動的共有結合によって疎水性度を制御可能なイオン液体の合成2015

    • Author(s)
      島田悠実子・黒田浩介・仁宮一章・高橋憲司
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス 寒梅館
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
  • [Presentation] 酸性イオン液体の in situ 合成による高効率なセルロースの加水分解2015

    • Author(s)
      Heri Satria・黒田浩介・仁宮一章・高橋憲司
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス 寒梅館
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
  • [Presentation] HPLC analysis of molecular weight distribution of cellulose and lignin extracted from biomass using ionic liquids2015

    • Author(s)
      Kosuke Kuroda, Kenji Takahashi, Hiroyuki Ohno
    • Organizer
      2nd EuCheMS Congress on Green and Sustainable Chemistry
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] A new class of ionic liquid: reversible change between hydrophilicity and hydrophobicity by means of dynamic covalent bond2015

    • Author(s)
      Yumiko Shimada, Kosuke Kuroda, Kazuaki Ninomiya, Kenji Takahashi
    • Organizer
      2nd EuCheMS Congress on Green and Sustainable Chemistry
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Valorization of lignin dissolved in ionic liquids by non-thermal atmospheric plasma2015

    • Author(s)
      Kai Shimomura, Kosuke Kuroda, Kazuaki Ninomiya, Kenji Takahashi
    • Organizer
      2nd EuCheMS Congress on Green and Sustainable Chemistry
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Hydrolysis of cellulose and recovery of glucose aqueous solution favorable to fermentation by using an acidic and hydrophobic ionic liquid2015

    • Author(s)
      Kyohei Miyamura, Kosuke Kuroda, Kazuaki Ninomiya, Kenji Takahashi
    • Organizer
      2nd EuCheMS Congress on Green and Sustainable Chemistry
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Book] Analytical applications of ionic liquids2016

    • Author(s)
      Kosuke Kuroda, Hiroyuki Ohno
    • Total Pages
      21
    • Publisher
      World Scientific Publishing
    • Related Report
      2016 Annual Research Report
  • [Book] Analytical applications of ionic liquids2016

    • Author(s)
      Kosuke Kuroda, Hiroyuki Ohno
    • Publisher
      Imperial College Press
    • Related Report
      2015 Research-status Report
  • [Remarks] 金沢大学 黒田

    • URL

      http://ionicliquid.w3.kanazawa-u.ac.jp

    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 有機塩、動的共有結合を有する化合物、イオン液体、並びに、可変抵抗器及び抵抗値の制御方法、バイオエタノール製造装置及びバイオエタノールの製造方法2017

    • Inventor(s)
      黒田浩介、高橋憲司
    • Industrial Property Rights Holder
      黒田浩介、高橋憲司
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-022527
    • Filing Date
      2017-02-09
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] イオン液体、グルコースの製造方法およびエタノールの製造方法2015

    • Inventor(s)
      黒田浩介、高橋憲司、宮村恭平、仁宮一章
    • Industrial Property Rights Holder
      黒田浩介、高橋憲司、宮村恭平、仁宮一章
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-06-12
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] エタノールの製造方法2015

    • Inventor(s)
      黒田浩介、高橋憲司、仁宮一章
    • Industrial Property Rights Holder
      黒田浩介、高橋憲司、仁宮一章
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-06-12
    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2022-02-16  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi