Project/Area Number |
15K17879
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Analytical chemistry
|
Research Institution | Toho University (2016) Chuo University (2015) |
Principal Investigator |
|
Research Collaborator |
KATAYAMA Kenji
HOSOKAWA Ryo
NISHIMURA Taisei
YAMAGUCHI Miki
|
Project Period (FY) |
2015-04-01 – 2017-03-31
|
Project Status |
Completed (Fiscal Year 2016)
|
Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
Keywords | 色素増感太陽電池 / 光電変換効率 / 界面 / ダイナミクス / 時間分解分光測定 / ラマン散乱 / 過渡格子法 / 過渡吸収法 / 相界面のダイナミクス |
Outline of Final Research Achievements |
The photon energy conversion interface of dye-sensitized solar cells, titanium oxide (TiO2)/dye/electrolyte interface, has been successfully investigated by using time-resolved spectroscopic method, especially transient absorption and transient grating technique. The transient absorption spectra of dye-sensitized solar cells showed temporal shift due to the interaction between absorbed dyes on the interface and ions in electrolyte, depending on the functional group of dyes and the absorbed manner of them. The surface enhanced Raman spectra of absorbed dyes has also been successfully observed by forming self-assembled metal nanoparticles monolayer on the interface。The obtained Raman spectra included the information about the structure of absorbed dyes, which could use for the evaluation of absorption manner of dyes.
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