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Analytical method for the evaluation of absorbed dyes on energy conversion interface of dye-sensitized solar cells via time-resolved spectroscopic method

Research Project

Project/Area Number 15K17879
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Analytical chemistry
Research InstitutionToho University (2016)
Chuo University (2015)

Principal Investigator

KUWAHARA Shota  東邦大学, 理学部, 講師 (10612658)

Research Collaborator KATAYAMA Kenji  
HOSOKAWA Ryo  
NISHIMURA Taisei  
YAMAGUCHI Miki  
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords色素増感太陽電池 / 光電変換効率 / 界面 / ダイナミクス / 時間分解分光測定 / ラマン散乱 / 過渡格子法 / 過渡吸収法 / 相界面のダイナミクス
Outline of Final Research Achievements

The photon energy conversion interface of dye-sensitized solar cells, titanium oxide (TiO2)/dye/electrolyte interface, has been successfully investigated by using time-resolved spectroscopic method, especially transient absorption and transient grating technique. The transient absorption spectra of dye-sensitized solar cells showed temporal shift due to the interaction between absorbed dyes on the interface and ions in electrolyte, depending on the functional group of dyes and the absorbed manner of them. The surface enhanced Raman spectra of absorbed dyes has also been successfully observed by forming self-assembled metal nanoparticles monolayer on the interface。The obtained Raman spectra included the information about the structure of absorbed dyes, which could use for the evaluation of absorption manner of dyes.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (20 results)

All 2017 2016 2015 Other

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (15 results) (of which Int'l Joint Research: 9 results) Remarks (2 results)

  • [Journal Article] Specific interaction between dyes and ions in dye-sensitized solar cells2017

    • Author(s)
      Ryo Hosokawa, Shota Kuwahara, Kenji Katayama
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 334 Pages: 107-112

    • DOI

      10.1016/j.jphotochem.2016.11.004

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Investigation of Photoexcited Carrier Dynamics in Hematite and the Effect of Surface Modifications by an Advanced Transient Grating Technique2017

    • Author(s)
      Woon Yong Sohn, Shota Kuwahara, James E. Thorne, Dunwei Wang, Kenji Katayama
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 3 Pages: 1031-1035

    • DOI

      10.1021/acsomega.7b00021

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Distinction of electron pathways at titanium oxide/liquid interfaces in photocatalytic processes and co-catalyst effects2016

    • Author(s)
      Shota Kuwahara, Kenji Katayama
    • Journal Title

      Physical Chemistry, Chemical Physics

      Volume: 18 Issue: 36 Pages: 25271-25276

    • DOI

      10.1039/c6cp04016k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Distinction between reactive and non-reactive trap states in photocatalytic reactions revealed by transient grating technique2016

    • Author(s)
      Kenji Katayama, Shota Kuwahara
    • Organizer
      9th Asian Photochemistry Conference
    • Place of Presentation
      Singapore, Singapore
    • Year and Date
      2016-12-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation on Aging Effect for Ruthenium-dye Sensitized Solar Cells with TEMPO Redox Electrolyte2016

    • Author(s)
      Taisei Nisimura, Shota Kuwahara, Kenji Katayama
    • Organizer
      9th Asian Photochemistry Conference
    • Place of Presentation
      Singapore, Singapore
    • Year and Date
      2016-12-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation on a Mechanism of TiO2 Surface Treatment for Solid-state Dye Sensitized Solar Cells2016

    • Author(s)
      Miki Yamaguchi, Shota Kuwahara, Qing Shen, Toyoda Toyoda, Kenji Katayama
    • Organizer
      9th Asian Photochemistry Conference
    • Place of Presentation
      Singapore, Singapore
    • Year and Date
      2016-12-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Distinction between reactive and non-reactive trap states in photocatalytic reactions revealed by transient grating technique2016

    • Author(s)
      Shota Kuwahara, Kenji Katayama
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学駒場第一キャンパス(東京都目黒区)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Distinction between reactive and non-reactive trap states in photocatalytic reactions revealed by transient grating technique2016

    • Author(s)
      Kenji Katayama, Shota Kuwahara
    • Organizer
      SPIE Nanoscience + Engineering, "Physical Chemistry of Interfaces and Nanomaterials XV"
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2016-08-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Distinction between reactive and non-reactive trap states in photocatalytic reactions revealed by transient grating technique2016

    • Author(s)
      Kenji Katayama, Shota Kuwahara
    • Organizer
      32nd Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      大宮ソニックシティ(埼玉県さいたま市)
    • Year and Date
      2016-06-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 過渡格子法を用いたTiO2薄膜上の光触媒反応及び助触媒効果の評価2016

    • Author(s)
      桑原彰太、片山建二
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス, 京都
    • Year and Date
      2016-03-25
    • Related Report
      2015 Research-status Report
  • [Presentation] 固体型色素増感太陽電池のホール輸送層界面におけるキャリア移動過程の解明2016

    • Author(s)
      山口光稀、桑原彰太、沈青、豊田太郎、片山建二
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス, 京都
    • Year and Date
      2016-03-25
    • Related Report
      2015 Research-status Report
  • [Presentation] ニトロキシラジカル電解液を用いた色素増感太陽電池のキャリア移動過程の観測2016

    • Author(s)
      西村泰成、桑原彰太、沈青、豊田太郎、片山建二
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス, 京都
    • Year and Date
      2016-03-25
    • Related Report
      2015 Research-status Report
  • [Presentation] In-situ evaluation of photocatalytic carriers on TiO2/liquid interface with the transient grating method2015

    • Author(s)
      Shota Kuwahara, Kenji Katayama
    • Organizer
      The international chemical congress of pacific basin society 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Investigation on dye-ion interactions in dye-sensitized solar cells using transient absorption spectra2015

    • Author(s)
      Ryo Hosokawa, Shota Kuwahara, Qing Shen, Taro Toyoda, Kenji Katayama
    • Organizer
      The international chemical congress of pacific basin society 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 過渡吸収スペクトルによる色素増感太陽電池の色素-イオン種間の相互作用の観測2015

    • Author(s)
      細川亮、桑原彰太、沈青、豊田太郎、片山建二
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学伊都キャンパス, 福岡
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 過渡格子法を用いた光触媒反応における助触媒効果の評価2015

    • Author(s)
      桑原彰太、片山建二
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学伊都キャンパス, 福岡
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] The effect of adsorbed dyes on carrier dynamics in dye-sensitized solar cell2015

    • Author(s)
      Shota Kuwahara, Keita Omata, Ryo Hosokawa, Taisei Nishimura, Qing Shen, Taro Toyoda, Kenji Katayama
    • Organizer
      RSC Tokyo International Conference 2015
    • Place of Presentation
      幕張メッセ, 千葉
    • Year and Date
      2015-09-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Dye-Iodide Interaction in Dye-Sensitized Solar Cells via Microsecond to Millisecond Transient Absorption Spectroscopy2015

    • Author(s)
      Ryo Hosokawa, Shota Kuwahara, Qing Shen, Taro Toyoda, Kenji Katayama
    • Organizer
      27th International Conference on Photochemistry
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-06-30
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 中央大学理工学部応用化学科 分光システム研究室

    • URL

      http://www.chem.chuo-u.ac.jp/~spec/index.htm

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東邦大学理学部化学科 物性化学教室

    • URL

      http://nano.chem.sci.toho-u.ac.jp/~lab/nanochem/index.html

    • Related Report
      2016 Annual Research Report

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Published: 2015-04-16   Modified: 2018-03-22  

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