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Preparation of Novel Catalyst for Steam Reforming Process

Research Project

Project/Area Number 15K17894
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy-related chemistry
Research InstitutionKitami Institute of Technology

Principal Investigator

Ohno Tomoya  北見工業大学, 工学部, 教授 (90397365)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords液相法 / 触媒ナノ粒子 / ペロブスカイト型酸化物 / 水蒸気改質 / 還元析出 / 液相合成 / 触媒 / ナノ粒子 / エタノール水蒸気改質 / 分散性
Outline of Final Research Achievements

The novel perovskite catalyst for steam reforming process using ethanol was developed by chemical solution deposition with partial reduction process. In general, the subject of the perovskite catalyst has been well known as a low surface area and a low dispersibility of metal catalyst component on the perovskite. As a result, the developed method successfully dissolved the above subjects.
In this study, we selected LaAlO3 as a target material, and Ni and Co was selected as a metal catalyst component. Thus, we prepared La(Al,Ni)O3 and La(Al,Co)O3 by chemical solution deposition. Subsequently, the obtained catalyst was reduced to generate the metal catalyst component on the perovskite catalyst. In conclude, the highest H2 yield was attained at 943 K reduction temperature in the case od La(Al,Co)O3, and the calculated H2 yield and the conversion ratio was 78 % and 99 %, respectively.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2018 2017 2016 2015 Other

All Journal Article (6 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Preparation of metal catalyst component doped perovskite catalyst particle for steam reforming process by chemical solution deposition with partial reduction2018

    • Author(s)
      T. Ohno, S. Ochibe, H. Wachi, S. Hirai, T. Arai, N. Sakamoto, H. Suzuki and T. Matsuda
    • Journal Title

      Adv. Powder Technol.

      Volume: 29 Issue: 3 Pages: 584-589

    • DOI

      10.1016/j.apt.2017.11.030

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 液相法によるハイブリッドナノ粒子の合成2017

    • Author(s)
      大野智也 鈴木久男
    • Journal Title

      化学工業

      Volume: 68 Pages: 72-77

    • NAID

      40021375779

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 液相法によるナノ粒子表面への酸化物材料のナノコーティング2017

    • Author(s)
      大野智也
    • Journal Title

      塗装工学

      Volume: 52 Pages: 4-9

    • NAID

      40021139088

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] 液相法による高表面積を有するペロブスカイト触媒の開発2016

    • Author(s)
      大野智也 松田剛
    • Journal Title

      粉体工学会誌

      Volume: 53 Pages: 436-441

    • NAID

      130005262174

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] ペロブスカイト型触媒ナノ粒子の合成と特性2016

    • Author(s)
      大野智也
    • Journal Title

      工業材料

      Volume: 64 Pages: 46-50

    • Related Report
      2016 Research-status Report
  • [Journal Article] Effect of the reduction condition on the catalytic activity for steam reforming process using Ni doped LaAlO3 nano-particles2016

    • Author(s)
      Tomoya Ohno, Tetsuo Masuda, Shohno Ochibe, Shigeto Hirai, Hisao Suzuki, Takeshi Arai, Naonori Sakamoto, Naoki Wakiya and Takeshi Matsuda
    • Journal Title

      Advanced Powder Technology

      Volume: 27 Issue: 1 Pages: 179-183

    • DOI

      10.1016/j.apt.2015.11.013

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Preparation of Perovskite Catalyst for Steam Reforming Porcess by Chemical Solution Deposition with Partial Reduction,2017

    • Author(s)
      T. Ohno, S. Ochibe, H. Wachi, S. Hirai, T. Matsuda, H. Suzuki
    • Organizer
      The 7th Asian Particle Technology Symposium (APT2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 液相合成したペロブスカイト型酸化物ナノ粒子の水蒸気改質への触媒としての応用2017

    • Author(s)
      和知英樹, 落部奨之, 平井慈人, 松田剛, 坂元尚紀, 脇谷尚樹, 鈴木久男, 大野智也
    • Organizer
      粉体工学会2017年度秋期研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effect of the reduction condition on the catalytic activity for steam reforming process using alkoxide derived perovskite catalyst with partial reduction2017

    • Author(s)
      S. Ochibe, H. Wachi, S. Hirai, T. Matsuda, N. Sakamoto, N. Wakiya, H. Suzuki, T. Ohno
    • Organizer
      The 34th International Japan-Korea Seminar on Ceramics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 還元析出法により作製したペロブスカイト型酸化物触媒の還元温度による触媒特性への影響2016

    • Author(s)
      落部奨之、平井慈人、松田剛、坂元尚紀、脇谷尚樹、鈴木久男、大野智也
    • Organizer
      2016年度 粉体工学会 秋季研究発表会
    • Place of Presentation
      東京都 江東区
    • Year and Date
      2016-11-29
    • Related Report
      2016 Research-status Report
  • [Presentation] 還元析出法により作製したペロブスカイト型酸化物触媒の還元温度による触媒特性への影響2016

    • Author(s)
      落部奨之、松田剛、平井慈人、大野智也
    • Organizer
      平成28年度日本セラミックス協会 東北北海道支部研究発表会
    • Place of Presentation
      札幌、北海道
    • Year and Date
      2016-10-27
    • Related Report
      2016 Research-status Report
  • [Presentation] 還元析出法を用いたペロブスカイト型酸化物触媒の開発2016

    • Author(s)
      大野智也、平井慈人,松田 剛、坂元 尚紀,脇谷 尚樹,鈴木 久男
    • Organizer
      第54回粉体に関する討論会
    • Place of Presentation
      登別、北海道
    • Year and Date
      2016-09-12
    • Related Report
      2016 Research-status Report
  • [Presentation] Preparation of the high performance catalyst for steam reforming process2016

    • Author(s)
      Tomoya Ohno
    • Organizer
      Jozef Stefan Institute Seminar
    • Place of Presentation
      Ljubljana, Slovenia
    • Year and Date
      2016-07-01
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of Novel Catalyst for Steam Reforming Process by Chemical Solution Deposition2015

    • Author(s)
      Tomoya Ohno, Takeshi Matsuda and Hisao Suzuki
    • Organizer
      IUMRS-ICAM2015
    • Place of Presentation
      Jejudo, Korea
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属触媒成分をドープしたLaAlO3触媒の還元条件による触媒特性への影響2015

    • Author(s)
      大野智也、平井慈人、松田剛、坂元尚紀、鈴木久男
    • Organizer
      2015年度粉体工学会秋季研究発表会
    • Place of Presentation
      大阪
    • Year and Date
      2015-10-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Preparation of Novel Catalyst for Steam Reforming Process by Chemical Solution Deposition2015

    • Author(s)
      T. Ohno, T. Matsuda and H. Suzuki
    • Organizer
      The 6th Asian Particle Technology Symposium
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] クリーンな社会へ ~エネルギー・水素~

    • URL

      http://www.kitami-it.ac.jp/wp-content/uploads/2016/03/Okhotskskies23.pdf

    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 空気電池用電極触媒及び空気電池2017

    • Inventor(s)
      大野智也 平井慈人 松田剛
    • Industrial Property Rights Holder
      北見工業大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-128446
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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