• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of NIR light responsible photoelectrodes for water splitting

Research Project

Project/Area Number 15K17895
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy-related chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

MINEGISHI TSUTOMU  東京大学, 大学院工学系研究科(工学部), 准教授 (40512992)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords水素 / 太陽光 / 人工光合成 / カルコゲナイド / 光電気化学 / 光カソード / カルコパイライト / 近赤外光応答 / 光触媒 / エネルギー変換 / 表面修飾 / 水分解 / エネルギーキャリア / 薄膜
Outline of Final Research Achievements

In the research project “Development of NIR light responsible photoelectrodes for water splitting”, photoelectrochemical materials with long absorption edge were investigated.
CuInSe2 showed considerably long absorption edge of over 1200 nm with significantly high onset potential of 0.7 V vs. RHE in hydrogen evolution from water.
In addition, we developed solid solution of ZnSe and Cu(In,Ga)Se2 (ZnSe:CIGS) as a photocathode material. ZnSe:CIGS was found to be the promising material for hydrogen evolution from water under sunlight. Because, the photocathode composed of the solid solution showed high onset potential of 0.9 V vs. RHE and long absorption edge on about 900 nm.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (21 results)

All 2017 2016 2015 Other

All Int'l Joint Research (1 results) Journal Article (11 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 11 results,  Acknowledgement Compliant: 7 results,  Open Access: 2 results) Presentation (9 results) (of which Int'l Joint Research: 5 results,  Invited: 3 results)

  • [Int'l Joint Research] UNIST/POSTECH(韓国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Enhancement of charge separation and hydrogen evolution on particulate La5Ti2CuS5O7 photocathodes by surface modification2017

    • Author(s)
      Jingyuan Liu, Takashi Hisatomi, Dharmapura H. K. Murthy, Miao Zhonga, Mamiko Nakabayashi, Tomohiro Higashia, Yohichi Suzuki, Hiroyuki Matsuzaki, Kazuhiko Seki, Akihiro Furube, Naoya Shibata, Masao Katayama, Tsutomu Minegishi, Kazunari Domen
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 8 Issue: 2 Pages: 375-379

    • DOI

      10.1021/acs.jpclett.6b02735

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photoelectrochemical hydrogen evolution from water on a surface modified CdTe thin film electrode under simulated sunlight2017

    • Author(s)
      Jin Su, Tsutomu Minegishi, Masao Katayama, Kazunari Domen
    • Journal Title

      J. Mater. Chem. A

      Volume: 5 Issue: 9 Pages: 4486-4492

    • DOI

      10.1039/c6ta10490h

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Concentrated Methylcyclohexane as Hydrogen Carrier through Photoelectrochemical Conversion of Toluene and Water2017

    • Author(s)
      Yosuke Kageshima, Tsutomu Minegishi, Takashi Hisatomi, Tsuyoshi Takata, Jun Kubota, and Kazunari Domen
    • Journal Title

      ChemSusChem

      Volume: 10 Issue: 4 Pages: 659-663

    • DOI

      10.1002/cssc.201601758

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhanced Hydrogen Evolution under Simulated Sunlight from Neutral Electrolytes on (ZnSe)0.85 (CuIn0.7 Ga0.3 Se2 )0.15 Photocathodes Prepared by a Bilayer Method2016

    • Author(s)
      Kaneko H, Minegishi T, Nakabayashi M, Shibata N, Domen K
    • Journal Title

      Angewandte Chemie (International ed. in English)

      Volume: 55 Issue: 49 Pages: 15329-15333

    • DOI

      10.1002/anie.201609202

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Novel Photocathode Material for Sunlight-Driven Overall Water Splitting: Solid Solution of ZnSe and Cu(In,Ga)Se22016

    • Author(s)
      Hiroyuki Kaneko, Tsutomu Minegishi, Mamiko Nakabayashi, Naoya Shibata,Yongbo Kuang, Taro Yamada, and Kazunari Domen
    • Journal Title

      Adv. Funct. Mater.

      Volume: 26 Issue: 25 Pages: 4570-4577

    • DOI

      10.1002/adfm.201600615

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure, Electronic Structure, and Photocatalytic Activity of Oxysulfides: La2Ta2ZrS2O8, La2Ta2TiS2O8, and La2Nb2TiS2O82016

    • Author(s)
      Goto, Yosuke; Seo, Jeongsuk; Kumamoto, Kazunori; Hisatomi, Takashi; Mizuguchi, Yoshikazu; Kamihara, Yoichi
    • Journal Title

      Inorganic Chemistry

      Volume: 55 Issue: 7 Pages: 3674-3679

    • DOI

      10.1021/acs.inorgchem.6b00247

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A SrTiO3 photoanode prepared by the particle transfer method for oxygen evolution from water with high quantum efficiencies2016

    • Author(s)
      Ham, Y.; Minegishi, T.; Hisatomi, T.; Domen, K.
    • Journal Title

      Chemical Communications

      Volume: 52 Issue: 28 Pages: 5011-5014

    • DOI

      10.1039/c6cc00497k

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Overall Photoelectrochemical Water Splitting using Tandem Cell under Simulated Sunlight2016

    • Author(s)
      Kim, J.; Kaneko, H.; Minegishi, T.; Kubota, J.; Domen, k.; Lee, J.
    • Journal Title

      Chemsuschem

      Volume: 9 Issue: 1 Pages: 61-66

    • DOI

      10.1002/cssc.201501401

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of particle size of La5Ti2CuS5O7 on photoelectrochemical properties in solar hydrogen evolution2016

    • Author(s)
      Liu, J.; Hisatomi, T.; Katayama, M.;Minegishi, T.; Kubota, J.; Domen, K.
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 4 Issue: 13 Pages: 4848-4854

    • DOI

      10.1039/c5ta10731h

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Mg-Zr Cosubstituted Ta3N5 Photoanode for Lower-Onset-Potential Solar-Driven Photoelectrochemical Water Splitting2015

    • Author(s)
      Seo, Jeongsuk; Takata, Tsuyoshi; Nakabayashi, Mamiko; Hisatomi, Takashi; Shibata, Naoya; Minegishi, Tsutomu; Domen, Kazunari
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Issue: 40 Pages: 12780-12783

    • DOI

      10.1021/jacs.5b08329

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chalcopyrite Thin Film Materials for Photoelectrochemical2015

    • Author(s)
      Kaneko, H.; Minegishi, T.; Domen, K.
    • Journal Title

      coatings

      Volume: 5 Issue: 3 Pages: 293-311

    • DOI

      10.3390/coatings5030293

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Photocatalytic Materials for Solar Hydrogen Production from Water2016

    • Author(s)
      Tsutomu Minegishi
    • Organizer
      International Symposium on Dynamic Process of Chemical Reaction and Catalysis on Surfaces
    • Place of Presentation
      Xiamen, China
    • Year and Date
      2016-12-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photoelectrodes for sunlight driven fuel production2016

    • Author(s)
      Tsutomu Minegishi
    • Organizer
      The 6th Sino-Japan Young Chemists Forum
    • Place of Presentation
      Dalian, China
    • Year and Date
      2016-06-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Solar Hydrogen Production from Water on Chalcogenide Photocathodes2016

    • Author(s)
      Tsutomu Minegishi, Kazunari Domen
    • Organizer
      13th International Conference on the Chemistry of Selenium and Tellurium
    • Place of Presentation
      岐阜, 長良川国際会議場
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ZnSe-CIGS薄膜光カソードの光電気化学特性への調製条件の効果2016

    • Author(s)
      兼古寛之・嶺岸耕・堂免一成
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      京都府京田辺市同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] La5Ti2Cu1-xAgxS5O7固溶体粉末の合成と可視光照射下における光電気化学的水分解反応への応用2016

    • Author(s)
      久富隆史、岡村晋太郎、劉セイ媛、篠原雄貴、植田紘一郎、東智弘、片山正士、嶺岸耕、堂免一成
    • Organizer
      第117回触媒討論会
    • Place of Presentation
      大阪府堺市大阪府立大学
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Hydrogen Evolution from Water using Cu(In,Ga)Se2 Photocathodes Modified With Nanometer-thick Conductor Layers2015

    • Author(s)
      Minegishi, T.; Kumagai, H.; Domen, K.
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      ホノルル(アメリカ)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photoelectrochemical properties BaTaO2N/BaTiO3/Ti photoanode2015

    • Author(s)
      Su, J.;Minegishi, T.; Domen, K.
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重県津市三重大学
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 吸収端を1240 nmにもつCuInSe2薄膜光カソードによる水からの水素発生2015

    • Author(s)
      杉﨑 匠・嶺岸 耕・兼古 寛之・堂免 一成
    • Organizer
      第34回光がかかわる触媒化学シンポジウム
    • Place of Presentation
      東京都目黒区東京工業大学
    • Year and Date
      2015-06-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Photoelectrochemical Water Reduction Using CuInSe2 Electrodes with Absorption Edge of 1240 nm2015

    • Author(s)
      Sugisaki, S.; Minegishi, T.; Domen, K.
    • Organizer
      The 7th Seminar of A3 Foresight Program
    • Place of Presentation
      大連(中国)
    • Year and Date
      2015-05-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi