Development of photo-functional polyhedron-shaped supramolecular complexes and applied them as the high efficient hydrogen evolution catalysts
| Project/Area Number |
15K17897
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Energy-related chemistry
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| Research Institution | Shimane University |
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Principal Investigator |
KATAOKA Yusuke 島根大学, 総合理工学研究科, 助教 (20725543)
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| Research Collaborator |
HANDA Makoto
YANO Natsumi
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 水素発生 / 金属錯体 / 超分子錯体 / 量子化学計算 / 人工光合成 / 多核金属錯体 / 水素生成 |
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| Outline of Final Research Achievements |
In this project, the polyhedron-shape metal complexes with paddlewheel-type dirhodium nodes as a building block have developed and applied as a hydrogen evolution catalyst (HEC) for photochemical water reduction. Molecular structures of their complexes were determined by the single crystal X-ray diffraction analyses. These complexes evolved molecular hydrogen in the presence of cyclometalated iridium complex and triethylamone, which were worked as a photosensitizer and a reducing agent, respectively.
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Report
(4 results)
Research Products
(45 results)
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[Journal Article] Paddlewheel-Type Dirhodium Tetrapivalate Based Coordination Polymer: Synthesis, Characterization, and Self-Assembly and Disassembly Transformation Properties2016
Author(s)
Yusuke Kataoka, Natsumi Yano, Takashi Shimodaira, Yin-Nan Yan, Mikio Yamasaki, Hidekazu Tanaka, Koji Omata, Tatsuya Kawamoto, and Makoto Handa
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Journal Title
European Journal of Inorganic Chemistry
Volume: -
Issue: 17
Pages: 2810-2815
DOI
Related Report
Peer Reviewed
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