| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Outline of Final Research Achievements |
In this project, the polyhedron-shape metal complexes with paddlewheel-type dirhodium nodes as a building block have developed and applied as a hydrogen evolution catalyst (HEC) for photochemical water reduction. Molecular structures of their complexes were determined by the single crystal X-ray diffraction analyses. These complexes evolved molecular hydrogen in the presence of cyclometalated iridium complex and triethylamone, which were worked as a photosensitizer and a reducing agent, respectively.
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