Research Project
Grant-in-Aid for Young Scientists (B)
NMR analyses for gas molecules in energy materials and devices have been important from the viewpoints of global climate and clean energy. In this work, we showed (1) NMR analyses of dynamics and local structure of gas molecules in the pores of porous coordination polymers and (2) hyperpolarization NMR of guest molecules in the pores. We found a concept to immobilize CO2 in the pores utilizing rotational organic ligands and magnetization transfer from proton of the porous coordination polymer to carbon of CO2.
All 2017 2016
All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (7 results) (of which Invited: 2 results)
J. Am. Chem. Soc.
Volume: 138 Issue: 27 Pages: 8505-8511
10.1021/jacs.6b03625
