Hyperpolarization NMR of gas molecules in porous coordination polymers
| Project/Area Number |
15K17902
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic and hybrid materials
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| Research Institution | The University of Tokushima |
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Principal Investigator |
Inukai Munehiro 徳島大学, 大学院理工学研究部, 講師 (60537124)
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | 核磁気共鳴 / 多孔性配位高分子 |
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| Outline of Final Research Achievements |
NMR analyses for gas molecules in energy materials and devices have been important from the viewpoints of global climate and clean energy. In this work, we showed (1) NMR analyses of dynamics and local structure of gas molecules in the pores of porous coordination polymers and (2) hyperpolarization NMR of guest molecules in the pores. We found a concept to immobilize CO2 in the pores utilizing rotational organic ligands and magnetization transfer from proton of the porous coordination polymer to carbon of CO2.
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Report
(3 results)
Research Products
(8 results)
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[Journal Article] Encapsulating Mobile Proton Carriers into Structural Defects in Coordination Polymer Crystals: High Anhydrous Proton Conduction and Fuel Cell Application2016
Author(s)
Munehiro Inukai, Satoshi Horike, Tomoya Itakura, Ryota Shinozaki, Naoki Ogiwara, Daiki Umeyama, Sanjog Nagarkar, Yusuke Nishiyama, Michal Malon, Akari Hayashi, Takashi Ohhara, Ryoji Kiyanagi, Susumu Kitagawa
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Journal Title
J. Am. Chem. Soc.
Volume: 138
Issue: 27
Pages: 8505-8511
DOI
Related Report
Peer Reviewed
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