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Development of composite electrodes based on oxides with perovskite-related structures for oxygen reduction reaction

Research Project

Project/Area Number 15K17916
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionKyoto University

Principal Investigator

Matsui Toshiaki  京都大学, 工学研究科, 准教授 (90378802)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords燃料電池 / ヘテロ界面 / 酸素還元電極触媒 / ペロブスカイト関連化合物
Outline of Final Research Achievements

In this study, composite electrodes based on oxides with perovskite-related structures were developed in order to reduce the electrode overpotential for oxygen reduction reaction of solid oxide fuel cells. This is because these oxide can take various crystal structures such as ABO3, A2BO4 and AA’B2O5+δ and readily form the heterointerface. We found that the oxygen surface exchange rate was accelerated at the heterointerface of (Sm,Sr)CoO3-δ/(Sm,Sr)2CoO4±δ. Thus, the introduction of heterointerface with the optimal mixed composition is the promising design guide of air electrode with high performance.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (3 results)

All 2016 2015

All Presentation (3 results)

  • [Presentation] Effect of Heterointerface on Cathode Performance of Solid Oxide Fuel Cells:(Sm, Sr)CoO3-Based Oxide2016

    • Author(s)
      K. Manriki, H. Muroyama, T. Matsui, K. Eguchi
    • Organizer
      PRiME2012: 第6回日米合同大会(2016年 電気化学秋季大会)
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
  • [Presentation] ヘテロ界面を有する(Sm,Sr)CoO3系空気極の特性評価2016

    • Author(s)
      万力皐平,室山広樹,松井敏明,江口浩一
    • Organizer
      第5回 JACI/GSCシンポジウム
    • Place of Presentation
      ANAクラウンプラザホテル神戸
    • Year and Date
      2016-06-02
    • Related Report
      2016 Annual Research Report
  • [Presentation] Effect of Heterointerface on Oxygen Reduction Kinetics of (Sm,Sr)CoO3-Based Electrodes2015

    • Author(s)
      H. Muroyama, H. Kanazawa, T. Okanishi, T. Matsui, K. Eguchi
    • Organizer
      20th International conference on Solid State Ionics
    • Place of Presentation
      Keystone, USA
    • Year and Date
      2015-06-14
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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