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Synthesis of small diameter single-walled carbon nanotubes and their application in Si heterojunction solar cells

Research Project

Project/Area Number 15K17984
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thermal engineering
Research InstitutionThe University of Tokyo

Principal Investigator

XIANG Rong  東京大学, 大学院工学系研究科(工学部), 助教 (20740096)

Co-Investigator(Renkei-kenkyūsha) MARUYAMA Shigeo  東京大学, 大学院工学研究科, 教授 (90209700)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsカーボンナノ材料 / ナノチューブ / 合成制御 / 太陽電池 / 透過型電子顕微鏡 / single-walled CNT / catalyst / Co-W / chirality / solar cell / carbon nanotube / Band gap engineering / TEM
Outline of Final Research Achievements

Single-walled carbon nanotubes (SWNTs) are representative 1D nano-material and possess many exceptional properties. Many applications have bee proposed. In this project, we focus on two issues in SWNT research. First, we performed diameter and chirality controlled synthesis of SWNTs. Sub-nm vertically aligned SWNTs are obtained from Co-Cu catalyst, and (12,6) enriched SWNTs are successfully synthesized from sputter Co-W catalyst. Second, we introduced VA-SWNT in a solar cell as the replacement of metal transparent conductive electrode. The SWNTs based are found to be effective in a solar cell with power conversion efficiency of 10%. This value can be further improved to about 12% by putting a PMMA coating layer.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (20 results)

All 2017 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (10 results) (of which Int'l Joint Research: 10 results,  Peer Reviewed: 10 results,  Open Access: 1 results,  Acknowledgement Compliant: 6 results) Presentation (6 results) (of which Int'l Joint Research: 6 results) Remarks (2 results)

  • [Int'l Joint Research] MIT/Vanderbilt University(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Zhejiang University(China)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Morphology dependence of the thermal transport properties of single-walled carbon nanotube thin films2017

    • Author(s)
      S. Yoshida, Y. Feng, C. Delacou, T. Inoue, R. Xiang, R. Kometani, S. Chiashi, E. Kauppinen, S. Maruyama
    • Journal Title

      Nanotechnology

      Volume: 28 Issue: 18 Pages: 185701-185701

    • DOI

      10.1088/1361-6528/aa6698

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Extended alcohol catalytic chemical vapor deposition for efficient growth of single-walled carbon nanotubes thinner than (6,5)2017

    • Author(s)
      B. Hou, C. Wu, T. Inoue, S. Chiashi, R. Xiang, S. Maruyama
    • Journal Title

      Carbon

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Chirality specific and spatially uniform synthesis of single-walled carbon nanotubes from a sputtered Co-W bimetallic catalyst2016

    • Author(s)
      H. An, A. Kumamoto, H. Takezaki, S. Ohyama, Y. Qian, T. Inoue, Y. Ikuhara, S. Chiashi, R. Xiang, S. Maruyama
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 30 Pages: 14523-14529

    • DOI

      10.1039/c6nr02749k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Chemical vapor deposition growth of large single-crystal bernal-stacked bilayer graphene from ethanol2016

    • Author(s)
      X. Chen, R. Xiang, P. Zhao, H. An, T. Inoue, S. Chiashi, S. Maruyama
    • Journal Title

      Carbon

      Volume: 8 Pages: 14523-14529

    • DOI

      10.1016/j.carbon.2016.06.078

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Load Dependent Frictional Response of Vertically Aligned Single-Walled Carbon Nanotube Films2016

    • Author(s)
      A. S. Westover, J. Choi, K. Cui, T. Ishikawa, T. Inoue, R. Xiang, S. Chiashi, T. Kato, S. Maruyama, C. L. Pint
    • Journal Title

      Scripta Materialia

      Volume: 125 Pages: 63-67

    • DOI

      10.1016/j.scriptamat.2016.07.032

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Epitaxial nucleation of CVD bilayer graphene on copper2016

    • Author(s)
      Y. Song, J. Zhuang, M. Song, S. Yin, Y. Cheng, X. Zhang, M. Wang, R. Xiang, Y. Xia, S. Maruyama, P. Zhao*, F. Ding, H. Wang,
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 48 Pages: 20001-20007

    • DOI

      10.1039/c6nr04557j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Room Temperature-processed Inverted Organic Solar Cells using High Working-Pressure-Sputtered ZnO film2016

    • Author(s)
      I. Jeon, Y. Qian, S. Nakao, D. Ogawa, R. Xiang, T. Inoue, S. Chiashi, T. Hasegawa, S. Maruyama, Y. Matsuo
    • Journal Title

      J. Mater. Chem. A

      Volume: 4 Issue: 48 Pages: 18763-18768

    • DOI

      10.1039/c6ta08068e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of subnanometer-diameter vertically aligned single-walled carbon nanotubes with copper-anchored cobalt catalysts2016

    • Author(s)
      K. Cui, A. Kumamoto, R. Xiang, H. An, B. Wang, T. Inoue, S. Chiashi, Y. Ikuhara, S. Maruyama†
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 3 Pages: 1608-1617

    • DOI

      10.1039/c5nr06007a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chemical Vapor Deposition Growth of Graphene and Related Materials2015

    • Author(s)
      R. Kitaura, Y. Miyata, R. Xiang, J. Hone, J. Kong, R. S Ruoff, S. Maruyama
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 84 Issue: 12 Pages: 121013-121013

    • DOI

      10.7566/jpsj.84.121013

    • NAID

      210000133753

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chemical Vapor Deposition Growth of 5 mm Hexagonal Single-Crystal Graphene from Ethanol2015

    • Author(s)
      X. Chen, P. Zhao, R. Xiang, S. Kim, J. Cha, S. Chiashi, S. Maruyama
    • Journal Title

      Carbon

      Volume: 94 Pages: 810-814

    • DOI

      10.1016/j.carbon.2015.07.045

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Controlled synthesis of single-walled carbon nanotubes using alcohol catalytic chemical vapor deposition2017

    • Author(s)
      Rong Xiang
    • Organizer
      The 6th International Symposium on Micro and Nano Technology (ISMNT)
    • Place of Presentation
      Kyushu University (Fukuoka, Japan)
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bimetallic Catalyst for Chirality and Diameter Controlled Growth of Single-walled Carbon Nanotubes2016

    • Author(s)
      Rong Xiang, Akihito Kumamoto, Hua An, Taiki Inoue, Shohei Chiashi, Yuichi Ikuhara, Shigeo Maruyama
    • Organizer
      International Symposium on Carbon Nanotube in Commemoration of its Quarter-century Anniversary (CNT25)
    • Place of Presentation
      Tokyo Institute of Technology (Meguro-ku, Tokyo, Japan)
    • Year and Date
      2016-11-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In-Plane TEM Imaging of Bimetallic Catalyst for SWNT Growth2016

    • Author(s)
      Rong Xiang, Akihito Kumamoto, Hua An, Taiki Inoue, Shohei Chiashi, Yuichi Ikuhara, Shigeo Maruyama
    • Organizer
      The 51st The Fullerenes-Nanotubes-Graphene General Symposium
    • Place of Presentation
      Hokkaido citizens actives center (Sapporo, Hokkaido, Japan)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modulating diameter of single-walled carbon nanotubes in alcohol catalytic chemical vapor deposition2015

    • Author(s)
      Rong Xiang, Kehang Cui, Akihito Kumamoto, Hua An, Taiki Inoue, Shohei Chiashi, Yuichi Ikuhara, Shigeo Maruyama
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] In-plane TEM investigation on mono- and bi- metallic catalyst for growth of single walled carbon nanotubes2015

    • Author(s)
      Rong Xiang, Akihito Kumamoto, Kehang Cui, Hua An, Yang Qian, Taiki Inoue, Shohei Chiashi, Yuichi Ikuhara, Shigeo Maruyama
    • Organizer
      The 49th Fullerenes-Nanotubes-Graphene General Symposium
    • Place of Presentation
      Kitakyushu International Conference Center, Kita-Kyushu, Fukuoka Prefecture, Japan
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Modulating diameter of single-walled carbon nanotubes in alcohol catalytic chemical vapor deposition2015

    • Author(s)
      Rong Xiang, Kehang Cui, Akihito Kumamoto, Hua An, Taiki Inoue, Shohei Chiashi, Yuichi Ikuhara, Shigeo Maruyama
    • Organizer
      The Sixteenth International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Nagoya University, Nagoya, Aichi Prefecture, Japan
    • Year and Date
      2015-06-29
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] HP of research group

    • URL

      http://www.photon.t.u-tokyo.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] Personal research webpage

    • URL

      http://www.photon.t.u-tokyo.ac.jp/~xiangrong/index.htm

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2022-02-16  

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