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Cavity-enhanced absorption spectroscopy for high-temperature chemical kinetics

Research Project

Project/Area Number 15K17991
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thermal engineering
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Matsugi Akira  国立研究開発法人産業技術総合研究所, 安全科学研究部門, 主任研究員 (90634668)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords高温化学反応 / 燃焼反応 / 衝撃波管 / 広帯域キャビティ増幅吸収分光法
Outline of Final Research Achievements

A novel method for studying high temperature reaction kinetics has been developed and applied to some high temperature reactions. In this method, transient absorption spectra of shock-heated sample gases are recorded by using broadband cavity-enhanced absorption spectroscopy technique. Kinetics of thermal decomposition reaction of nitrogen dioxide and formation and decomposition reactions of formaldehyde have been studied by using the method developed. The results demonstrated the applicability of the method to kinetic studies of high-temperature reactions. The method has also been applied to investigate the high-temperature reactions of nitromethane, benzyl radical, and anisole, for which new kinetic and mechanistic insights have been obtained.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (7 results)

All 2017 2016 2015

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (5 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Time-Resolved Broadband Cavity-Enhanced Absorption Spectroscopy behind Shock Wave2016

    • Author(s)
      Akira Matsugi, Hiroumi Shiina, Tatsuo Oguchi, Kazuo Takahashi
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 120 Issue: 13 Pages: 2070-2077

    • DOI

      10.1021/acs.jpca.6b01069

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Collisional energy transfer in polyatomic molecules at high temperatures: Master equation analysis of vibrational relaxation of shock-heated alkanes2015

    • Author(s)
      A. Matsugi
    • Journal Title

      Chemical Physics Letters

      Volume: 635 Pages: 295-300

    • DOI

      10.1016/j.cplett.2015.06.084

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ニトロメタンの気相熱分解と生成物の再結合反応2017

    • Author(s)
      松木 亮、椎名 拡海
    • Organizer
      平成28年度衝撃波シンポジウム
    • Place of Presentation
      ヴェルクよこすか(神奈川県横須賀市)
    • Year and Date
      2017-03-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] A Sensitive and Broadband Transient Absorption Spectroscopy for High-Temperature Reaction Kinetics2016

    • Author(s)
      Akira Matsugi
    • Organizer
      International Discussion Meeting on Chemical Kinetics for Aerospace Applications
    • Place of Presentation
      Indian Institute of Science (Bangalore, India)
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ベンジルラジカルの熱分解について2016

    • Author(s)
      松木 亮
    • Organizer
      第54回燃焼シンポジウム
    • Place of Presentation
      仙台国際センター(宮城県仙台市)
    • Year and Date
      2016-11-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] Thermal Decomposition of Nitromethane Studied by Cavity-Enhanced Absorption Spectroscopy behind Shock Waves2016

    • Author(s)
      Akira Matsugi and Hiroumi Shiina
    • Organizer
      32nd Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      大宮ソニックシティ(埼玉県大宮市)
    • Year and Date
      2016-06-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 衝撃波管/時間分解広帯域キャビティ増幅吸収分光法2016

    • Author(s)
      松木 亮、椎名 拡海、小口 達夫、高橋 和夫
    • Organizer
      平成27年度衝撃波シンポジウム
    • Place of Presentation
      熊本大学
    • Year and Date
      2016-03-07
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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