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Direct imaging of dopant intercalation in two-dimensional materials

Research Project

Project/Area Number 15K18202
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Physical properties of metals/Metal-base materials
Research InstitutionThe University of Tokyo

Principal Investigator

Ishikawa Ryo  東京大学, 大学院工学系研究科(工学部), 助教 (20734156)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsインターカレーション / 電子顕微鏡 / 単原子ドーパント / 蛍光体 / 走査透過型電子顕微鏡 / 二次元物質 / 低加速電子顕微鏡法 / 原子分解能 / モアレ
Outline of Final Research Achievements

After the success of GaN in blue-light-emission, researchers are exploring new materials for optoelectronic devises working in ultraviolet or far-ultraviolet wavelength ranges. In this study, we have investigated hexagonal boron nitride (h-BN) with doping rare-earth elements, exhibiting light luminescence. To elucidate the origin of light emission, we have used atomic-resolution scanning transmission electron microscopy, suggesting that the heavy dopants are location not in the lattice but between inter-layers: the dopants are intercalating. This result indicates that layer compounds could be useful to dope functional elements with relatively larger ionic radii compared to the bulk constituent elements.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (40 results)

All 2017 2016 2015 Other

All Int'l Joint Research (5 results) Journal Article (19 results) (of which Int'l Joint Research: 16 results,  Peer Reviewed: 19 results,  Open Access: 9 results,  Acknowledgement Compliant: 4 results) Presentation (16 results) (of which Int'l Joint Research: 7 results,  Invited: 6 results)

  • [Int'l Joint Research] Technische University Darmstadt/Deutsches Elektronen-Synchrotron DESY/University Bayreuth(ドイツ)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Oak Ridge National Laboratory(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Peking University/Xiamen University(中国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] National University of Singapore(シンガポール)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Monash University(オーストラリア)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Direct visualization of lithium via annular bright field scanning transmission electron microscopy: a review2017

    • Author(s)
      S.D. Findlay, R. Huang, R. Ishikawa, N. Shibata, Y. Ikuhara
    • Journal Title

      Microscopy

      Volume: 66 Pages: 3-14

    • DOI

      10.1093/jmicro/dfw041

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A new method to detect and correct sample tilt in scanning transmission electron microscopy bright-field imaging2017

    • Author(s)
      H. Brown, R. Ishikawa, G. Sánchez-Santolino, N. Lugg, Y. Ikuhara, L.J. Allen, N. Shibata,
    • Journal Title

      Ultamicroscopy

      Volume: 137 Pages: 76-83

    • DOI

      10.1016/j.ultramic.2016.11.024

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomic-scale tracking of a phase transition from spinel to rocksalt in lithium manganese oxide2017

    • Author(s)
      P. Gao, R. Ishikawa, E. Tochigi, A. Kumamoto, N. Shibata and Y. Ikuhara
    • Journal Title

      Chem. Mater.

      Volume: 29 Issue: 3 Pages: 1006-1013

    • DOI

      10.1021/acs.chemmater.6b03659

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Transparent polycrystalline cubic silicon nitride.2017

    • Author(s)
      N. Nishiyama, R. Ishikawa, H. Ohfuji, H. Marquardt, A. Kurnosov, T. Taniguchi, B.-N. Kim, H. Yoshida, A. Masuno, J. Bednarcik, E. Kulik, Y. Ikuhara, F. Wakai, T. Irifune
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 44755-44755

    • DOI

      10.1038/srep44755

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] One-pot synthesis of a C/SiFeN(O)-based ceramic paper with in-situ generated hierarchical micro/nano-morphology2017

    • Author(s)
      C. Zhou, C. Fasel, R. Ishikawa, M. Gallei, Y. Ikuhara, H-J. Kleebe, R. Riedel, E. Ionescue
    • Journal Title

      Journal of European Ceramic Society

      Volume: 印刷中 Issue: 16 Pages: 5193-5203

    • DOI

      10.1016/j.jeurceramsoc.2017.03.007

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Full Picture Discovery for Mixed-Fluorine Anion Effects on High-Voltage Spinel Manganese Cathodes2017

    • Author(s)
      D. Kim, H. Shiiba, N. Zettsu, T. Yamada, T. Kimijima, G.S. Santolino, R. Ishikawa, Y. Ikuhara, K. Teshima
    • Journal Title

      NPG Asia Materials

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Possible Absence of Critical Thickness and Size Effect in Ultrathin Perovskite Ferroelectric Films2017

    • Author(s)
      P. Gao, Z. Zhang, M. Li, R. Ishikawa, B. Feng, H.-J, Liu, Y.-L. Huang, N. Shibata, X. Ma, S. Chen, J. Zhang, K. Liu, E.-G. Wang, D. Yu, L. Liao, Y. -H. Chu, Y. Ikuhara
    • Journal Title

      Nature Communications

      Volume: 印刷中 Issue: 1 Pages: 15549-15549

    • DOI

      10.1038/ncomms15549

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Atomic Mechanism of Polarization-Controlled Surface Reconstruction in Ferroelectric Thin Films2016

    • Author(s)
      P. Gao, HJ. Liu, YL. Huang, YH. Chu, R. Ishikawa, B. Feng, Y. Jiang, N. Shibata, E. Wang, and Y. Ikuhara
    • Journal Title

      Nature Communications

      Volume: 7 Issue: 1 Pages: 11318-11318

    • DOI

      10.1038/ncomms11318

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Adsorption sites of single noble metal atoms on the rutile TiO2 (110) surface influenced by different surface oxygen vacancies2016

    • Author(s)
      K. Matsunaga, T.-Y. Chang, R. Ishikawa, Q. Dong, K. Toyoura, A. Nakamura, Y. Ikuhara and N. Shibata
    • Journal Title

      J. Phys.: Condens. Matter.

      Volume: 28 Issue: 17 Pages: 175002-175002

    • DOI

      10.1088/0953-8984/28/17/175002

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Jointed magnetic skyrmion lattices at a small-angle grain boundary directly visualized by advanced electron microscopy2016

    • Author(s)
      Takao Matsumoto, Yeong-Gi So, Yuji Kohno, Hidetaka Sawada, Ryo Ishikawa, Yuichi Ikuhara, Naoya Shibata
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 35880-35880

    • DOI

      10.1038/srep35880

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Single atom visibility in STEM optical depth sectioning2016

    • Author(s)
      Ryo Ishikawa, Stephen J. Pennycook, Andrew R. Lupini, Scott D. Findlay, Naoya Shibata, Yuichi Ikuhara
    • Journal Title

      APPLIED PHYSICS LETTERS

      Volume: 109 Issue: 16 Pages: 163102-163102

    • DOI

      10.1063/1.4965709

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] An artificial photosynthesis anode electrode composed of a nanoparticulate photocatalyst film in a visible light responsive GaN-ZnO solid solution system2016

    • Author(s)
      Y. Imanaka, T. Anazawa, T. Manabe, H. Amada, S. Ido, F. Kumasaka, N. Awaji, G. S. Santolino, R. Ishikawa, Y. Ikuhara
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 35593-35593

    • DOI

      10.1038/srep35593

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Interfacial Atomic Structure of Twisted Few-Layer Graphene2016

    • Author(s)
      R. Ishikawa, N. Lugg, K. Inoue, H. Sawada, T. Taniguchi, N. Shibata, Y. Ikuhara
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 21273-21273

    • DOI

      10.1038/srep21273

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Towards 3D Mapping of BO6 Octahedron Rotations at Perovskite Thin Film Heterointerfaces, Unit Cell by Unit Cell2015

    • Author(s)
      Q. He, R. Ishikawa, A. R. Lupini, L. Qiao, E.J. Moon, O. Ovchinnikov, S.J. May, M. D. Biegalski, and A. Borisevich
    • Journal Title

      ACS Nano

      Volume: 8 Issue: 8 Pages: 8412-8419

    • DOI

      10.1021/acsnano.5b03232

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomic-Scale Assessment of the Crystallization Onset in Silicon Carbonitride2015

    • Author(s)
      G. Mera, R. Ishikawa, E. Ionescu, Y. Ikuhara and R. Riedel
    • Journal Title

      Journal of European Ceramic Society

      Volume: 35 Issue: 12 Pages: 3355-3362

    • DOI

      10.1016/j.jeurceramsoc.2015.01.008

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Visualizing the Mixed Bonding Properties of Liquid Boron with High-Resolution X-Ray Compton Scattering2015

    • Author(s)
      J. T. Okada, P.H.-L. Sit, Y. Watanabe, B. Barbiellini, T. Ishikawa, Y.J. Wang, M. Itou, Y. Sakurai, A. Bansil, R. Ishikawa, M. Hamaishi, P.-F. Paradis, K. Kimura, T. Ishikawa, and S. Nanao
    • Journal Title

      Physical Review Letters

      Volume: 114 Issue: 17 Pages: 177401-177401

    • DOI

      10.1103/physrevlett.114.177401

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Large-angle illumination STEM: Toward three-dimensional atom-by-atom imaging2015

    • Author(s)
      R. Ishikawa, A.R. Lupini, Y. Hinuma and S.J. Pennycook
    • Journal Title

      Ultramicroscopy

      Volume: 151 Pages: 122-129

    • DOI

      10.1016/j.ultramic.2014.11.009

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Quantitative Electron Microscopy and the Application by Single Electron Signals2015

    • Author(s)
      R. Ishikawa, A.R. Lupini, S.D. Findlay, T. Taniguchi, and S.J. Pennycook
    • Journal Title

      Microscopy and Microanalysis

      Volume: 21 Issue: S3 Pages: 1449-1450

    • DOI

      10.1017/s1431927615008028

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Advanced Electron Microscopy for Energy Related Materials2015

    • Author(s)
      R. Ishikawa, N. Shibata and Y. Ikuhara
    • Journal Title

      Microscopy and Microanalysis

      Volume: 21 Issue: S3 Pages: 471-472

    • DOI

      10.1017/s1431927615003153

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 先進電子顕微鏡法を用いた点欠陥構造解析2017

    • Author(s)
      石川亮
    • Organizer
      Workshop on Materials Science undr Ultra-High Pressure 2017
    • Place of Presentation
      愛媛大学,松山市,愛媛県
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] MnドープSrTiO3における希薄磁性転位の創成2017

    • Author(s)
      石川亮,真保陽一,杉山一生,柴田直哉,幾原雄一
    • Organizer
      日本セラミックス協会 2017年 年会
    • Place of Presentation
      日本大学駿河台キャンパス,東京都
    • Related Report
      2016 Annual Research Report
  • [Presentation] ADF-STEM法による単原子ドーパントの解析2016

    • Author(s)
      石川亮
    • Organizer
      ニューダイヤモンドフォーラム
    • Place of Presentation
      東京都目黒区、東京大学生産技術研究所
    • Year and Date
      2016-01-22
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Luminous complex point defect structure in Ce doped cubic boron nitride2016

    • Author(s)
      R. Ishikawa, N. Shibata, F. Oba, T. Taniguchi, S.D. Findlay, I. Tanaka, Y. Ikuhara
    • Organizer
      Global Forum on Advanced Materials and Technologies 2016
    • Place of Presentation
      Toronto, Canada
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Single Si atoms and silicon nitride nano-clusters in SiCN polymer-derived ceramics2016

    • Author(s)
      R. Ishikawa, G. Mera, E. Ionescu, K. Morita, R. Reidel, Y. Ikuhara
    • Organizer
      High Temperature Ceramic Matrix Composites 2016
    • Place of Presentation
      Toronto, Canada
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SrTiO3小傾角粒界における転位原子構造解析2016

    • Author(s)
      石川亮,P. Gao, B. Feng, 熊本明仁,柴田直哉,幾原雄一
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Place of Presentation
      仙台国際センター, 仙台市, 宮城県
    • Related Report
      2016 Annual Research Report
  • [Presentation] Direct Observation of Functional Point Defect Structures in Nitrides2016

    • Author(s)
      Ryo Ishikawa
    • Organizer
      8th International Workshop on Spinel Nitrides and Related Materials
    • Place of Presentation
      Rudesheim, Germany
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ペロブスカイト型固体電解質の粒界構造とリチウムイオンの伝導性2016

    • Author(s)
      石川亮,東拓磨,佐々野駿,木村禎一,幾原裕美,柴田直哉,幾原雄一
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ,千葉県
    • Related Report
      2016 Annual Research Report
  • [Presentation] Tracking Dopant Diffusion Pathways in Bulk Materials2015

    • Author(s)
      R. Ishikawa
    • Organizer
      2015 Sweden-Japan Workshop on Nanoscale Electron-Photon Interactions via Energy Dissipation and Fluctuation
    • Place of Presentation
      Royal Institute of Technology, Stockholm, Sweden
    • Year and Date
      2015-11-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Atomic Structure of Twisted a Few Layer Graphene2015

    • Author(s)
      R. Ishikawa, K. Inoue, H. Sawada, T. Taniguchi, N. Shibata, Y. Ikuhara
    • Organizer
      Materials Science & Technology 2015
    • Place of Presentation
      Ohio, USA
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
  • [Presentation] STEM像の定量解析手法の開発とその応用2015

    • Author(s)
      石川亮
    • Organizer
      日本金属学会 第157回秋季大会
    • Place of Presentation
      福岡県福岡市,九州大学伊東キャンパス
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] ねじれ粒界を含む複層グラフェンの原子構造2015

    • Author(s)
      石川亮,N. Lugg, 井上和俊, 谷口尚,柴田直哉,幾原雄一
    • Organizer
      日本金属学会 第157回秋季大会
    • Place of Presentation
      福岡県, 福岡市, 九州大学 伊東キャンパス
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] Atomic Structure of Twisted Bilayer Graphene2015

    • Author(s)
      R. Ishikawa, K. Inoue, T. Taniguchi, N. Shibata, Y. Ikuhara
    • Organizer
      The 11th Pacific Rim Conference of Ceramic Societies
    • Place of Presentation
      Juju, Korea
    • Year and Date
      2015-08-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Advanced Electron Microscopy for Energy Related Materials2015

    • Author(s)
      R. Ishikawa, N. Shibata, Y. Ikuhara
    • Organizer
      Microscopy and Microanalysis
    • Place of Presentation
      Portland, USA
    • Year and Date
      2015-08-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Quantitative Electron Microscopy and the Application by Single Electron Signals2015

    • Author(s)
      R. Ishikawa, A.R. Lupini, S.D. Findlay, T. Taniguchi, and S.J. Pennycook
    • Organizer
      Microscopy and Microanalysis
    • Place of Presentation
      Portland, USA
    • Year and Date
      2015-08-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 数原子層グラフェンのねじれ粒界構造2015

    • Author(s)
      石川亮 , 井上和俊, 谷口尚,柴田直哉,幾原雄一
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      京都府京都市,国立京都国際会館
    • Year and Date
      2015-05-12
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2022-02-16  

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