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Development of lithium-free sodium ion battery working at room temperature

Research Project

Project/Area Number 15K18240
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Riki Kataoka  国立研究開発法人産業技術総合研究所, 電池技術研究部門, 研究員 (20737994)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsナトリウム二次電池 / 無機合成 / 酸化物 / 正極材料
Outline of Final Research Achievements

A Sodium ion battery (SIB) is one of the candidates as alternative of a lithium ion battery (LIB) due to the abundance of sodium resources. In this study, we challenged to develop a high capacity positive electrode material for SIB comparable to that of LIB. Positive electrode active materials for the rechargeable sodium ion battery are in-situ synthesized during initial charge process in an electrochemical cell from precursor composites of Na and Mn oxides. By this approach, we directly synthesized a high capacity sodium-rich manganese oxide material for the first time, which have only been prepared by ion-exchange method so far. In addition, its initial gravimetric energy density, 550 Wh/kg, is comparable to that of a conventional material for LIB.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (7 results)

All 2017 2016 2015

All Journal Article (2 results) Presentation (3 results) (of which Int'l Joint Research: 1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Electrochemical In Situ Synthesis: A New Synthesis Route for Redox Active Manganese Oxides for Rechargeable Sodium Ion Battery through Initial Charge Process2017

    • Author(s)
      Riki Kataoka, M. Kitta, Nobuhiko Takeichi, Tetsu Kiyobayashi
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 164 Issue: 2 Pages: A226-A230

    • DOI

      10.1149/2.0851702jes

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Spinel manganese oxide: A high capacity positive electrode material for the sodium ion battery2016

    • Author(s)
      Riki Kataoka, Mitsunori Kitta, Hiroyuki Ozaki, Nobuhiko Takeichi, Tetsu Kiyobayashi
    • Journal Title

      Electrochimica Acta

      Volume: 212 Pages: 458-464

    • DOI

      10.1016/j.electacta.2016.07.038

    • Related Report
      2016 Annual Research Report
  • [Presentation] Electrochemical Properties of Composites of Sodium Peroxide(Na2O2) and Transition Metal Oxide (MnOx) As a Positive Electrode Material for the Sodium Ion Battery2016

    • Author(s)
      Riki Kataoka, Tetsu Kiyobayashi, Nobuhiko Takeichi
    • Organizer
      PRIME2016
    • Place of Presentation
      ハワイコンベンションセンター、ホノルル、アメリカ
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Na過酸化物-遷移金属酸化物複合体のNa挿入脱離特性2016

    • Author(s)
      片岡理樹、清林哲、竹市信彦
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学、吹田キャンパス
    • Year and Date
      2016-03-29
    • Related Report
      2015 Research-status Report
  • [Presentation] Electrochemical performances of lithium extracted Li2-xMnO3 as the positive electrode material for the room temperature Na ion battery2015

    • Author(s)
      Riki Kataoka, Tetsu Kiyobayashi
    • Organizer
      2272015th Electrochemical society meeting
    • Place of Presentation
      アメリカ、シカゴ
    • Year and Date
      2015-05-24
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 非水電解質二次電池用の正極材料およびその製造方法2016

    • Inventor(s)
      片岡理樹
    • Industrial Property Rights Holder
      片岡理樹
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-168503
    • Filing Date
      2016-08-30
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 非水電解質二次電池用の正極材料およびその製造方法2016

    • Inventor(s)
      片岡理樹、清林哲、竹市信彦
    • Industrial Property Rights Holder
      片岡理樹、清林哲、竹市信彦
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-03-22
    • Related Report
      2015 Research-status Report
    • Overseas

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Published: 2015-04-16   Modified: 2018-03-22  

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