Project/Area Number |
15K18250
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Metal making/Resorce production engineering
|
Research Institution | Hokkaido University |
Principal Investigator |
Natsui Shungo 北海道大学, 工学研究院, 助教 (70706879)
|
Research Collaborator |
SUZUKI Ryosuke
KIKUCHI Tatsuya
SUUDO Takuya
NASHIMOTO Ryota
TAKAI Hifumi
|
Project Period (FY) |
2015-04-01 – 2018-03-31
|
Project Status |
Completed (Fiscal Year 2017)
|
Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
Keywords | コロイダルメタル / 溶融塩電解 / その場観察 / 界面活性 / 数値流体力学 / 溶融塩 / 電気化学 / 流体力学 / 界面形状 / 共還元 / 気液流動場 / 混相流 |
Outline of Final Research Achievements |
In the thermic reduction of oxide XOx-1(s)(X = Ti, Zr, or difficult reducibility metals) using electrodeposited liquid metal (Me = Ca, Li, or their alloys), the presence of dissolved Me at the vicinity of the cathode is essential, when the oxide is placed close to the cathode. To understand the transient behavior of Me droplets in the molten salt bath, the interface between the electrodeposited phase and the bath system was observed in-situ using a high-speed digital microscope. Further, the transient behaviors of multi-fluid system were investigated using the SPH model. We found that the droplets on the electrode are slightly flattened, when the colloidal Me content decreases. This mechanism indicates that the heterogeneous distribution of the colloidal Me may be due to the local Me solubility in the electrolyte.
|