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High-speed reduction method by bubbles induced emulsified metal droplets in molten salt bath

Research Project

Project/Area Number 15K18250
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Metal making/Resorce production engineering
Research InstitutionHokkaido University

Principal Investigator

Natsui Shungo  北海道大学, 工学研究院, 助教 (70706879)

Research Collaborator SUZUKI Ryosuke  
KIKUCHI Tatsuya  
SUUDO Takuya  
NASHIMOTO Ryota  
TAKAI Hifumi  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsコロイダルメタル / 溶融塩電解 / その場観察 / 界面活性 / 数値流体力学 / 溶融塩 / 電気化学 / 流体力学 / 界面形状 / 共還元 / 気液流動場 / 混相流
Outline of Final Research Achievements

In the thermic reduction of oxide XOx-1(s)(X = Ti, Zr, or difficult reducibility metals) using electrodeposited liquid metal (Me = Ca, Li, or their alloys), the presence of dissolved Me at the vicinity of the cathode is essential, when the oxide is placed close to the cathode. To understand the transient behavior of Me droplets in the molten salt bath, the interface between the electrodeposited phase and the bath system was observed in-situ using a high-speed digital microscope. Further, the transient behaviors of multi-fluid system were investigated using the SPH model. We found that the droplets on the electrode are slightly flattened, when the colloidal Me content decreases. This mechanism indicates that the heterogeneous distribution of the colloidal Me may be due to the local Me solubility in the electrolyte.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (25 results)

All 2018 2017 2016 2015 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Remarks (3 results) Funded Workshop (1 results)

  • [Journal Article] Morphology of lithium droplets electrolytically deposited in LiCl-KCl-Li2O melt2017

    • Author(s)
      Natsui Shungo、Sudo Takuya、Kikuchi Tatsuya、Suzuki Ryosuke O.
    • Journal Title

      Electrochemistry Communications

      Volume: 81 Pages: 43-47

    • DOI

      10.1016/j.elecom.2017.06.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An SPH Study of Molten Matte-Slag Dispersion2017

    • Author(s)
      Natsui Shungo、Nashimoto Ryota、Kumagai Takehiko、Kikuchi Tatsuya、Suzuki Ryosuke O.
    • Journal Title

      Metallurgical Materials Transactions B

      Volume: 48 Issue: 3 Pages: 1792-1806

    • DOI

      10.1007/s11663-017-0930-z

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Observation of Interface Deformation in Sodium Polytungstate Solution–Silicone Oil System due to Single Rising Bubble2017

    • Author(s)
      Shungo Natsui, Ryota Nashimoto, Daiki Nakajima, Takehiko Kumagai, Tatsuya Kikuchi, and Ryosuke O. Suzuki
    • Journal Title

      ISIJ International

      Volume: 57 Issue: 2 Pages: 394-396

    • DOI

      10.2355/isijinternational.ISIJINT-2016-521

    • NAID

      130005331754

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Temperature Dependence of Behavior of Interface between Molten Sn and LiCl-KCl Eutectic Melt Due to Rising Gas Bubble2016

    • Author(s)
      Shungo Natsui, Ryota Nashimoto, Hifumi Takai, Takehiko Kumagai, Tatsuya Kikuchi, and Ryosuke O. Suzuki
    • Journal Title

      Metallurgical and Materials Transactions B

      Volume: 47 Issue: 3 Pages: 1532-1537

    • DOI

      10.1007/s11663-016-0618-9

    • NAID

      120006219911

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] SPH Simulations of the Behavior of Two Immiscible Liquid Stirred by the Movement of a Gas Bubble2016

    • Author(s)
      Shungo Natsui, Ryota Nashimoto, Hifumi Takai, Takehiko Kumagai, Tatsuya Kikuchi, and Ryosuke O. Suzuki
    • Journal Title

      Chemical Engineering Science

      Volume: 141 Pages: 342-355

    • DOI

      10.1016/j.ces.2015.11.018

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 溶融CaCl2-LiCl電解におけるカソード界面と流れ2018

    • Author(s)
      夏井 俊悟、数土 卓也, 菊地 竜也、鈴木 亮輔
    • Organizer
      資源素材学会2018年春季講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 日本鉄鋼協会第175回春季講演大会2018

    • Author(s)
      夏井俊悟
    • Organizer
      製錬プロセスにおける分散相と融体界面移動の数理モデル
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 液体金属界面の流れと形状制御の追求2017

    • Author(s)
      夏井俊悟
    • Organizer
      2016年度ベースメタル研究ステーションワークショップ”鉄鋼原料の多様化と精錬プロセスにおける課題
    • Place of Presentation
      東北大学多元物質科学研究所事務棟2F大会議室
    • Year and Date
      2017-01-17
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 溶融LiCl-KCl中で電析したLi液滴とTi酸化物との濡れ2017

    • Author(s)
      数土卓也、夏井俊悟、菊地竜也、鈴木亮輔
    • Organizer
      日本電気化学会溶融塩委員会第49回溶融塩化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 溶融LiCl-KClの電析による液体Liの高速顕微鏡観察2017

    • Author(s)
      数土卓也、夏井 俊悟、菊地竜也、鈴木亮輔
    • Organizer
      資源・素材&EARTH 2017(札幌)平成29年度資源・素材関係協会合同秋期大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 溶融塩中で析出したLi液滴の高速顕微鏡観察2017

    • Author(s)
      数土卓也、夏井俊悟、菊地竜也、鈴木亮輔
    • Organizer
      日本金属学会2017年秋期(第161回)講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] High-speed Observation of Electrolytic Deposition of Liquid Lithium Droplets in molten LiCl-KCl Melt2017

    • Author(s)
      Shungo Natsui, Takuya Sudo, Tatsuya Kikuchi, and Ryosuke O. Suzuki
    • Organizer
      232nd ECS Meeting (October 16, 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Phenomenological analysis of interfacial behavior of melts2017

    • Author(s)
      Shungo Natsui
    • Organizer
      Joint Workshop between KU and HU on Computational Materials Processing
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 流動TiO2粒子の電解還元挙動2016

    • Author(s)
      数土 卓也, 夏井 俊悟, 菊地 竜也, 鈴木 亮輔
    • Organizer
      電気化学会溶融塩委員会第48回溶融塩化学討論会
    • Place of Presentation
      新潟大学駅南キャンパス「ときめいと」
    • Year and Date
      2016-11-24
    • Related Report
      2016 Research-status Report
  • [Presentation] LiCl-KCl-Li2O溶融塩中での流動TiO2粒子の電解還元2016

    • Author(s)
      数土卓也, 夏井俊悟, 菊地竜也, 鈴木亮輔
    • Organizer
      日本金属学会2016年秋期講演大会
    • Place of Presentation
      大坂大学豊中キャンパス
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report
  • [Presentation] 二液相間に生成・分離するエマルジョンの動力学モデル2016

    • Author(s)
      夏井俊悟、梨元涼太、菊地竜也、鈴木亮輔
    • Organizer
      平成28年度資源・素材関係学協会合同秋季大会
    • Place of Presentation
      岩手大学理工学部キャンパス
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] LiCl-KCl溶融塩中における流動酸化物粒子の電解還元2016

    • Author(s)
      数土卓也,夏井俊悟, 菊地竜也,鈴木亮輔
    • Organizer
      日本金属学会日本鉄鋼協会北海道支部サマーセッション
    • Place of Presentation
      北海道大学情報教育館スタジオ型多目的室・遠友学舎
    • Year and Date
      2016-07-01
    • Related Report
      2016 Research-status Report
  • [Presentation] SPH Analysis of Interfacial Flow of the Two Immiscible Melts2016

    • Author(s)
      Shungo Natsui, Ryota Nashimoto, Tatsuya Kikuchi, and Ryosuke O. Suzuki
    • Organizer
      Advances in Molten Slags, Fluxes, and Salts: Proceedings of the 10th International Conference on Molten Slags, Fluxes and Salts (MOLTEN) 2016
    • Place of Presentation
      Seattle, Washington, USA.
    • Year and Date
      2016-05-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 気泡通過時の溶融メタル-スラグ界面流れ解析2015

    • Author(s)
      梨元涼太, 夏井俊悟, 高井比文, 菊地竜也, 鈴木亮輔
    • Organizer
      日本鉄鋼協会第170回秋季講演大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 固気液三相流の粒子ベース直接数値モデル2015

    • Author(s)
      夏井俊悟, 梨元涼太, 高井比文, 菊地竜也, 鈴木亮輔
    • Organizer
      日本鉄鋼協会第170回秋季講演大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Particle-based Multiphase Flow Simulation for Low Carbon Ironmaking Design2015

    • Author(s)
      Shungo Natsui, Tatsuya Kikuchi, and Ryosuke O. Suzuki
    • Organizer
      Asia Steel International Conference 2015 (Asia Steel 2015)
    • Place of Presentation
      Pacifico Yokohama, Yokohama, Japan.
    • Year and Date
      2015-09-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 北海道大学研究者総覧

    • URL

      https://researchers.general.hokudai.ac.jp/profile/sp/ja.omk7jGHD.PXLd6w1FjxANw==.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] Researchmap

    • URL

      https://researchmap.jp/natsui/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 夏井 俊悟 - 北海道大学研究者総覧

    • URL

      https://researchers.general.hokudai.ac.jp/profile/sp/ja.omk7jGHD.PXLd6w1FjxANw==.html

    • Related Report
      2016 Research-status Report
  • [Funded Workshop] 1st Joint Workshop between KU and HU on Computational Materials Processing2017

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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