| Project/Area Number |
15K18257
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
|
|---|
| Research Institution | Hiroshima University |
|---|
Principal Investigator |
Balgis Ratna 広島大学, 工学研究院, 助教 (70731917)
|
|---|
| Project Period (FY) |
2015-04-01 – 2017-03-31
|
| Project Status |
Completed (Fiscal Year 2016)
|
| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
|
|---|
| Keywords | Aerosol process / Nanostructured carbon / Energy resources / Energy storages / Polymer / Polymers / nanostructured Pt/C / aerosol process / Phenolic resin / PSL / Self-Organization / Fluid flow model |
|---|
| Outline of Final Research Achievements |
In this study, the effects of various carbon nanostructures on the catalytic performances of carbon supported platinum (Pt/C) electrocatalysts were evaluated experimentally and numerically. The Pt/C catalysts were prepared using a hybrid method involving the preparation of dense, hollow, and porous carbon particle via aerosol spray pyrolysis followed by microwave-assisted Pt deposition. Electrochemical surface area of porous Pt/C catalyst was more than twice than those of hollow or dense Pt/C. The effects of pore size on electrocatalysis were also studied. The results showed the importance of a balance between mesopores and macropores for effective catalysis with a high charge transfer rate. A fluid flow model showed that good oxygen transport contributed to the catalytic activity. Furthermore, the addition of N doping to porous carbon may further increase the electrocatalytic performance. While, the formation of hollow spherical carbon gave a good capacitance performance.
|
