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Multistep purification system for automotive exhaust using redox behavior of transition metals

Research Project

Project/Area Number 15K18268
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionKyoto University

Principal Investigator

Yoshida Hiroshi  京都大学, 実験と理論計算科学のインタープレイによる触媒・電池の元素戦略研究拠点ユニット, 特定助教 (40722426)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords貴金属代替 / 汎用元素 / 自動車触媒 / タンデム構造 / 自動車排ガス浄化触媒 / 遷移金属触媒
Outline of Final Research Achievements

For the simultaneous purification of NO, CO and HC in automotive exhaust, a new three-way catalysis with a tandem structure was developed. In the former stage, CO oxidation was carried out over Cr-Cu/CeO2, resulting in the decrease of CO and O2 concentration. The gas which contained stoichiometric NO, C3H6 and O2 was consecutively introduced to the latter stage and NO-C3H6-O2 reaction over Pd/CeO2 was carried out for the simultaneous purification of NO and HC. The results demonstrated that the tandem structure is one of useful ways for the development of new three-way catalysis.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (28 results)

All 2017 2016 2015

All Journal Article (6 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 6 results,  Acknowledgement Compliant: 1 results) Presentation (22 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Catalytic CO-NO reaction over Cr-Cu embedded CeO2 surface structure2017

    • Author(s)
      H. Yoshida, Y. Okabe, N. Yamashita, S. Hinokuma, M. Machida
    • Journal Title

      Catalysis Today

      Volume: 281 Pages: 590-595

    • DOI

      10.1016/j.cattod.2016.05.018

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structures and catalytic properties of Cr-Cu embedded CeO2 surfaces with different Cr/Cu ratios2016

    • Author(s)
      H. Yoshida, Y. Okabe, S. Misumi, H. Oyama, K. Tokusada, S. Hinokuma, M. Machida
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 120 Issue: 47 Pages: 26852-26863

    • DOI

      10.1021/acs.jpcc.6b08785

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A thermally stable Cr-Cu nanostructure embedded in CeO2 surface as a substitute for platinum-group metal catalysts2015

    • Author(s)
      H. Yoshida, N. Yamashita, S. Ijichi, Y. Okabe, S. Misumi, S. Hinokuma, M. Machida
    • Journal Title

      ACS Catalysis

      Volume: 5 Issue: 11 Pages: 6738-6747

    • DOI

      10.1021/acscatal.5b01847

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nanoparticle catalysts preparation using pulsed arc-plasma deposition2015

    • Author(s)
      H. Hinokuma, S. Misumi, H. Yoshida, M. Machida
    • Journal Title

      Catalysis Science & Technology

      Volume: 5 Issue: 9 Pages: 4249-4257

    • DOI

      10.1039/c5cy00636h

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Rh/ZrP2O7 as an efficient automotive catalyst for NOx reduction under slightly lean conditions2015

    • Author(s)
      Y. Nagao, Y. Nakahara, T. Sato, H. Kanemitsu, H. Iwakura, S. Takeshita, S. Minami, H. Yoshida, M. Machida
    • Journal Title

      ACS Catalysis

      Volume: 5 Issue: 3 Pages: 1986-1994

    • DOI

      10.1021/cs5020157

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Unusual redox behavior of Rh/AlPO4 and its impacts on three-way catalysis2015

    • Author(s)
      M. Machida, S. Minami, S. Hinokuma, H. Yoshida, Y. Nagao, T. Sato, Y. Nakahara
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 119 Issue: 1 Pages: 373-380

    • DOI

      10.1021/jp509649r

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 担持Cr-Cu系触媒の三元触媒特性2017

    • Author(s)
      芳田嘉志,小山遥加,日隈聡士,町田正人
    • Organizer
      第119回触媒討論会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2017-03-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] 担持Ni-Cu系触媒の三元触媒特性2017

    • Author(s)
      小山遥加,芳田嘉志,日隈聡士,町田正人
    • Organizer
      第119回触媒討論会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2017-03-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ni-Cu系複合酸化物の構造と三元触媒特性2017

    • Author(s)
      小山遥加,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター
    • Year and Date
      2017-01-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ni/CeO2のNO-CO反応特性と機構解析2017

    • Author(s)
      徳貞香織,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター
    • Year and Date
      2017-01-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] Cr-Cu/CeO2のCO-O2およびCO-NO反応に対する触媒特性(2)2016

    • Author(s)
      芳田嘉志,岡部有里,三角仁志,日隈聡士,町田正人
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Cr-Cu embedded CeO2 as an efficient catalyst for CO-NO reaction2016

    • Author(s)
      H. Yoshida, Y. Okabe, S. Hinokuma, M. Machida
    • Organizer
      Rare Earths 2016
    • Place of Presentation
      Hokkaido University
    • Year and Date
      2016-06-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Cr-Cu embedded CeO2 as an efficient catalyst for CO-NO reaction2016

    • Author(s)
      H. Yoshida, Y. Okabe, S. Hinokuma, M. Machida
    • Organizer
      Rare Earth 2016
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2016-06-05
    • Related Report
      2015 Research-status Report
  • [Presentation] Cu/Al2O3触媒を用いたNO-CO-C3H6-O2反応2016

    • Author(s)
      小山遥加,芳田嘉志,伊地知翔太,日隈聡士,町田正人
    • Organizer
      第117回触媒討論会
    • Place of Presentation
      大阪府立大学(堺市)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Ni触媒を用いたNO-CO反応における担体効果2016

    • Author(s)
      徳貞香織,芳田嘉志,伊地知翔太,日隈聡士,町田正人
    • Organizer
      第117回触媒討論会
    • Place of Presentation
      大阪府立大学(堺市)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Cr-Cu系担持酸化物を用いた省貴金属触媒の開発2016

    • Author(s)
      伊地知翔太,小山遥加,徳貞香織,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第54回セラミックス基礎科学討論会
    • Place of Presentation
      アバンセ(佐賀市)
    • Year and Date
      2016-01-07
    • Related Report
      2015 Research-status Report
  • [Presentation] 三元触媒反応におけるCu/Al2O3触媒の活性点構造解析2016

    • Author(s)
      小山遥加,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第53回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2016 Annual Research Report
  • [Presentation] NO-CO反応におけるNi/CeO2の触媒特性2016

    • Author(s)
      徳貞香織,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第53回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2016 Annual Research Report
  • [Presentation] 三元触媒反応におけるCu/Al2O3のNO還元特性2016

    • Author(s)
      小山遥加,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第7回触媒科学研究発表会
    • Place of Presentation
      大分大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ni/CeO2を用いたNO-CO反応における反応機構解析2016

    • Author(s)
      徳貞香織,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第7回触媒科学研究発表会
    • Place of Presentation
      大分大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] 排ガス浄化触媒における貴金属節減・代替を目的とした触媒設計2016

    • Author(s)
      芳田嘉志
    • Organizer
      第2回元素戦略に基づいた環境調和型触媒創製に関する研究会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] CO removal from automotive emission over thermally durable CeO2-supported Cr-Cu catalyst2015

    • Author(s)
      H. Yoshida, Y. Okabe, N. Yamashita, S. Hinokuma, M. Machida
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      ハワイ(アメリカ合衆国)
    • Year and Date
      2015-12-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Thermally stable Cr-Cu surface nanostructures over CeO2 as substitutes for PGM catalysts2015

    • Author(s)
      H. Yoshida, Y. Okabe, S. Ijichi, S. Hinokuma, M. Machida
    • Organizer
      7th China-Japan Workshop on Environmental Catalysis and Eco-Materials
    • Place of Presentation
      広州(中国)
    • Year and Date
      2015-11-06
    • Related Report
      2015 Research-status Report
  • [Presentation] Cr-Cu/CeO2のCO-O2およびCO-NO反応に対する触媒特性2015

    • Author(s)
      芳田嘉志,岡部有里,伊地知翔太,日隈聡士,町田正人
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学(津市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 含浸法で調製したCr-Cu/CeO2のCO酸化反応特性2015

    • Author(s)
      岡部有里,伊地知翔太,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学(津市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Highly active Cr-Cu/CeO2 catalyst for CO-O2 and CO-NO reactions2015

    • Author(s)
      H. Yoshida, Y. Okabe, N. Yamashita, S. Hinokuma, M. Machida
    • Organizer
      250th ACS National meeting
    • Place of Presentation
      ボストン(アメリカ合衆国)
    • Year and Date
      2015-08-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 微量のCr-Cu添加によるCeO2の触媒活性発現2015

    • Author(s)
      岡部有里,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Year and Date
      2015-06-27
    • Related Report
      2015 Research-status Report
  • [Presentation] CrおよびCuを共含浸したCeO2の構造および触媒活性2015

    • Author(s)
      岡部有里,日隈聡士,芳田嘉志,町田正人
    • Organizer
      第32回希土類討論会
    • Place of Presentation
      かごしま県民交流センター(鹿児島市)
    • Year and Date
      2015-05-21
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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