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Direct compositing of oxide and carbon by solution combustion synthesis

Research Project

Project/Area Number 15K18325
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionHokkaido University

Principal Investigator

ZHU Chunyu  北海道大学, 工学研究院, 特任助教 (30749255)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsリチウム電池 / 負極 / 複合体 / 酸化物 / リチウムイオン電池 / 燃焼合成 / 炭素材料
Outline of Final Research Achievements

For increasing the energy density of lithium ion batteries, it is vital to increase the capacity of negative material. In this study, we focused on the non-expensive transition metal oxides, which have capacities of more than two times of conventional graphite. However, due to severe volume change problem upon charging-discharing, it is difficult to obtain a good rate and cycling performance. To solve this problem, we proposed a solution combusiton synthesis to produce nano-oxide/carbon composites, which is effective to increase the rate and cycling performance of the oxide negative materials.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (15 results)

All 2017 2016 2015

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 7 results) Presentation (4 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Journal Article] Enhanced cycling performance of surface-doped LiMn2O4 modified by a Li2CuO2-Li2NiO2 solid solution for rechargeable lithium-ion batteries2017

    • Author(s)
      Cheng-Gong Han, Chunyu Zhu, Genki Saito, Nan Sheng, Takahiro Nomura, Tomohiro Akiyama
    • Journal Title

      Electrochimica Acta

      Volume: 224 Pages: 71-79

    • DOI

      10.1016/j.electacta.2016.12.041

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A facile one-pot synthesis of FeOx/carbon/graphene composites as superior anode materials for lithium-ion batteries2017

    • Author(s)
      Cheng-Gong Han, Chunyu Zhu, Nan Sheng, Yoshitaka Aoki, Hiroki Habazaki, Tomohiro Akiyama
    • Journal Title

      Electrochimica Acta

      Volume: 235 Pages: 88-97

    • DOI

      10.1016/j.electacta.2017.03.109

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Microencapsulated phase change materials with high heat capacity and high cyclic durability for high-temperature thermal energy storage and transportation2017

    • Author(s)
      Takahiro Nomura, Nan Sheng, Chunyu Zhu, Genki Saito, Daiki Hanzaki, Takehito Hiraki
    • Journal Title

      Applied Energy

      Volume: 188 Pages: 9-18

    • DOI

      10.1016/j.apenergy.2016.11.025

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Efficiency Hydrogen Membrane Fuel Cells with BaCe0.8Y0.2O3-δ Electrolyte Thin Films and Pd1-xAgx Solid Anodes2017

    • Author(s)
      Y. Aoki, T. yamaguchi, S. Kobayashi, C. Zhu, H. Habazaki
    • Journal Title

      Journal of Electrochemical Society

      Volume: 164 Issue: 6 Pages: F577-F581

    • DOI

      10.1149/2.0661706jes

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthesis of MnO/carbon composites by a single-step nitrate-cellulose combustion synthesis for Li ion battery anode2016

    • Author(s)
      Chunyu Zhu, Cheng-gong Han, Genki Saito, Tomohiro Akiyama
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 689 Pages: 931-937

    • DOI

      10.1016/j.jallcom.2016.08.054

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cotton derived porous carbon via an MgO template method for high performance lithium ion battery anodes2016

    • Author(s)
      Chunyu Zhu and Tomohiro Akiyama
    • Journal Title

      Green Chemistry

      Volume: 18 Issue: 7 Pages: 2106-2114

    • DOI

      10.1039/c5gc02397a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Solution combustion synthesis of porous Sn-C composite as anode material for lithium ion batteries2016

    • Author(s)
      Genki Saito, Chunyu Zhu, Cheng-Gong Han, Norihito Sakaguchi, Tomohiro Akiyama
    • Journal Title

      Advanced Powder Technology

      Volume: 27 Issue: 4 Pages: 1730-1737

    • DOI

      10.1016/j.apt.2016.06.004

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved electrochemical performance of LiMn2O4 surface-modified by a Mn4+-rich phase for rechargeable lithium-ion batteries2016

    • Author(s)
      Cheng-Gong Han, Chunyu Zhu, Genki Saito, Tomohiro Akiyama
    • Journal Title

      Electrochimica Acta

      Volume: 209 Pages: 225-234

    • DOI

      10.1016/j.electacta.2016.05.075

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] MnO nanocrystals incorporated in a N-containing carbon matrix for Li ion battery anodes2016

    • Author(s)
      Chunyu Zhu, Cheng-gong Han, Genki Saito, Tomohiro Akiyama.
    • Journal Title

      RSC Advances

      Volume: 6(36) Issue: 36 Pages: 30445-30453

    • DOI

      10.1039/c6ra00571c

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] MnO nanoparticles embedded in a carbon matrix for a high performance Li ion battery anode.2015

    • Author(s)
      Chunyu Zhu, Nan Sheng, Tomohiro Akiyama.
    • Journal Title

      RSC Advances

      Volume: 5(27) Issue: 27 Pages: 21066-21073

    • DOI

      10.1039/c5ra02649k

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A facile solution combustion synthesis of nanosized amorphous iron oxide incorporated in a carbon matrix for use as a high-performance lithium ion battery anode material.2015

    • Author(s)
      Chunyu Zhu, Genki Saito, Tomohiro Akiyama.
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 633(0) Pages: 424-429

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Facile synthesis of porous materials for energy storage2016

    • Author(s)
      朱春宇
    • Organizer
      Silk Road International Symposium for Distinguished Young Scholars
    • Place of Presentation
      西安交通大学,中国
    • Year and Date
      2016-12-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Solution Combustion Synthesis of Transition Metal Oxide-Carbon Composite for Li Ion Battery Anode2016

    • Author(s)
      C. Zhu, Y. Aoki, and H. Habazaki
    • Organizer
      PRiME2016
    • Place of Presentation
      Hawaii Convention Center, Honolulu
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] リチウムイオン電池負極用酸化物ナノ粒子・炭素複合体の簡易合成2016

    • Author(s)
      朱春宇
    • Organizer
      第32回ライラックセミナー・第22回若手研究者交流会
    • Place of Presentation
      おこばち山荘,小樽
    • Year and Date
      2016-06-25
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Facile synthesis of MnO/carbon composite with controlled carbon contents as high-performance negative electrode for Li ion batteries2015

    • Author(s)
      Chunyu ZHU and Tomohiro AKIYAMA
    • Organizer
      International Symposium on Energy Conversion and Storage
    • Place of Presentation
      Chinese Academy of Sciences (IPE-CAS) Beijing, China
    • Year and Date
      2015-05-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2018-03-22  

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